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dc.creatorČeković, Živorad
dc.creatorDimitrijević, Lj.
dc.creatorDjokić, G
dc.creatorSrnić, T
dc.date.accessioned2019-04-27T16:17:53Z
dc.date.available2019-04-27T16:17:53Z
dc.date.issued1979
dc.identifier.issn0040-4020
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/2752
dc.description.abstractBy decomposition of alkyl hydroperoxides 1-8 with ferrous sulfate-cupric acetate reagent, intramolecular functionalisation of remote non-activated C atom takes place and unsaturated alcohols with double bond mainly at δ-position are obtained. The reaction proceeds involving the corresponding alkoxy radical 9 and δ-carbon radical 10 as intermediates. One-electron oxidative interception of δ-carbon radical by cupric acetate does not involve the corresponding carbonium ion; instead, the alkyl-copper intermediate 11 is formed and by elimination affords olefinic alcohols. The isotope effect for this elimination process was found to be kh/kd=6.1. © 1979.
dc.publisherPergamon Press
dc.rightsrestrictedAccess
dc.sourceTetrahedron
dc.sourceTetrahedron
dc.titleRemote functionalisation by ferrous ion-cupric ion induced decomposition of alkyl hydroperoxides
dc.typearticleen
dc.rights.licenseARR
dcterms.abstractСрнић, Т; Димитријевић, Љ.; Чековић, Ж; Дјокић, Г;
dc.rights.holderElsevier Ltd.
dc.citation.volume35
dc.citation.issue17
dc.citation.spage2021
dc.citation.epage2026
dc.identifier.doi10.1016/S0040-4020(01)88972-9
dc.identifier.scopus2-s2.0-49249150332
dc.type.versionpublishedVersion


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