Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings

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2009

Authors

Vulović, Bojan

Bihelović, Filip

Matović, Radomir

Saičić, Radomir N.

Article (Published version)

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Abstract

A combination of organotransition metal catalysis and organocatalysis allows for Tsuji-Trost 5-exo- and 6-exo-cyclizations of aldehydes. This transformation can also be accomplished as a catalytic asymmetric reaction, which affords vinylcyclopentane derivatives with up to 98%ee. (C) 2009 Elsevier Ltd. All rights reserved.

Keywords:

Cyclization / Organocatalysis / Enantioselective catalysis / Cyclopentanes / Cyclohexanes / pi-Allylpalladium complexes

Source:
Tetrahedron, 2009, 65, 50, 10485-10494

Publisher:

Pergamon-Elsevier Science Ltd, Oxford

Projects:

Razvoj novih sintetičkih metoda i njihova primena u sintezi prirodnih proizvoda i biološki aktivnih jedinjenja (RS-142021)

Note:

Corrigendum: http://cer.ihtm.bg.ac.rs/handle/123456789/658

DOI: 10.1016/j.tet.2009.10.006

ISSN: 0040-4020

WoS: 000272089500028

Scopus: 2-s2.0-70449356896

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http://cherry.chem.bg.ac.rs/handle/123456789/1031
http://cer.ihtm.bg.ac.rs/handle/123456789/2774

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