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dc.creatorMojović, Zorica
dc.creatorMentus, Slavko
dc.creatorKrstic, I.
dc.date.accessioned2019-01-30T17:15:02Z
dc.date.available2019-01-30T17:15:02Z
dc.date.issued2007
dc.identifier.issn0036-0244
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/291
dc.description.abstractA new type of an electrode material, zeolite modified by the incorporation of Ni or NiO clusters into its cavities, was synthesized by multiple impregnation of zeolite 13X with a Ni-acetylacetonate solution followed by solvent evaporation and thermal degradation of the nickel compound. Samples with a Ni/13X mass ratio within the range 0.2-1.0 were synthesized. Modification by both Ni and NiO clusters, depending on whether the atmosphere was reducing (H-2) or oxidizing (air), respectively, was used to finish the sample. After modification, the zeolite kept its original crystallographic structure, as proven by X-ray diffractommetry. The dimensions of the incorporated clusters were limited by the diameter of the zeolite cavities (reaching1.3 nm). This material, homogenized with 10 wt% of nanodispersed carbon, was bonded in the form of a thin layer to a glassy carbon disc by means of Nafion and used as an electrode material in an aqueous 0.1 M NaOH solution. The cyclovoltammograms of this thin-layer electrode resemble those of a smooth nickel electrode in alkaline solutions.en
dc.publisherMaik Nauka/Interperiodica/Springer, New York
dc.relationinfo:eu-repo/grantAgreement/MESTD/MPN2006-2010/142047/RS//
dc.rightsrestrictedAccess
dc.sourceRussian Journal of Physical Chemistry A
dc.titleThin layer of Ni-modified 13X zeolite on glassy carbon support as an electrode material in aqueous solutionsen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractМојовић, Зорица; Ментус, С.; Крстиц, И.;
dc.citation.volume81
dc.citation.issue9
dc.citation.spage1452
dc.citation.epage1457
dc.citation.other81(9): 1452-1457
dc.citation.rankM23
dc.identifier.doi10.1134/S0036024407090208
dc.identifier.rcubConv_2327
dc.identifier.scopus2-s2.0-34548507916
dc.identifier.wos000253706400020
dc.type.versionpublishedVersion


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