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13C N.M.R. spectra of some 5-substituted-3-isopropyl-6-methyl uracils

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1990
Authors
Jovanović, Bratislav Ž.
Tadić, Ž. D.
Vajs, Vlatka
Pešić, Mirjana B.
Article (Published version)
,
Elsevier
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Abstract
13C n.m.r. spectra of some 5-substituted-3-isopropyl-6-methyl uracils were determined in deuterated dimethyl sulfoxide (d6 - DMSO). The substituents are : H, Cl, Br, J, NO2, NH2, N(CH3)2, C6H5, C6H4-NO2-p and C6H4-NH2-p. It has been shown that 13C chemical shifts of C-5 of some of the examined compounds correlated linearly with the 13C chemical shifts of C-5 in the 5-substituted uracils as well as with the 13C chemical shifts of the substituted carbon in an analogues series of monosubstituted benzenes. The 13C chemical shifts of C-6 in some of the above compounds depend on the steric effects of the substituent in position 5 of the uracil ring. © 1990.
Source:
Journal of Molecular Structure, 1990, 219, C, 317-322
Publisher:
  • Elsevier Science Publishers B.V., Amsterdam

DOI: 10.1016/0022-2860(90)80075-U

ISSN: 0022-2860

Scopus: 2-s2.0-45149137557
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URI
http://cer.ihtm.bg.ac.rs/handle/123456789/2791
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