Improved electrolyte for zinc-polyaniline batteries
Authors
Jugović, Branimir
Trišović, Tomislav

Stevanović, Jasmina

Gvozdenović, Milica M.

Grgur, Branimir N.

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Electrochemical behavior of zinc and polyaniline (PANI) electrode polymerized from 0.1 M HCl and 0.1 M aniline on graphite electrode, in 0.2 M ZnCl2 and 0.50 M NH4Cl (chloride electrolyte) and with addition of 0.33 M Na-citrate (chloride/citrate electrolyte) were investigated. In the chloride/citrate comparing with chloride containing electrolyte for the zinc electrode negative shift of the open circuit potential of 150 mV, decreases of exchange current density for more than order of magnitude and increase of cathodic Tafel slope, due to the zinc ions complexation, were observed. In citrate/chloride electrolyte zinc dendrite formation were completely suppressed. PANI electrodes show better discharge characteristic in chloride/citrate electrolyte with determined maximum discharge capacity of 164 mAh g-1.
Keywords:
polyaniline / PANI / citrate / batteriesSource:
Proceedings of the 37th International Conference of Slovak Society of Chemical Engineering, 2010, 866-870Publisher:
- Tatranské Matliare : Slovak Society of Chemical Engineering
Funding / projects:
- Modifikacija metalnih i nemetalnih materijala elektroprovodnim polimerima za primenu u novim tehnologijama (RS-142044)
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IHTMTY - CONF AU - Jugović, Branimir AU - Trišović, Tomislav AU - Stevanović, Jasmina AU - Gvozdenović, Milica M. AU - Grgur, Branimir N. PY - 2010 UR - http://dais.sanu.ac.rs/123456789/3498 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2613 AB - Electrochemical behavior of zinc and polyaniline (PANI) electrode polymerized from 0.1 M HCl and 0.1 M aniline on graphite electrode, in 0.2 M ZnCl2 and 0.50 M NH4Cl (chloride electrolyte) and with addition of 0.33 M Na-citrate (chloride/citrate electrolyte) were investigated. In the chloride/citrate comparing with chloride containing electrolyte for the zinc electrode negative shift of the open circuit potential of 150 mV, decreases of exchange current density for more than order of magnitude and increase of cathodic Tafel slope, due to the zinc ions complexation, were observed. In citrate/chloride electrolyte zinc dendrite formation were completely suppressed. PANI electrodes show better discharge characteristic in chloride/citrate electrolyte with determined maximum discharge capacity of 164 mAh g-1. PB - Tatranské Matliare : Slovak Society of Chemical Engineering C3 - Proceedings of the 37th International Conference of Slovak Society of Chemical Engineering T1 - Improved electrolyte for zinc-polyaniline batteries SP - 866 EP - 870 UR - https://hdl.handle.net/21.15107/rcub_dais_3498 ER -
@conference{ author = "Jugović, Branimir and Trišović, Tomislav and Stevanović, Jasmina and Gvozdenović, Milica M. and Grgur, Branimir N.", year = "2010", abstract = "Electrochemical behavior of zinc and polyaniline (PANI) electrode polymerized from 0.1 M HCl and 0.1 M aniline on graphite electrode, in 0.2 M ZnCl2 and 0.50 M NH4Cl (chloride electrolyte) and with addition of 0.33 M Na-citrate (chloride/citrate electrolyte) were investigated. In the chloride/citrate comparing with chloride containing electrolyte for the zinc electrode negative shift of the open circuit potential of 150 mV, decreases of exchange current density for more than order of magnitude and increase of cathodic Tafel slope, due to the zinc ions complexation, were observed. In citrate/chloride electrolyte zinc dendrite formation were completely suppressed. PANI electrodes show better discharge characteristic in chloride/citrate electrolyte with determined maximum discharge capacity of 164 mAh g-1.", publisher = "Tatranské Matliare : Slovak Society of Chemical Engineering", journal = "Proceedings of the 37th International Conference of Slovak Society of Chemical Engineering", title = "Improved electrolyte for zinc-polyaniline batteries", pages = "866-870", url = "https://hdl.handle.net/21.15107/rcub_dais_3498" }
Jugović, B., Trišović, T., Stevanović, J., Gvozdenović, M. M.,& Grgur, B. N.. (2010). Improved electrolyte for zinc-polyaniline batteries. in Proceedings of the 37th International Conference of Slovak Society of Chemical Engineering Tatranské Matliare : Slovak Society of Chemical Engineering., 866-870. https://hdl.handle.net/21.15107/rcub_dais_3498
Jugović B, Trišović T, Stevanović J, Gvozdenović MM, Grgur BN. Improved electrolyte for zinc-polyaniline batteries. in Proceedings of the 37th International Conference of Slovak Society of Chemical Engineering. 2010;:866-870. https://hdl.handle.net/21.15107/rcub_dais_3498 .
Jugović, Branimir, Trišović, Tomislav, Stevanović, Jasmina, Gvozdenović, Milica M., Grgur, Branimir N., "Improved electrolyte for zinc-polyaniline batteries" in Proceedings of the 37th International Conference of Slovak Society of Chemical Engineering (2010):866-870, https://hdl.handle.net/21.15107/rcub_dais_3498 .