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Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings

Authorized Users Only
2009
Authors
Vulović, Bojan
Bihelović, Filip
Matović, Radomir
Saičić, Radomir N.
Article (Published version)
Metadata
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Abstract
A combination of organotransition metal catalysis and organocatalysis allows for Tsuji-Trost 5-exo- and 6-exo-cyclizations of aldehydes. This transformation can also be accomplished as a catalytic asymmetric reaction, which affords vinylcyclopentane derivatives with up to 98%ee. (C) 2009 Elsevier Ltd. All rights reserved.
Keywords:
Cyclization / Organocatalysis / Enantioselective catalysis / Cyclopentanes / Cyclohexanes / pi-Allylpalladium complexes
Source:
Tetrahedron, 2009, 65, 50, 10485-10494
Publisher:
  • Pergamon-Elsevier Science Ltd, Oxford
Projects:
  • Razvoj novih sintetičkih metoda i njihova primena u sintezi prirodnih proizvoda i biološki aktivnih jedinjenja (RS-142021)
Note:
  • Corrigendum: http://cer.ihtm.bg.ac.rs/handle/123456789/658

DOI: 10.1016/j.tet.2009.10.006

ISSN: 0040-4020

WoS: 000272089500028

Scopus: 2-s2.0-70449356896
[ Google Scholar ]
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URI
http://cherry.chem.bg.ac.rs/handle/123456789/1031
http://cer.ihtm.bg.ac.rs/handle/123456789/2774
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