Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings
Abstract
A combination of organotransition metal catalysis and organocatalysis allows for Tsuji-Trost 5-exo- and 6-exo-cyclizations of aldehydes. This transformation can also be accomplished as a catalytic asymmetric reaction, which affords vinylcyclopentane derivatives with up to 98%ee. (C) 2009 Elsevier Ltd. All rights reserved.
Keywords:
Cyclization / Organocatalysis / Enantioselective catalysis / Cyclopentanes / Cyclohexanes / pi-Allylpalladium complexesSource:
Tetrahedron, 2009, 65, 50, 10485-10494Publisher:
- Oxford : Pergamon-Elsevier Science Ltd
Funding / projects:
Note:
- Corrigendum: http://cer.ihtm.bg.ac.rs/handle/123456789/658
DOI: 10.1016/j.tet.2009.10.006
ISSN: 0040-4020
WoS: 000272089500028
Scopus: 2-s2.0-70449356896
URI
http://cherry.chem.bg.ac.rs/handle/123456789/1031https://cer.ihtm.bg.ac.rs/handle/123456789/2774
Collections
Institution/Community
IHTMTY - JOUR AU - Vulović, Bojan AU - Bihelović, Filip AU - Matović, Radomir AU - Saičić, Radomir N. PY - 2009 UR - http://cherry.chem.bg.ac.rs/handle/123456789/1031 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2774 AB - A combination of organotransition metal catalysis and organocatalysis allows for Tsuji-Trost 5-exo- and 6-exo-cyclizations of aldehydes. This transformation can also be accomplished as a catalytic asymmetric reaction, which affords vinylcyclopentane derivatives with up to 98%ee. (C) 2009 Elsevier Ltd. All rights reserved. PB - Oxford : Pergamon-Elsevier Science Ltd T2 - Tetrahedron T1 - Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings VL - 65 IS - 50 SP - 10485 EP - 10494 DO - 10.1016/j.tet.2009.10.006 ER -
@article{ author = "Vulović, Bojan and Bihelović, Filip and Matović, Radomir and Saičić, Radomir N.", year = "2009", abstract = "A combination of organotransition metal catalysis and organocatalysis allows for Tsuji-Trost 5-exo- and 6-exo-cyclizations of aldehydes. This transformation can also be accomplished as a catalytic asymmetric reaction, which affords vinylcyclopentane derivatives with up to 98%ee. (C) 2009 Elsevier Ltd. All rights reserved.", publisher = "Oxford : Pergamon-Elsevier Science Ltd", journal = "Tetrahedron", title = "Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings", volume = "65", number = "50", pages = "10485-10494", doi = "10.1016/j.tet.2009.10.006" }
Vulović, B., Bihelović, F., Matović, R.,& Saičić, R. N.. (2009). Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings. in Tetrahedron Oxford : Pergamon-Elsevier Science Ltd., 65(50), 10485-10494. https://doi.org/10.1016/j.tet.2009.10.006
Vulović B, Bihelović F, Matović R, Saičić RN. Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings. in Tetrahedron. 2009;65(50):10485-10494. doi:10.1016/j.tet.2009.10.006 .
Vulović, Bojan, Bihelović, Filip, Matović, Radomir, Saičić, Radomir N., "Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings" in Tetrahedron, 65, no. 50 (2009):10485-10494, https://doi.org/10.1016/j.tet.2009.10.006 . .