The influence of the oxygen-containing species on the electrooxidation of the C1 – C4 alcohols at some platinum single crystal surfaces in alkaline solution
Само за регистроване кориснике
2001
Чланак у часопису (Објављена верзија)
,
Elsevier
Метаподаци
Приказ свих података о документуАпстракт
The electrochemical oxidation of methanol, ethanol, n-propanol and n-butanol has been carried out at the Pt(111) and the stepped Pt(755) and Pt(332) surfaces in sodium hydroxide solution. Special attention was paid to the study of the oxygen-containing species generated and adsorbed during surface oxidation. The existence of reversible OHad, irreversible OHad and PtO species was suggested in the potential region relevant for the alcohol oxidation. The role of these species in the reaction was determined and a dual path mechanism was proposed for the alcohols studied.
Кључне речи:
Oxygen-containing species / Platinum single crystal surfaces / Alcohol electrooxidation / Reaction mechanismИзвор:
Electrochimica Acta, 2001, 46, 20-21, 3163-3173Издавач:
- Elsevier
Институција/група
IHTMTY - JOUR AU - Tripković, Amalija AU - Popović, Ksenija AU - Lović, Jelena PY - 2001 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2882 AB - The electrochemical oxidation of methanol, ethanol, n-propanol and n-butanol has been carried out at the Pt(111) and the stepped Pt(755) and Pt(332) surfaces in sodium hydroxide solution. Special attention was paid to the study of the oxygen-containing species generated and adsorbed during surface oxidation. The existence of reversible OHad, irreversible OHad and PtO species was suggested in the potential region relevant for the alcohol oxidation. The role of these species in the reaction was determined and a dual path mechanism was proposed for the alcohols studied. PB - Elsevier T2 - Electrochimica Acta T1 - The influence of the oxygen-containing species on the electrooxidation of the C1 – C4 alcohols at some platinum single crystal surfaces in alkaline solution VL - 46 IS - 20-21 SP - 3163 EP - 3173 DO - 10.1016/S0013-4686(01)00608-9 ER -
@article{ author = "Tripković, Amalija and Popović, Ksenija and Lović, Jelena", year = "2001", abstract = "The electrochemical oxidation of methanol, ethanol, n-propanol and n-butanol has been carried out at the Pt(111) and the stepped Pt(755) and Pt(332) surfaces in sodium hydroxide solution. Special attention was paid to the study of the oxygen-containing species generated and adsorbed during surface oxidation. The existence of reversible OHad, irreversible OHad and PtO species was suggested in the potential region relevant for the alcohol oxidation. The role of these species in the reaction was determined and a dual path mechanism was proposed for the alcohols studied.", publisher = "Elsevier", journal = "Electrochimica Acta", title = "The influence of the oxygen-containing species on the electrooxidation of the C1 – C4 alcohols at some platinum single crystal surfaces in alkaline solution", volume = "46", number = "20-21", pages = "3163-3173", doi = "10.1016/S0013-4686(01)00608-9" }
Tripković, A., Popović, K.,& Lović, J.. (2001). The influence of the oxygen-containing species on the electrooxidation of the C1 – C4 alcohols at some platinum single crystal surfaces in alkaline solution. in Electrochimica Acta Elsevier., 46(20-21), 3163-3173. https://doi.org/10.1016/S0013-4686(01)00608-9
Tripković A, Popović K, Lović J. The influence of the oxygen-containing species on the electrooxidation of the C1 – C4 alcohols at some platinum single crystal surfaces in alkaline solution. in Electrochimica Acta. 2001;46(20-21):3163-3173. doi:10.1016/S0013-4686(01)00608-9 .
Tripković, Amalija, Popović, Ksenija, Lović, Jelena, "The influence of the oxygen-containing species on the electrooxidation of the C1 – C4 alcohols at some platinum single crystal surfaces in alkaline solution" in Electrochimica Acta, 46, no. 20-21 (2001):3163-3173, https://doi.org/10.1016/S0013-4686(01)00608-9 . .