Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose
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2019
Authors
Jugović, Dragana
Mitrić, Miodrag

Milović, Miloš

Ivanovski, Valentin N.
Škapin, Srečo Davor
Dojčinović, Biljana

Uskoković, Dragan

Article (Published version)

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A new method involving the homogeneous dispersion of precursor compounds inside a methylcellulose matrix is used for the synthesis of a composite powder of Li 2 FeP 2 O 7 and carbon. The properties of carbon-containing and carbon-free powders are studied by X-ray powder diffraction (XRD) including Rietveld refinement, Mössbauer spectroscopy, Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), galvanostatic cycling, and electrochemical impedance spectroscopy (EIS). The structure of both powders is refined in a monoclinic framework (space group P2 1 /c). The structural refinement and Mössbauer spectroscopy reveal different degrees of partial occupancy of mixed-occupied sites by lithium. Electrochemical measurements show that the in situ formation of carbon improves capacity (90% of 1-electron theoretical capacity) through decreased charge-transfer resistance. © 2019 Elsevier B.V.
Keywords:
crystal structure / electrochemical reactions / energy storage materials / Mössbauer spectroscopy / X-ray diffractionSource:
Journal of Alloys and Compounds, 2019, 786, 912-919Publisher:
- Elsevier
Funding / projects:
- Molecular designing of nanoparticles with controlled morphological and physicochemical characteristics and functional materials based on them (RS-45004)
- Magnetic and radionuclide labeled nanostructured materials for medical applications (RS-45015)
- Investigation of intermetallics and semiconductors and possible application in renewable energy sources (RS-171001)
Note:
- The peer-reviewed version: https://cer.ihtm.bg.ac.rs/handle/123456789/3330
DOI: 10.1016/j.jallcom.2019.01.392
ISSN: 0925-8388
WoS: 000461778600108
Scopus: 2-s2.0-85061204040
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IHTMTY - JOUR AU - Jugović, Dragana AU - Mitrić, Miodrag AU - Milović, Miloš AU - Ivanovski, Valentin N. AU - Škapin, Srečo Davor AU - Dojčinović, Biljana AU - Uskoković, Dragan PY - 2019 UR - http://dais.sanu.ac.rs/123456789/4937 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2649 AB - A new method involving the homogeneous dispersion of precursor compounds inside a methylcellulose matrix is used for the synthesis of a composite powder of Li 2 FeP 2 O 7 and carbon. The properties of carbon-containing and carbon-free powders are studied by X-ray powder diffraction (XRD) including Rietveld refinement, Mössbauer spectroscopy, Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), galvanostatic cycling, and electrochemical impedance spectroscopy (EIS). The structure of both powders is refined in a monoclinic framework (space group P2 1 /c). The structural refinement and Mössbauer spectroscopy reveal different degrees of partial occupancy of mixed-occupied sites by lithium. Electrochemical measurements show that the in situ formation of carbon improves capacity (90% of 1-electron theoretical capacity) through decreased charge-transfer resistance. © 2019 Elsevier B.V. PB - Elsevier T2 - Journal of Alloys and Compounds T1 - Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose VL - 786 SP - 912 EP - 919 DO - 10.1016/j.jallcom.2019.01.392 ER -
@article{ author = "Jugović, Dragana and Mitrić, Miodrag and Milović, Miloš and Ivanovski, Valentin N. and Škapin, Srečo Davor and Dojčinović, Biljana and Uskoković, Dragan", year = "2019", abstract = "A new method involving the homogeneous dispersion of precursor compounds inside a methylcellulose matrix is used for the synthesis of a composite powder of Li 2 FeP 2 O 7 and carbon. The properties of carbon-containing and carbon-free powders are studied by X-ray powder diffraction (XRD) including Rietveld refinement, Mössbauer spectroscopy, Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), galvanostatic cycling, and electrochemical impedance spectroscopy (EIS). The structure of both powders is refined in a monoclinic framework (space group P2 1 /c). The structural refinement and Mössbauer spectroscopy reveal different degrees of partial occupancy of mixed-occupied sites by lithium. Electrochemical measurements show that the in situ formation of carbon improves capacity (90% of 1-electron theoretical capacity) through decreased charge-transfer resistance. © 2019 Elsevier B.V.", publisher = "Elsevier", journal = "Journal of Alloys and Compounds", title = "Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose", volume = "786", pages = "912-919", doi = "10.1016/j.jallcom.2019.01.392" }
Jugović, D., Mitrić, M., Milović, M., Ivanovski, V. N., Škapin, S. D., Dojčinović, B.,& Uskoković, D.. (2019). Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose. in Journal of Alloys and Compounds Elsevier., 786, 912-919. https://doi.org/10.1016/j.jallcom.2019.01.392
Jugović D, Mitrić M, Milović M, Ivanovski VN, Škapin SD, Dojčinović B, Uskoković D. Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose. in Journal of Alloys and Compounds. 2019;786:912-919. doi:10.1016/j.jallcom.2019.01.392 .
Jugović, Dragana, Mitrić, Miodrag, Milović, Miloš, Ivanovski, Valentin N., Škapin, Srečo Davor, Dojčinović, Biljana, Uskoković, Dragan, "Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose" in Journal of Alloys and Compounds, 786 (2019):912-919, https://doi.org/10.1016/j.jallcom.2019.01.392 . .