The effect of hydrogen codeposition on the morphology of copper electrodeposits. 1. The concept of effective overpotential
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2006
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The effect of hydrogen codeposition on the morphology of copper electrodeposits was studied. The dependences of the overall current and the volume of evolved hydrogen on the quantity of electricity used were plotted and the average current efficiencies of the evolved hydrogen were derived from them. The morphologies of copper electrodeposits were correlated with the hydrogen evolution rates. It was shown that dendrites are the main characteristic of deposits obtained at overpotentials belonging to the limiting diffusion current density plateau, at which the hydrogen evolution rate is low. At larger overpotentials the dominant form become craters in the honeycomb-like electrodeposits due to the intensive hydrogen codeposition.
Ključne reči:
electrodeposition / copper / hydrogen evolution / morphology / SEMIzvor:
Journal of Electroanalytical Chemistry, 2006, 588, 1, 88-98Izdavač:
- Elsevier
DOI: 10.1016/j.jelechem.2005.12.006
ISSN: 1572-6657
WoS: 000235264000010
Scopus: 2-s2.0-31344474887
Institucija/grupa
IHTMTY - JOUR AU - Nikolić, Nebojša D. AU - Popov, Konstantin I. AU - Pavlovic, LJ AU - Pavlović, Miomir PY - 2006 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/268 AB - The effect of hydrogen codeposition on the morphology of copper electrodeposits was studied. The dependences of the overall current and the volume of evolved hydrogen on the quantity of electricity used were plotted and the average current efficiencies of the evolved hydrogen were derived from them. The morphologies of copper electrodeposits were correlated with the hydrogen evolution rates. It was shown that dendrites are the main characteristic of deposits obtained at overpotentials belonging to the limiting diffusion current density plateau, at which the hydrogen evolution rate is low. At larger overpotentials the dominant form become craters in the honeycomb-like electrodeposits due to the intensive hydrogen codeposition. PB - Elsevier T2 - Journal of Electroanalytical Chemistry T1 - The effect of hydrogen codeposition on the morphology of copper electrodeposits. 1. The concept of effective overpotential VL - 588 IS - 1 SP - 88 EP - 98 DO - 10.1016/j.jelechem.2005.12.006 ER -
@article{ author = "Nikolić, Nebojša D. and Popov, Konstantin I. and Pavlovic, LJ and Pavlović, Miomir", year = "2006", abstract = "The effect of hydrogen codeposition on the morphology of copper electrodeposits was studied. The dependences of the overall current and the volume of evolved hydrogen on the quantity of electricity used were plotted and the average current efficiencies of the evolved hydrogen were derived from them. The morphologies of copper electrodeposits were correlated with the hydrogen evolution rates. It was shown that dendrites are the main characteristic of deposits obtained at overpotentials belonging to the limiting diffusion current density plateau, at which the hydrogen evolution rate is low. At larger overpotentials the dominant form become craters in the honeycomb-like electrodeposits due to the intensive hydrogen codeposition.", publisher = "Elsevier", journal = "Journal of Electroanalytical Chemistry", title = "The effect of hydrogen codeposition on the morphology of copper electrodeposits. 1. The concept of effective overpotential", volume = "588", number = "1", pages = "88-98", doi = "10.1016/j.jelechem.2005.12.006" }
Nikolić, N. D., Popov, K. I., Pavlovic, L.,& Pavlović, M.. (2006). The effect of hydrogen codeposition on the morphology of copper electrodeposits. 1. The concept of effective overpotential. in Journal of Electroanalytical Chemistry Elsevier., 588(1), 88-98. https://doi.org/10.1016/j.jelechem.2005.12.006
Nikolić ND, Popov KI, Pavlovic L, Pavlović M. The effect of hydrogen codeposition on the morphology of copper electrodeposits. 1. The concept of effective overpotential. in Journal of Electroanalytical Chemistry. 2006;588(1):88-98. doi:10.1016/j.jelechem.2005.12.006 .
Nikolić, Nebojša D., Popov, Konstantin I., Pavlovic, LJ, Pavlović, Miomir, "The effect of hydrogen codeposition on the morphology of copper electrodeposits. 1. The concept of effective overpotential" in Journal of Electroanalytical Chemistry, 588, no. 1 (2006):88-98, https://doi.org/10.1016/j.jelechem.2005.12.006 . .