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The influence of the oxygen-containing species on the electrooxidation of the C1 – C4 alcohols at some platinum single crystal surfaces in alkaline solution
The electrochemical oxidation of methanol, ethanol, n-propanol and n-butanol has been carried out at the Pt(111) and the stepped Pt(755) and Pt(332) surfaces in sodium hydroxide solution. Special attention was paid to the study of the oxygen-containing species generated and adsorbed during surface oxidation. The existence of reversible OHad, irreversible OHad and PtO species was suggested in the potential region relevant for the alcohol oxidation. The role of these species in the reaction was determined and a dual path mechanism was proposed for the alcohols studied.
Keywords:
Oxygen-containing species / Platinum single crystal surfaces / Alcohol electrooxidation / Reaction mechanism
TY - JOUR
AU - Tripković, Amalija
AU - Popović, Ksenija
AU - Lović, Jelena
PY - 2001
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2882
AB - The electrochemical oxidation of methanol, ethanol, n-propanol and n-butanol has been carried out at the Pt(111) and the stepped Pt(755) and Pt(332) surfaces in sodium hydroxide solution. Special attention was paid to the study of the oxygen-containing species generated and adsorbed during surface oxidation. The existence of reversible OHad, irreversible OHad and PtO species was suggested in the potential region relevant for the alcohol oxidation. The role of these species in the reaction was determined and a dual path mechanism was proposed for the alcohols studied.
PB - Elsevier
T2 - Electrochimica Acta
T1 - The influence of the oxygen-containing species on the electrooxidation of the C1 – C4 alcohols at some platinum single crystal surfaces in alkaline solution
VL - 46
IS - 20-21
SP - 3163
EP - 3173
DO - 10.1016/S0013-4686(01)00608-9
ER -
@article{
author = "Tripković, Amalija and Popović, Ksenija and Lović, Jelena",
year = "2001",
abstract = "The electrochemical oxidation of methanol, ethanol, n-propanol and n-butanol has been carried out at the Pt(111) and the stepped Pt(755) and Pt(332) surfaces in sodium hydroxide solution. Special attention was paid to the study of the oxygen-containing species generated and adsorbed during surface oxidation. The existence of reversible OHad, irreversible OHad and PtO species was suggested in the potential region relevant for the alcohol oxidation. The role of these species in the reaction was determined and a dual path mechanism was proposed for the alcohols studied.",
publisher = "Elsevier",
journal = "Electrochimica Acta",
title = "The influence of the oxygen-containing species on the electrooxidation of the C1 – C4 alcohols at some platinum single crystal surfaces in alkaline solution",
volume = "46",
number = "20-21",
pages = "3163-3173",
doi = "10.1016/S0013-4686(01)00608-9"
}
Tripković, A., Popović, K.,& Lović, J.. (2001). The influence of the oxygen-containing species on the electrooxidation of the C1 – C4 alcohols at some platinum single crystal surfaces in alkaline solution. in Electrochimica Acta
Elsevier., 46(20-21), 3163-3173.
https://doi.org/10.1016/S0013-4686(01)00608-9
Tripković A, Popović K, Lović J. The influence of the oxygen-containing species on the electrooxidation of the C1 – C4 alcohols at some platinum single crystal surfaces in alkaline solution. in Electrochimica Acta. 2001;46(20-21):3163-3173.
doi:10.1016/S0013-4686(01)00608-9 .
Tripković, Amalija, Popović, Ksenija, Lović, Jelena, "The influence of the oxygen-containing species on the electrooxidation of the C1 – C4 alcohols at some platinum single crystal surfaces in alkaline solution" in Electrochimica Acta, 46, no. 20-21 (2001):3163-3173,
https://doi.org/10.1016/S0013-4686(01)00608-9 . .
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