Study of supported Pt and PtRu catalysts in methanol and formic acid oxidation
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2004
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Trans Tech Publications Ltd, Switzerland
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The kinetics of methanol and formic acid oxidation on supported Pt and Pt2Ru3 catalysts are measured in 0.5 M H2SO4 at ambient temperature using thin-film rotating disc electrode (RDE) method. Both catalysts are characterized by HRTEM and STM techniques. Only negligible differences in the kinetics are observed between Pt and Pt2Ru3 catalysts in both reactions studied. The activity of Pt and Pt2Ru3 catalysts is much higher in formic acid than in methanol oxidation at the potentials of electrocatalytic interest.
Keywords:
Formic acid / High Surface Area Catalysts / High Resolution Transmission Electron Microscopy / Methanol / STMSource:
Progress in Advanced Materials and Processes: Materials Science Forum, 2004, 453-454, 121-126Publisher:
- Trans Tech Publications Ltd, Switzerland
Funding / projects:
- Ministry of Science, Technology and Development of the Republic of Serbia, Contract No. H1796
DOI: 10.4028/www.scientific.net/MSF.453-454.121
ISSN: 0255-5476
WoS: 000221535700022
Scopus: 2-s2.0-3142658186
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IHTMTY - JOUR AU - Tripković, Amalija AU - Popović, Ksenija AU - Lović, Jelena PY - 2004 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2885 AB - The kinetics of methanol and formic acid oxidation on supported Pt and Pt2Ru3 catalysts are measured in 0.5 M H2SO4 at ambient temperature using thin-film rotating disc electrode (RDE) method. Both catalysts are characterized by HRTEM and STM techniques. Only negligible differences in the kinetics are observed between Pt and Pt2Ru3 catalysts in both reactions studied. The activity of Pt and Pt2Ru3 catalysts is much higher in formic acid than in methanol oxidation at the potentials of electrocatalytic interest. PB - Trans Tech Publications Ltd, Switzerland T2 - Progress in Advanced Materials and Processes: Materials Science Forum T1 - Study of supported Pt and PtRu catalysts in methanol and formic acid oxidation VL - 453-454 SP - 121 EP - 126 DO - 10.4028/www.scientific.net/MSF.453-454.121 ER -
@article{ author = "Tripković, Amalija and Popović, Ksenija and Lović, Jelena", year = "2004", abstract = "The kinetics of methanol and formic acid oxidation on supported Pt and Pt2Ru3 catalysts are measured in 0.5 M H2SO4 at ambient temperature using thin-film rotating disc electrode (RDE) method. Both catalysts are characterized by HRTEM and STM techniques. Only negligible differences in the kinetics are observed between Pt and Pt2Ru3 catalysts in both reactions studied. The activity of Pt and Pt2Ru3 catalysts is much higher in formic acid than in methanol oxidation at the potentials of electrocatalytic interest.", publisher = "Trans Tech Publications Ltd, Switzerland", journal = "Progress in Advanced Materials and Processes: Materials Science Forum", title = "Study of supported Pt and PtRu catalysts in methanol and formic acid oxidation", volume = "453-454", pages = "121-126", doi = "10.4028/www.scientific.net/MSF.453-454.121" }
Tripković, A., Popović, K.,& Lović, J.. (2004). Study of supported Pt and PtRu catalysts in methanol and formic acid oxidation. in Progress in Advanced Materials and Processes: Materials Science Forum Trans Tech Publications Ltd, Switzerland., 453-454, 121-126. https://doi.org/10.4028/www.scientific.net/MSF.453-454.121
Tripković A, Popović K, Lović J. Study of supported Pt and PtRu catalysts in methanol and formic acid oxidation. in Progress in Advanced Materials and Processes: Materials Science Forum. 2004;453-454:121-126. doi:10.4028/www.scientific.net/MSF.453-454.121 .
Tripković, Amalija, Popović, Ksenija, Lović, Jelena, "Study of supported Pt and PtRu catalysts in methanol and formic acid oxidation" in Progress in Advanced Materials and Processes: Materials Science Forum, 453-454 (2004):121-126, https://doi.org/10.4028/www.scientific.net/MSF.453-454.121 . .