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Preparation of zeolite from coal fly ash as waste raw material

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2018
bitstream_6985.pdf (2.181Mb)
Authors
Pavlović, Stefan
Marinković, Dalibor
Stanković, Miroslav
Milovanović, Biljana
Conference object (Published version)
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Abstract
The zeolite from F class coal fly ash (FA) was prepared from alkali fused fly ash followed by hydrothermal treatment. Sodium water glass obtained from the calcined and acid activated FA and sodium aluminate were used in zeolitization. Hydrothermal reaction was performed at 90°C for 4h. The prepared zeolitic material was characterized by EDX, XRD, FT-IR and Hg-porosimetry. The concentrations of the main components SiO2, Al2O3, and Na2O in the synthesized material are: 51.45%, 30.01%, and 16.64%, respectively. The diffraction patterns show that the characteristics lines are at 14.4°, 20.5°, 25.5°, 32.7°, 39°, and 44.5° that are typical for Na-X zeolite. The FT-IR spectra show that the strongest vibration is at 960 cm-1 (T-O stretch), whereas the vibrations in the region between 600 and 750 cm-1 are related to tetrahedral atoms in zeolite structure [1, 2]. The Hg porsimetry measurements show that the porosity of obtained material is around 62% and the total pore volume is 1,10 ...cm3/g. Such characteristics of the prepared zeolitic material allow its use in various catalytic chemical processes for converting vegetable oil to biofuel including transesterification, deoxygenation, thermal cracking, catalytic cracking, and hydroprocessing.

Keywords:
Lignite fly ash / Zeolite-based meterial / Alkali fusion
Source:
Sixt Conference of the Young Chemists of Serbia, 2018, 99-
Publisher:
  • Serbian Chemical Society
Funding / projects:
  • Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes (RS-45001)

ISBN: 978-86-7132-072-6

[ Google Scholar ]
Handle
https://hdl.handle.net/21.15107/rcub_cer_2891
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/2891
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - CONF
AU  - Pavlović, Stefan
AU  - Marinković, Dalibor
AU  - Stanković, Miroslav
AU  - Milovanović, Biljana
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2891
AB  - The zeolite from F class coal fly ash (FA) was prepared from alkali fused fly ash
followed by hydrothermal treatment. Sodium water glass obtained from the calcined and
acid activated FA and sodium aluminate were used in zeolitization. Hydrothermal
reaction was performed at 90°C for 4h. The prepared zeolitic material was characterized
by EDX, XRD, FT-IR and Hg-porosimetry. The concentrations of the main components
SiO2, Al2O3, and Na2O in the synthesized material are: 51.45%, 30.01%, and 16.64%,
respectively. The diffraction patterns show that the characteristics lines are at 14.4°,
20.5°, 25.5°, 32.7°, 39°, and 44.5° that are typical for Na-X zeolite. The FT-IR spectra
show that the strongest vibration is at 960 cm-1 (T-O stretch), whereas the vibrations in
the region between 600 and 750 cm-1 are related to tetrahedral atoms in zeolite structure
[1, 2]. The Hg porsimetry measurements show that the porosity of obtained material is
around 62% and the total pore volume is 1,10 cm3/g. Such characteristics of the prepared
zeolitic material allow its use in various catalytic chemical processes for converting
vegetable oil to biofuel including transesterification, deoxygenation, thermal cracking,
catalytic cracking, and hydroprocessing.
PB  - Serbian Chemical Society
C3  - Sixt Conference of the Young Chemists of Serbia
T1  - Preparation of zeolite from coal fly ash as waste raw material
SP  - 99
UR  - https://hdl.handle.net/21.15107/rcub_cer_2891
ER  - 
@conference{
author = "Pavlović, Stefan and Marinković, Dalibor and Stanković, Miroslav and Milovanović, Biljana",
year = "2018",
abstract = "The zeolite from F class coal fly ash (FA) was prepared from alkali fused fly ash
followed by hydrothermal treatment. Sodium water glass obtained from the calcined and
acid activated FA and sodium aluminate were used in zeolitization. Hydrothermal
reaction was performed at 90°C for 4h. The prepared zeolitic material was characterized
by EDX, XRD, FT-IR and Hg-porosimetry. The concentrations of the main components
SiO2, Al2O3, and Na2O in the synthesized material are: 51.45%, 30.01%, and 16.64%,
respectively. The diffraction patterns show that the characteristics lines are at 14.4°,
20.5°, 25.5°, 32.7°, 39°, and 44.5° that are typical for Na-X zeolite. The FT-IR spectra
show that the strongest vibration is at 960 cm-1 (T-O stretch), whereas the vibrations in
the region between 600 and 750 cm-1 are related to tetrahedral atoms in zeolite structure
[1, 2]. The Hg porsimetry measurements show that the porosity of obtained material is
around 62% and the total pore volume is 1,10 cm3/g. Such characteristics of the prepared
zeolitic material allow its use in various catalytic chemical processes for converting
vegetable oil to biofuel including transesterification, deoxygenation, thermal cracking,
catalytic cracking, and hydroprocessing.",
publisher = "Serbian Chemical Society",
journal = "Sixt Conference of the Young Chemists of Serbia",
title = "Preparation of zeolite from coal fly ash as waste raw material",
pages = "99",
url = "https://hdl.handle.net/21.15107/rcub_cer_2891"
}
Pavlović, S., Marinković, D., Stanković, M.,& Milovanović, B.. (2018). Preparation of zeolite from coal fly ash as waste raw material. in Sixt Conference of the Young Chemists of Serbia
Serbian Chemical Society., 99.
https://hdl.handle.net/21.15107/rcub_cer_2891
Pavlović S, Marinković D, Stanković M, Milovanović B. Preparation of zeolite from coal fly ash as waste raw material. in Sixt Conference of the Young Chemists of Serbia. 2018;:99.
https://hdl.handle.net/21.15107/rcub_cer_2891 .
Pavlović, Stefan, Marinković, Dalibor, Stanković, Miroslav, Milovanović, Biljana, "Preparation of zeolite from coal fly ash as waste raw material" in Sixt Conference of the Young Chemists of Serbia (2018):99,
https://hdl.handle.net/21.15107/rcub_cer_2891 .

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