13C N.M.R. spectra of some 5-substituted-3-isopropyl-6-methyl uracils

Jovanović, Bratislav Ž.; Tadić, Ž. D.; Vajs, Vlatka; Pešić, Mirjana B.

doi:10.1016/0022-2860(90)80075-U

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1990

Authors

Jovanović, Bratislav Ž.
Tadić, Ž. D.
Vajs, Vlatka
Pešić, Mirjana B.

Article (Published version)

Elsevier

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Abstract

13C n.m.r. spectra of some 5-substituted-3-isopropyl-6-methyl uracils were determined in deuterated dimethyl sulfoxide (d6 - DMSO). The substituents are : H, Cl, Br, J, NO2, NH2, N(CH3)2, C6H5, C6H4-NO2-p and C6H4-NH2-p. It has been shown that 13C chemical shifts of C-5 of some of the examined compounds correlated linearly with the 13C chemical shifts of C-5 in the 5-substituted uracils as well as with the 13C chemical shifts of the substituted carbon in an analogues series of monosubstituted benzenes. The 13C chemical shifts of C-6 in some of the above compounds depend on the steric effects of the substituent in position 5 of the uracil ring. © 1990.

Source:
Journal of Molecular Structure, 1990, 219, C, 317-322

Publisher:

Elsevier Science Publishers B.V., Amsterdam

DOI: 10.1016/0022-2860(90)80075-U

ISSN: 0022-2860

TY  - JOUR
AU  - Jovanović, Bratislav Ž.
AU  - Tadić, Ž. D.
AU  - Vajs, Vlatka
AU  - Pešić, Mirjana B.
PY  - 1990
UR  - http://cer.ihtm.bg.ac.rs/handle/123456789/2791
AB  - 13C n.m.r. spectra of some 5-substituted-3-isopropyl-6-methyl uracils were determined in deuterated dimethyl sulfoxide (d6 - DMSO). The substituents are : H, Cl, Br, J, NO2, NH2, N(CH3)2, C6H5, C6H4-NO2-p and C6H4-NH2-p. It has been shown that 13C chemical shifts of C-5 of some of the examined compounds correlated linearly with the 13C chemical shifts of C-5 in the 5-substituted uracils as well as with the 13C chemical shifts of the substituted carbon in an analogues series of monosubstituted benzenes. The 13C chemical shifts of C-6 in some of the above compounds depend on the steric effects of the substituent in position 5 of the uracil ring. © 1990.
PB  - Elsevier Science Publishers B.V., Amsterdam
T2  - Journal of Molecular Structure
T1  - 13C N.M.R. spectra of some 5-substituted-3-isopropyl-6-methyl uracils
VL  - 219
IS  - C
SP  - 317
EP  - 322
DO  - 10.1016/0022-2860(90)80075-U
ER  -

@article{
author = "Jovanović, Bratislav Ž. and Tadić, Ž. D. and Vajs, Vlatka and Pešić, Mirjana B.",
year = "1990",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/2791",
abstract = "13C n.m.r. spectra of some 5-substituted-3-isopropyl-6-methyl uracils were determined in deuterated dimethyl sulfoxide (d6 - DMSO). The substituents are : H, Cl, Br, J, NO2, NH2, N(CH3)2, C6H5, C6H4-NO2-p and C6H4-NH2-p. It has been shown that 13C chemical shifts of C-5 of some of the examined compounds correlated linearly with the 13C chemical shifts of C-5 in the 5-substituted uracils as well as with the 13C chemical shifts of the substituted carbon in an analogues series of monosubstituted benzenes. The 13C chemical shifts of C-6 in some of the above compounds depend on the steric effects of the substituent in position 5 of the uracil ring. © 1990.",
publisher = "Elsevier Science Publishers B.V., Amsterdam",
journal = "Journal of Molecular Structure",
title = "13C N.M.R. spectra of some 5-substituted-3-isopropyl-6-methyl uracils",
volume = "219",
number = "C",
pages = "317-322",
doi = "10.1016/0022-2860(90)80075-U"
}

Jovanović, B. Ž., Tadić, Ž. D., Vajs, V.,& Pešić, M. B. (1990). 13C N.M.R. spectra of some 5-substituted-3-isopropyl-6-methyl uracils.
Journal of Molecular Structure
Elsevier Science Publishers B.V., Amsterdam., 219(C), 317-322.
https://doi.org/10.1016/0022-2860(90)80075-U

Jovanović BŽ, Tadić ŽD, Vajs V, Pešić MB. 13C N.M.R. spectra of some 5-substituted-3-isopropyl-6-methyl uracils. Journal of Molecular Structure. 1990;219(C):317-322

Jovanović Bratislav Ž., Tadić Ž. D., Vajs Vlatka, Pešić Mirjana B., "13C N.M.R. spectra of some 5-substituted-3-isopropyl-6-methyl uracils" Journal of Molecular Structure, 219, no. C (1990):317-322,
https://doi.org/10.1016/0022-2860(90)80075-U .