Effect of sepiolite organomodification on the performance of PCL/sepiolite nanocomposites
2017
Authors
Nikolić, Marija S.
Petrovic, Rada
Veljović, Đorđe

Ćosović, Vladan

Stankovic, Nadezda

Đonlagić, Jasna

Article (Accepted Version)
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Show full item recordAbstract
Poly(epsilon-caprolactone) (PCL) based nanocomposites with unmodified and organomodified sepiolites were prepared by solution casting method. The sepiolites were modified with short (3-mercaptopropyl)trimethoxysilane (SEP-SI) by using covalent grafting or with long hexadecylamine (SEP-HDA) by using ionic exchange. In order to reveal the influence of the organomodification on the nanoclay dispersion and the properties of the nano composites XRD, DSC, TG, SEM, TEM, optical microscopy, melt rheology and dynamic-mechanical analyses were performed. A better dispersion was achieved when organomodified sepiolites instead of native ones were used as fillers. As deduced from the melt rheology data, by analysis of the Cole-Cole plots, the best dispersion was obtained for SEP-SI nanoclay. The thermal stability was not improved, however in the initial stages of the thereto-oxidative degradation a delay in the weight loss was observed for nanocomposites with organomodified sepiolites. The mechanica...l properties of the nanocomposites were improved in comparison to PCL, particularly for those with modified sepiolites. In terms of mechanical properties the use of sepiolite modified with HDA gave the best results, as a consequence of better interaction between longer alkyl hydrophobic part of the organic modificator and the hydrophobic PCL matrix.
Keywords:
Sepiolite / Poly(epsilon-caprolactone) / Biodegradable / NanocompositeSource:
European Polymer Journal, 2017, 97, 198-209Publisher:
- Oxford : Pergamon-Elsevier Science Ltd
Funding / projects:
- Synthesis and characterization of novel functional polymers and polymeric nanocomposites (RS-172062)
Note:
- This is a peer-reviewed version of the article https://doi.org/10.1016/j.eurpolymj.2017.10.010
- http://cer.ihtm.bg.ac.rs/handle/123456789/2104
DOI: 10.1016/j.eurpolymj.2017.10.010
ISSN: 0014-3057
WoS: 000419415800021
Scopus: 2-s2.0-85031711347
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IHTMTY - JOUR AU - Nikolić, Marija S. AU - Petrovic, Rada AU - Veljović, Đorđe AU - Ćosović, Vladan AU - Stankovic, Nadezda AU - Đonlagić, Jasna PY - 2017 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2941 AB - Poly(epsilon-caprolactone) (PCL) based nanocomposites with unmodified and organomodified sepiolites were prepared by solution casting method. The sepiolites were modified with short (3-mercaptopropyl)trimethoxysilane (SEP-SI) by using covalent grafting or with long hexadecylamine (SEP-HDA) by using ionic exchange. In order to reveal the influence of the organomodification on the nanoclay dispersion and the properties of the nano composites XRD, DSC, TG, SEM, TEM, optical microscopy, melt rheology and dynamic-mechanical analyses were performed. A better dispersion was achieved when organomodified sepiolites instead of native ones were used as fillers. As deduced from the melt rheology data, by analysis of the Cole-Cole plots, the best dispersion was obtained for SEP-SI nanoclay. The thermal stability was not improved, however in the initial stages of the thereto-oxidative degradation a delay in the weight loss was observed for nanocomposites with organomodified sepiolites. The mechanical properties of the nanocomposites were improved in comparison to PCL, particularly for those with modified sepiolites. In terms of mechanical properties the use of sepiolite modified with HDA gave the best results, as a consequence of better interaction between longer alkyl hydrophobic part of the organic modificator and the hydrophobic PCL matrix. PB - Oxford : Pergamon-Elsevier Science Ltd T2 - European Polymer Journal T1 - Effect of sepiolite organomodification on the performance of PCL/sepiolite nanocomposites VL - 97 SP - 198 EP - 209 DO - 10.1016/j.eurpolymj.2017.10.010 ER -
@article{ author = "Nikolić, Marija S. and Petrovic, Rada and Veljović, Đorđe and Ćosović, Vladan and Stankovic, Nadezda and Đonlagić, Jasna", year = "2017", abstract = "Poly(epsilon-caprolactone) (PCL) based nanocomposites with unmodified and organomodified sepiolites were prepared by solution casting method. The sepiolites were modified with short (3-mercaptopropyl)trimethoxysilane (SEP-SI) by using covalent grafting or with long hexadecylamine (SEP-HDA) by using ionic exchange. In order to reveal the influence of the organomodification on the nanoclay dispersion and the properties of the nano composites XRD, DSC, TG, SEM, TEM, optical microscopy, melt rheology and dynamic-mechanical analyses were performed. A better dispersion was achieved when organomodified sepiolites instead of native ones were used as fillers. As deduced from the melt rheology data, by analysis of the Cole-Cole plots, the best dispersion was obtained for SEP-SI nanoclay. The thermal stability was not improved, however in the initial stages of the thereto-oxidative degradation a delay in the weight loss was observed for nanocomposites with organomodified sepiolites. The mechanical properties of the nanocomposites were improved in comparison to PCL, particularly for those with modified sepiolites. In terms of mechanical properties the use of sepiolite modified with HDA gave the best results, as a consequence of better interaction between longer alkyl hydrophobic part of the organic modificator and the hydrophobic PCL matrix.", publisher = "Oxford : Pergamon-Elsevier Science Ltd", journal = "European Polymer Journal", title = "Effect of sepiolite organomodification on the performance of PCL/sepiolite nanocomposites", volume = "97", pages = "198-209", doi = "10.1016/j.eurpolymj.2017.10.010" }
Nikolić, M. S., Petrovic, R., Veljović, Đ., Ćosović, V., Stankovic, N.,& Đonlagić, J.. (2017). Effect of sepiolite organomodification on the performance of PCL/sepiolite nanocomposites. in European Polymer Journal Oxford : Pergamon-Elsevier Science Ltd., 97, 198-209. https://doi.org/10.1016/j.eurpolymj.2017.10.010
Nikolić MS, Petrovic R, Veljović Đ, Ćosović V, Stankovic N, Đonlagić J. Effect of sepiolite organomodification on the performance of PCL/sepiolite nanocomposites. in European Polymer Journal. 2017;97:198-209. doi:10.1016/j.eurpolymj.2017.10.010 .
Nikolić, Marija S., Petrovic, Rada, Veljović, Đorđe, Ćosović, Vladan, Stankovic, Nadezda, Đonlagić, Jasna, "Effect of sepiolite organomodification on the performance of PCL/sepiolite nanocomposites" in European Polymer Journal, 97 (2017):198-209, https://doi.org/10.1016/j.eurpolymj.2017.10.010 . .