Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings
Abstract
A combination of organotransition metal catalysis and organocatalysis allows for Tsuji-Trost 5-exo- and 6-exo-cyclizations of aldehydes. This transformation can also be accomplished as a catalytic asymmetric reaction, which affords vinylcyclopentane derivatives with up to 98%ee. (C) 2009 Elsevier Ltd. All rights reserved.
Keywords:
Cyclization / Organocatalysis / Enantioselective catalysis / Cyclopentanes / Cyclohexanes / pi-Allylpalladium complexesSource:
Tetrahedron, 2009, 65, 50, 10485-10494Publisher:
- Pergamon-Elsevier Science Ltd, Oxford
Projects:
Note:
- Corrigendum: http://cer.ihtm.bg.ac.rs/handle/123456789/658
DOI: 10.1016/j.tet.2009.10.006
ISSN: 0040-4020