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Structural effects in electrocatalysis: Formic acid oxidation at model and real Pt catalysts

Authorized Users Only
2006
Authors
Lović, Jelena
Gojković, Snežana Lj.
Popović, Ksenija
Tripković, Dušan
Tripković, Amalija
Article (Published version)
Metadata
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Abstract
Formic acid oxidation was studied at low-index Pt single crystals (model systems) as well as at the platinum catalyst supported on high area carbon (real catalyst) in HClO4. The Pt single crystals were characterized by LEED. The LEED patterns obtained after a mild heating of flame-annealed crystals have shown clean, well ordered unreconstructured surfaces. Pt-C supported catalyst was analyzed by AFM and STM in air and by XRD. AFM and STM images revealed the presence of Pt-C agglomerates of several tenth of nm consisting of Pt particles ranged from 2 nm to 6 nm. The electrocatalytic activity of these catalysts in formic acid oxidation increased in a sequence: Pt(100) < Pt(110) < Pt-C/GC < Pt(111).
Keywords:
Electrode characterization / Formic acid oxidation / Pt single crystals / Pt supported catalyst
Source:
Materials Science Forum, 2006, 518, 259-264

ISSN: 0255-5476

Scopus: 2-s2.0-37849035912
[ Google Scholar ]
1
Handle
https://hdl.handle.net/21.15107/rcub_cer_282
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/282
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Lović, Jelena
AU  - Gojković, Snežana Lj.
AU  - Popović, Ksenija
AU  - Tripković, Dušan
AU  - Tripković, Amalija
PY  - 2006
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/282
AB  - Formic acid oxidation was studied at low-index Pt single crystals (model systems) as well as at the platinum catalyst supported on high area carbon (real catalyst) in HClO4. The Pt single crystals were characterized by LEED. The LEED patterns obtained after a mild heating of flame-annealed crystals have shown clean, well ordered unreconstructured surfaces. Pt-C supported catalyst was analyzed by AFM and STM in air and by XRD. AFM and STM images revealed the presence of Pt-C agglomerates of several tenth of nm consisting of Pt particles ranged from 2 nm to 6 nm. The electrocatalytic activity of these catalysts in formic acid oxidation increased in a sequence: Pt(100) < Pt(110) < Pt-C/GC < Pt(111).
T2  - Materials Science Forum
T1  - Structural effects in electrocatalysis: Formic acid oxidation at model and real Pt catalysts
VL  - 518
SP  - 259
EP  - 264
UR  - https://hdl.handle.net/21.15107/rcub_cer_282
ER  - 
@article{
author = "Lović, Jelena and Gojković, Snežana Lj. and Popović, Ksenija and Tripković, Dušan and Tripković, Amalija",
year = "2006",
abstract = "Formic acid oxidation was studied at low-index Pt single crystals (model systems) as well as at the platinum catalyst supported on high area carbon (real catalyst) in HClO4. The Pt single crystals were characterized by LEED. The LEED patterns obtained after a mild heating of flame-annealed crystals have shown clean, well ordered unreconstructured surfaces. Pt-C supported catalyst was analyzed by AFM and STM in air and by XRD. AFM and STM images revealed the presence of Pt-C agglomerates of several tenth of nm consisting of Pt particles ranged from 2 nm to 6 nm. The electrocatalytic activity of these catalysts in formic acid oxidation increased in a sequence: Pt(100) < Pt(110) < Pt-C/GC < Pt(111).",
journal = "Materials Science Forum",
title = "Structural effects in electrocatalysis: Formic acid oxidation at model and real Pt catalysts",
volume = "518",
pages = "259-264",
url = "https://hdl.handle.net/21.15107/rcub_cer_282"
}
Lović, J., Gojković, S. Lj., Popović, K., Tripković, D.,& Tripković, A.. (2006). Structural effects in electrocatalysis: Formic acid oxidation at model and real Pt catalysts. in Materials Science Forum, 518, 259-264.
https://hdl.handle.net/21.15107/rcub_cer_282
Lović J, Gojković SL, Popović K, Tripković D, Tripković A. Structural effects in electrocatalysis: Formic acid oxidation at model and real Pt catalysts. in Materials Science Forum. 2006;518:259-264.
https://hdl.handle.net/21.15107/rcub_cer_282 .
Lović, Jelena, Gojković, Snežana Lj., Popović, Ksenija, Tripković, Dušan, Tripković, Amalija, "Structural effects in electrocatalysis: Formic acid oxidation at model and real Pt catalysts" in Materials Science Forum, 518 (2006):259-264,
https://hdl.handle.net/21.15107/rcub_cer_282 .

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