This work presents the characterization of novel synthesized WO3/Fe3O4 catalysts and investigates their photocatalytic activity for thiacloprid decomposition under UV and simulated sunlight radiation. Four WO3/Fe3O4 nanopowders with different amounts of WO3 were synthesized by chemical co-precipitation method. XRD analysis showed the presence of hematite and magnetite nano-dimensional phases of Fe3O4 in the catalysts. The magnetite phase content increased with increasing WO3 content. Degradation efficiency of thiacloprid in the presence of 6.1WO3/Fe3O4/H2O2 under simulated solar radiation was 2.2 times higher compared to Fe3O4. Under an external magnetic field, a significant increase in the catalysts separation from reaction mixture was observed.
Keywords:
Hematite/magnetite / Magnetic separation / Photodegradation / Thiacloprid / WO3/Fe3O4
Source:
Journal of Industrial and Engineering Chemistry, 2019, 70, 264-275
Publisher:
Korean Society of Industrial Engineering Chemistry
TY - JOUR
AU - Banić, Nemanja
AU - Abramović, Biljana F.
AU - Krstić, Jugoslav
AU - Šojić, Merkulov D.V.
AU - Finčur, Nina L.
AU - Mitrić, Miodrag
PY - 2019
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2901
AB - This work presents the characterization of novel synthesized WO3/Fe3O4 catalysts and investigates their photocatalytic activity for thiacloprid decomposition under UV and simulated sunlight radiation. Four WO3/Fe3O4 nanopowders with different amounts of WO3 were synthesized by chemical co-precipitation method. XRD analysis showed the presence of hematite and magnetite nano-dimensional phases of Fe3O4 in the catalysts. The magnetite phase content increased with increasing WO3 content. Degradation efficiency of thiacloprid in the presence of 6.1WO3/Fe3O4/H2O2 under simulated solar radiation was 2.2 times higher compared to Fe3O4. Under an external magnetic field, a significant increase in the catalysts separation from reaction mixture was observed.
PB - Korean Society of Industrial Engineering Chemistry
T2 - Journal of Industrial and Engineering Chemistry
T1 - Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation
VL - 70
SP - 264
EP - 275
DO - 10.1016/j.jiec.2018.10.025
ER -
@article{
author = "Banić, Nemanja and Abramović, Biljana F. and Krstić, Jugoslav and Šojić, Merkulov D.V. and Finčur, Nina L. and Mitrić, Miodrag",
year = "2019",
abstract = "This work presents the characterization of novel synthesized WO3/Fe3O4 catalysts and investigates their photocatalytic activity for thiacloprid decomposition under UV and simulated sunlight radiation. Four WO3/Fe3O4 nanopowders with different amounts of WO3 were synthesized by chemical co-precipitation method. XRD analysis showed the presence of hematite and magnetite nano-dimensional phases of Fe3O4 in the catalysts. The magnetite phase content increased with increasing WO3 content. Degradation efficiency of thiacloprid in the presence of 6.1WO3/Fe3O4/H2O2 under simulated solar radiation was 2.2 times higher compared to Fe3O4. Under an external magnetic field, a significant increase in the catalysts separation from reaction mixture was observed.",
publisher = "Korean Society of Industrial Engineering Chemistry",
journal = "Journal of Industrial and Engineering Chemistry",
title = "Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation",
volume = "70",
pages = "264-275",
doi = "10.1016/j.jiec.2018.10.025"
}
Banić, N., Abramović, B. F., Krstić, J., Šojić, M. D.V., Finčur, N. L.,& Mitrić, M.. (2019). Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation. in Journal of Industrial and Engineering Chemistry
Korean Society of Industrial Engineering Chemistry., 70, 264-275.
https://doi.org/10.1016/j.jiec.2018.10.025
Banić N, Abramović BF, Krstić J, Šojić MD, Finčur NL, Mitrić M. Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation. in Journal of Industrial and Engineering Chemistry. 2019;70:264-275.
doi:10.1016/j.jiec.2018.10.025 .
Banić, Nemanja, Abramović, Biljana F., Krstić, Jugoslav, Šojić, Merkulov D.V., Finčur, Nina L., Mitrić, Miodrag, "Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation" in Journal of Industrial and Engineering Chemistry, 70 (2019):264-275,
https://doi.org/10.1016/j.jiec.2018.10.025 . .
