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Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia

Authorized Users Only
2019
Authors
Ognjanović, Miloš
Stanković, Dalibor
Ming, Y.
Zhang, H.
Jančar, Boštjan
Dojčinović, Biljana
Prijović, Ž.
Antić, Bratislav
Article (Published version)
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Abstract
In a new approach based on a two-step procedure, co-precipitation method followed by hydrothermal treatment in a microwave field, Zn-substituted Fe3O4 nanoparticles (ZnxFe3-xO4) were synthesized. Results of XRD, FT–IR and TEM analysis clearly demonstrate that nanoparticles were single phase, crystallizing in the spinel structure type (S.G. Fd3¯m) with crystallite size in the range of 2–20 nm, which strongly depends on Zn concentration. The produced nanoparticles were used for fabrication of modified carbon paste electrodes as a novel system for electrochemical non-enzymatic glucose detection. It was found that the increase of zinc concentration up to the value of x = 0.56 (Zn0.56Fe2.44O4) of as-prepared nanoparticles was followed with an increase of a performance of the modified carbon paste electrode toward glucose detection. Linear working range from 0.1 to 2 mM was obtained with detection limit of 0.03 mM, and with fast response time (<3 s). Proposed sensor was successfully appli...ed for the determination of glucose level in real samples with satisfactory recovery. The synthesized zinc-ferrite samples were also tested as potential heating agents in magnetic hyperthermia. The heating ability (SAR value) increases with x value, reaching maximum for x = 0.37. This is correlated with changes of particle size and magnetic characteristics which strongly depend on Zn concentration.

Keywords:
Carbon electrodes / Glucose sensor / Hyperthermia / MW hydrothermal synthesis / Structural characterization
Source:
Journal of Alloys and Compounds, 2019, 454-462
Publisher:
  • Elsevier Ltd
Projects:
  • Strengthening of the MagBioVin Research and Innovation Team for Development of Novel Approaches for Tumour Therapy based on Nanostructured Materials (EU-621375)
  • Ministry of Education, Science and Technological Development of the Republic of Serbia through the Eureka Project, E!9982

DOI: 10.1016/j.jallcom.2018.10.369

ISSN: 0925-8388

WoS: 000454856800055

Scopus: 2-s2.0-85056178941
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URI
http://cer.ihtm.bg.ac.rs/handle/123456789/2501
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