Electrochemical behavior of polyaniline in chloride/citrate electrolyte

2011
Authors
Jugović, Branimir
Gvozdenović, Milica M.

Trišović, Tomislav

Stevanović, Jasmina

Grgur, Branimir N.

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Polyaniline electrode, was obtained by electrochemical polymerization at constant current density of 2.0 mA cm-2 from aqueous solution of 1.0 mol dm-3 HCl containing 0.25 mol dm-3 aniline. Electrochemical characterization of the polyaniline electrode in chloride and chloride/citrate electrolyte, for different anodic potential limits, was performed using cyclic voltammetry and galvanostatic measurements. It was observed that for anodic potential 0.32 V, higher electrode capacity in chloride/citrate was obtained. For anodic potential limit of 0.50 V, faster decrease of theelectrode capacity in chloride/citrate electrolyte was also observed. It was suggested that influence of both chloride and citrate anions has to be taken into account.
Keywords:
polyaniline / chloride and citrate electrolyte / polymers / electrochemical techniques / electrochemical propertiesSource:
Proceedings of the 38th International Conference of Slovak Society of Chemical Engineering, 2011, 963-967Publisher:
- Tatranské Matliare : Slovak Society of Chemical Engineering
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IHTMTY - CONF AU - Jugović, Branimir AU - Gvozdenović, Milica M. AU - Trišović, Tomislav AU - Stevanović, Jasmina AU - Grgur, Branimir N. PY - 2011 UR - http://dais.sanu.ac.rs/123456789/548 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2616 AB - Polyaniline electrode, was obtained by electrochemical polymerization at constant current density of 2.0 mA cm-2 from aqueous solution of 1.0 mol dm-3 HCl containing 0.25 mol dm-3 aniline. Electrochemical characterization of the polyaniline electrode in chloride and chloride/citrate electrolyte, for different anodic potential limits, was performed using cyclic voltammetry and galvanostatic measurements. It was observed that for anodic potential 0.32 V, higher electrode capacity in chloride/citrate was obtained. For anodic potential limit of 0.50 V, faster decrease of theelectrode capacity in chloride/citrate electrolyte was also observed. It was suggested that influence of both chloride and citrate anions has to be taken into account. PB - Tatranské Matliare : Slovak Society of Chemical Engineering C3 - Proceedings of the 38th International Conference of Slovak Society of Chemical Engineering T1 - Electrochemical behavior of polyaniline in chloride/citrate electrolyte SP - 963 EP - 967 UR - https://hdl.handle.net/21.15107/rcub_dais_548 ER -
@conference{ author = "Jugović, Branimir and Gvozdenović, Milica M. and Trišović, Tomislav and Stevanović, Jasmina and Grgur, Branimir N.", year = "2011", abstract = "Polyaniline electrode, was obtained by electrochemical polymerization at constant current density of 2.0 mA cm-2 from aqueous solution of 1.0 mol dm-3 HCl containing 0.25 mol dm-3 aniline. Electrochemical characterization of the polyaniline electrode in chloride and chloride/citrate electrolyte, for different anodic potential limits, was performed using cyclic voltammetry and galvanostatic measurements. It was observed that for anodic potential 0.32 V, higher electrode capacity in chloride/citrate was obtained. For anodic potential limit of 0.50 V, faster decrease of theelectrode capacity in chloride/citrate electrolyte was also observed. It was suggested that influence of both chloride and citrate anions has to be taken into account.", publisher = "Tatranské Matliare : Slovak Society of Chemical Engineering", journal = "Proceedings of the 38th International Conference of Slovak Society of Chemical Engineering", title = "Electrochemical behavior of polyaniline in chloride/citrate electrolyte", pages = "963-967", url = "https://hdl.handle.net/21.15107/rcub_dais_548" }
Jugović, B., Gvozdenović, M. M., Trišović, T., Stevanović, J.,& Grgur, B. N.. (2011). Electrochemical behavior of polyaniline in chloride/citrate electrolyte. in Proceedings of the 38th International Conference of Slovak Society of Chemical Engineering Tatranské Matliare : Slovak Society of Chemical Engineering., 963-967. https://hdl.handle.net/21.15107/rcub_dais_548
Jugović B, Gvozdenović MM, Trišović T, Stevanović J, Grgur BN. Electrochemical behavior of polyaniline in chloride/citrate electrolyte. in Proceedings of the 38th International Conference of Slovak Society of Chemical Engineering. 2011;:963-967. https://hdl.handle.net/21.15107/rcub_dais_548 .
Jugović, Branimir, Gvozdenović, Milica M., Trišović, Tomislav, Stevanović, Jasmina, Grgur, Branimir N., "Electrochemical behavior of polyaniline in chloride/citrate electrolyte" in Proceedings of the 38th International Conference of Slovak Society of Chemical Engineering (2011):963-967, https://hdl.handle.net/21.15107/rcub_dais_548 .