Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings

Vulović, Bojan; Bihelović, Filip; Matović, Radomir; Saičić, Radomir N.

doi:10.1016/j.tet.2009.10.006

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2009

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Abstract

A combination of organotransition metal catalysis and organocatalysis allows for Tsuji-Trost 5-exo- and 6-exo-cyclizations of aldehydes. This transformation can also be accomplished as a catalytic asymmetric reaction, which affords vinylcyclopentane derivatives with up to 98%ee. (C) 2009 Elsevier Ltd. All rights reserved.

Keywords:

Cyclization / Organocatalysis / Enantioselective catalysis / Cyclopentanes / Cyclohexanes / pi-Allylpalladium complexes

Source:
Tetrahedron, 2009, 65, 50, 10485-10494

Publisher:

Oxford : Pergamon-Elsevier Science Ltd

Funding / projects:

Razvoj novih sintetičkih metoda i njihova primena u sintezi prirodnih proizvoda i biološki aktivnih jedinjenja (RS-142021)

Note:

Corrigendum: http://cer.ihtm.bg.ac.rs/handle/123456789/658

DOI: 10.1016/j.tet.2009.10.006

ISSN: 0040-4020

WoS: 000272089500028

Scopus: 2-s2.0-70449356896

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TY  - JOUR
AU  - Vulović, Bojan
AU  - Bihelović, Filip
AU  - Matović, Radomir
AU  - Saičić, Radomir N.
PY  - 2009
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/1031
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2774
AB  - A combination of organotransition metal catalysis and organocatalysis allows for Tsuji-Trost 5-exo- and 6-exo-cyclizations of aldehydes. This transformation can also be accomplished as a catalytic asymmetric reaction, which affords vinylcyclopentane derivatives with up to 98%ee. (C) 2009 Elsevier Ltd. All rights reserved.
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - Tetrahedron
T1  - Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings
VL  - 65
IS  - 50
SP  - 10485
EP  - 10494
DO  - 10.1016/j.tet.2009.10.006
ER  -

@article{
author = "Vulović, Bojan and Bihelović, Filip and Matović, Radomir and Saičić, Radomir N.",
year = "2009",
abstract = "A combination of organotransition metal catalysis and organocatalysis allows for Tsuji-Trost 5-exo- and 6-exo-cyclizations of aldehydes. This transformation can also be accomplished as a catalytic asymmetric reaction, which affords vinylcyclopentane derivatives with up to 98%ee. (C) 2009 Elsevier Ltd. All rights reserved.",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "Tetrahedron",
title = "Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings",
volume = "65",
number = "50",
pages = "10485-10494",
doi = "10.1016/j.tet.2009.10.006"
}

Vulović, B., Bihelović, F., Matović, R.,& Saičić, R. N.. (2009). Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings. in Tetrahedron
Oxford : Pergamon-Elsevier Science Ltd., 65(50), 10485-10494.
https://doi.org/10.1016/j.tet.2009.10.006

Vulović B, Bihelović F, Matović R, Saičić RN. Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings. in Tetrahedron. 2009;65(50):10485-10494.
doi:10.1016/j.tet.2009.10.006 .

Vulović, Bojan, Bihelović, Filip, Matović, Radomir, Saičić, Radomir N., "Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings" in Tetrahedron, 65, no. 50 (2009):10485-10494,
https://doi.org/10.1016/j.tet.2009.10.006 . .