Effect of codeposition of polymer on the morphology of electrodeposited copper
Само за регистроване кориснике
1979
Чланак у часопису (Објављена верзија)

Chapman and Hall Ltd. 1979
Метаподаци
Приказ свих података о документуАпстракт
Poly(4-vinyl pyridine-co-methyl methacrylate), which is soluble in water in its protonated form and insoluble as a neutral molecule, has been synthesized and introduced into an acid bath for copper deposition. Potential-sweep investigations have shown that the copolymer affects the electrocrystallization of copper on graphite by delaying nucleation even before conditions for codeposition of the polymer are reached. At overpotentials at which the diffusion limiting current of copper is reached and hydrogen evolution starts, alkalinity at the electrode surface causes precipitation of the polymer. This is found to affect the resistivity of the deposit. Electron microscopy revealed that under such conditions copper is deposited in the form of globular particles, the size of the globules being in the micron range and decreasing with increasing overpotential. © 1979 Chapman and Hall Ltd.
Кључне речи:
Polymers / Composite materials / Copper and Alloys / ElectrodepositionИзвор:
Journal of Applied Electrochemistry, 1979, 9, 2, 147-153Издавач:
- Kluwer Academic Publishers
Финансирање / пројекти:
- Research Fund of Serbia
- NSF (USA)
Институција/група
IHTMTY - JOUR AU - Despić, Aleksandar R. AU - Maglić, G S AU - Jaćović, M PY - 1979 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2749 AB - Poly(4-vinyl pyridine-co-methyl methacrylate), which is soluble in water in its protonated form and insoluble as a neutral molecule, has been synthesized and introduced into an acid bath for copper deposition. Potential-sweep investigations have shown that the copolymer affects the electrocrystallization of copper on graphite by delaying nucleation even before conditions for codeposition of the polymer are reached. At overpotentials at which the diffusion limiting current of copper is reached and hydrogen evolution starts, alkalinity at the electrode surface causes precipitation of the polymer. This is found to affect the resistivity of the deposit. Electron microscopy revealed that under such conditions copper is deposited in the form of globular particles, the size of the globules being in the micron range and decreasing with increasing overpotential. © 1979 Chapman and Hall Ltd. PB - Kluwer Academic Publishers T2 - Journal of Applied Electrochemistry T1 - Effect of codeposition of polymer on the morphology of electrodeposited copper VL - 9 IS - 2 SP - 147 EP - 153 DO - 10.1007/BF00616084 ER -
@article{ author = "Despić, Aleksandar R. and Maglić, G S and Jaćović, M", year = "1979", abstract = "Poly(4-vinyl pyridine-co-methyl methacrylate), which is soluble in water in its protonated form and insoluble as a neutral molecule, has been synthesized and introduced into an acid bath for copper deposition. Potential-sweep investigations have shown that the copolymer affects the electrocrystallization of copper on graphite by delaying nucleation even before conditions for codeposition of the polymer are reached. At overpotentials at which the diffusion limiting current of copper is reached and hydrogen evolution starts, alkalinity at the electrode surface causes precipitation of the polymer. This is found to affect the resistivity of the deposit. Electron microscopy revealed that under such conditions copper is deposited in the form of globular particles, the size of the globules being in the micron range and decreasing with increasing overpotential. © 1979 Chapman and Hall Ltd.", publisher = "Kluwer Academic Publishers", journal = "Journal of Applied Electrochemistry", title = "Effect of codeposition of polymer on the morphology of electrodeposited copper", volume = "9", number = "2", pages = "147-153", doi = "10.1007/BF00616084" }
Despić, A. R., Maglić, G. S.,& Jaćović, M.. (1979). Effect of codeposition of polymer on the morphology of electrodeposited copper. in Journal of Applied Electrochemistry Kluwer Academic Publishers., 9(2), 147-153. https://doi.org/10.1007/BF00616084
Despić AR, Maglić GS, Jaćović M. Effect of codeposition of polymer on the morphology of electrodeposited copper. in Journal of Applied Electrochemistry. 1979;9(2):147-153. doi:10.1007/BF00616084 .
Despić, Aleksandar R., Maglić, G S, Jaćović, M, "Effect of codeposition of polymer on the morphology of electrodeposited copper" in Journal of Applied Electrochemistry, 9, no. 2 (1979):147-153, https://doi.org/10.1007/BF00616084 . .