Crystal Structure and Solid State Conformation of 5‐Hydroxy‐8,9‐Dioxo‐8,9‐Seco‐α‐Cholestan‐3β‐yl Acetate
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1993
Authors
Tinant, BernardDeclercq, J P
Dabović, Milan
Krstić, Natalija
Lorenc, Ljubinka
Mihailović, Milhailo Lj.
Article (Published version)
,
Elsevier B.V.
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The molecular structure of the title compound, which might be a possible intermediate in the synthesis of 5,10:8,9‐diseco‐steroids (=steroklastanes), was determined by X‐ray analysis. Hydrogen bonding between the 5α‐hydroxyl group and the 9‐oxo function attached to the ten‐membered ring, and the presence of two conformational forms of the side‐chain in the solid state structure of 2 are established. Copyright © 1993 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
Source:
Bulletin des Sociétés Chimiques Belges, 1993, 102, 8, 539-544Publisher:
- Comltb van Beheer van het Bulletin V.Z.W.
Funding / projects:
- F.N.R.S. Belgium
- Serbian Academy of Sciences and Arts
- Serbian Research Fund
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IHTMTY - JOUR AU - Tinant, Bernard AU - Declercq, J P AU - Dabović, Milan AU - Krstić, Natalija AU - Lorenc, Ljubinka AU - Mihailović, Milhailo Lj. PY - 1993 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2704 AB - The molecular structure of the title compound, which might be a possible intermediate in the synthesis of 5,10:8,9‐diseco‐steroids (=steroklastanes), was determined by X‐ray analysis. Hydrogen bonding between the 5α‐hydroxyl group and the 9‐oxo function attached to the ten‐membered ring, and the presence of two conformational forms of the side‐chain in the solid state structure of 2 are established. Copyright © 1993 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim PB - Comltb van Beheer van het Bulletin V.Z.W. T2 - Bulletin des Sociétés Chimiques Belges T1 - Crystal Structure and Solid State Conformation of 5‐Hydroxy‐8,9‐Dioxo‐8,9‐Seco‐α‐Cholestan‐3β‐yl Acetate VL - 102 IS - 8 SP - 539 EP - 544 DO - 10.1002/bscb.19931020806 ER -
@article{ author = "Tinant, Bernard and Declercq, J P and Dabović, Milan and Krstić, Natalija and Lorenc, Ljubinka and Mihailović, Milhailo Lj.", year = "1993", abstract = "The molecular structure of the title compound, which might be a possible intermediate in the synthesis of 5,10:8,9‐diseco‐steroids (=steroklastanes), was determined by X‐ray analysis. Hydrogen bonding between the 5α‐hydroxyl group and the 9‐oxo function attached to the ten‐membered ring, and the presence of two conformational forms of the side‐chain in the solid state structure of 2 are established. Copyright © 1993 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim", publisher = "Comltb van Beheer van het Bulletin V.Z.W.", journal = "Bulletin des Sociétés Chimiques Belges", title = "Crystal Structure and Solid State Conformation of 5‐Hydroxy‐8,9‐Dioxo‐8,9‐Seco‐α‐Cholestan‐3β‐yl Acetate", volume = "102", number = "8", pages = "539-544", doi = "10.1002/bscb.19931020806" }
Tinant, B., Declercq, J. P., Dabović, M., Krstić, N., Lorenc, L.,& Mihailović, M. Lj.. (1993). Crystal Structure and Solid State Conformation of 5‐Hydroxy‐8,9‐Dioxo‐8,9‐Seco‐α‐Cholestan‐3β‐yl Acetate. in Bulletin des Sociétés Chimiques Belges Comltb van Beheer van het Bulletin V.Z.W.., 102(8), 539-544. https://doi.org/10.1002/bscb.19931020806
Tinant B, Declercq JP, Dabović M, Krstić N, Lorenc L, Mihailović ML. Crystal Structure and Solid State Conformation of 5‐Hydroxy‐8,9‐Dioxo‐8,9‐Seco‐α‐Cholestan‐3β‐yl Acetate. in Bulletin des Sociétés Chimiques Belges. 1993;102(8):539-544. doi:10.1002/bscb.19931020806 .
Tinant, Bernard, Declercq, J P, Dabović, Milan, Krstić, Natalija, Lorenc, Ljubinka, Mihailović, Milhailo Lj., "Crystal Structure and Solid State Conformation of 5‐Hydroxy‐8,9‐Dioxo‐8,9‐Seco‐α‐Cholestan‐3β‐yl Acetate" in Bulletin des Sociétés Chimiques Belges, 102, no. 8 (1993):539-544, https://doi.org/10.1002/bscb.19931020806 . .