Facile synthesis of hydrophilic polymer-capped upconverting NaYF4:Yb,Er particles

2017
Authors
Dinić, Ivana
Mančić, Lidija

Nikolić, Marko G.
Radulović, Katarina

Marinković, Bojan A.
Milošević, Olivera

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Over the last decade, solvothermal decomposition of organometallic compounds has been indicated as one of the most convenient method for the synthesis of monodisperse lanthanide doped upconverting fluorides. Due to their hydrophobic nature such particles could not be used for a conjugation of the molecular targeting agents which is necessary for optical imaging of biological tissues. In this work, hydrophilic NaYF4:Yb,Er (17 mol% Yb; 3mol% Er) nanoparticles were synthesized by facile one-pot hydrothermal synthesis performed with a help of chitosan (CS) and poly(acrylic acid) (PAA). Obtained powders were analyzed by X-ray powder diffraction (XRPD), field emission scanning electron microscopy (FESEM), Fourier transform infrared (FTIR) and photoluminescence (PL) spectroscopy. The obtained results implied that particle size, shape and surface characteristics are dependent on the polymer choice. Although both powders crystallize in the same crystal arrangement (cubic, Fm-3m) more intense re...d emission, assigned to the Er3+ 4F9/2 → 4I15/2 electronic transitions, characterize spherical NaYF4:Yb,Er@CS particles. To asses a biological safety of their use, viability of the human gingival fibroblasts (HFG) was additionally tested by a colorimetric MTT assay.
Keywords:
organometallic compounds / solvothermal decomposition / NaYF4:Yb,Er / upconversionSource:
Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017, 2017, 67-67Publisher:
- Belgrade : Serbian Ceramic Society
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IHTMTY - CONF AU - Dinić, Ivana AU - Mančić, Lidija AU - Nikolić, Marko G. AU - Radulović, Katarina AU - Marinković, Bojan A. AU - Milošević, Olivera PY - 2017 UR - http://dais.sanu.ac.rs/123456789/2361 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2849 AB - Over the last decade, solvothermal decomposition of organometallic compounds has been indicated as one of the most convenient method for the synthesis of monodisperse lanthanide doped upconverting fluorides. Due to their hydrophobic nature such particles could not be used for a conjugation of the molecular targeting agents which is necessary for optical imaging of biological tissues. In this work, hydrophilic NaYF4:Yb,Er (17 mol% Yb; 3mol% Er) nanoparticles were synthesized by facile one-pot hydrothermal synthesis performed with a help of chitosan (CS) and poly(acrylic acid) (PAA). Obtained powders were analyzed by X-ray powder diffraction (XRPD), field emission scanning electron microscopy (FESEM), Fourier transform infrared (FTIR) and photoluminescence (PL) spectroscopy. The obtained results implied that particle size, shape and surface characteristics are dependent on the polymer choice. Although both powders crystallize in the same crystal arrangement (cubic, Fm-3m) more intense red emission, assigned to the Er3+ 4F9/2 → 4I15/2 electronic transitions, characterize spherical NaYF4:Yb,Er@CS particles. To asses a biological safety of their use, viability of the human gingival fibroblasts (HFG) was additionally tested by a colorimetric MTT assay. PB - Belgrade : Serbian Ceramic Society C3 - Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017 T1 - Facile synthesis of hydrophilic polymer-capped upconverting NaYF4:Yb,Er particles SP - 67 EP - 67 UR - https://hdl.handle.net/21.15107/rcub_dais_2361 ER -
@conference{ author = "Dinić, Ivana and Mančić, Lidija and Nikolić, Marko G. and Radulović, Katarina and Marinković, Bojan A. and Milošević, Olivera", year = "2017", abstract = "Over the last decade, solvothermal decomposition of organometallic compounds has been indicated as one of the most convenient method for the synthesis of monodisperse lanthanide doped upconverting fluorides. Due to their hydrophobic nature such particles could not be used for a conjugation of the molecular targeting agents which is necessary for optical imaging of biological tissues. In this work, hydrophilic NaYF4:Yb,Er (17 mol% Yb; 3mol% Er) nanoparticles were synthesized by facile one-pot hydrothermal synthesis performed with a help of chitosan (CS) and poly(acrylic acid) (PAA). Obtained powders were analyzed by X-ray powder diffraction (XRPD), field emission scanning electron microscopy (FESEM), Fourier transform infrared (FTIR) and photoluminescence (PL) spectroscopy. The obtained results implied that particle size, shape and surface characteristics are dependent on the polymer choice. Although both powders crystallize in the same crystal arrangement (cubic, Fm-3m) more intense red emission, assigned to the Er3+ 4F9/2 → 4I15/2 electronic transitions, characterize spherical NaYF4:Yb,Er@CS particles. To asses a biological safety of their use, viability of the human gingival fibroblasts (HFG) was additionally tested by a colorimetric MTT assay.", publisher = "Belgrade : Serbian Ceramic Society", journal = "Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017", title = "Facile synthesis of hydrophilic polymer-capped upconverting NaYF4:Yb,Er particles", pages = "67-67", url = "https://hdl.handle.net/21.15107/rcub_dais_2361" }
Dinić, I., Mančić, L., Nikolić, M. G., Radulović, K., Marinković, B. A.,& Milošević, O.. (2017). Facile synthesis of hydrophilic polymer-capped upconverting NaYF4:Yb,Er particles. in Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017 Belgrade : Serbian Ceramic Society., 67-67. https://hdl.handle.net/21.15107/rcub_dais_2361
Dinić I, Mančić L, Nikolić MG, Radulović K, Marinković BA, Milošević O. Facile synthesis of hydrophilic polymer-capped upconverting NaYF4:Yb,Er particles. in Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017. 2017;:67-67. https://hdl.handle.net/21.15107/rcub_dais_2361 .
Dinić, Ivana, Mančić, Lidija, Nikolić, Marko G., Radulović, Katarina, Marinković, Bojan A., Milošević, Olivera, "Facile synthesis of hydrophilic polymer-capped upconverting NaYF4:Yb,Er particles" in Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017 (2017):67-67, https://hdl.handle.net/21.15107/rcub_dais_2361 .