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dc.creatorRomanović, Mima
dc.creatorMilenković, Milica
dc.creatorPevec, Andrej
dc.creatorTurel, Iztok
dc.creatorSpasojević, Vojislav
dc.creatorGrubišić, Sonja
dc.creatorRadanović, Dušanka
dc.creatorAnđelković, Katarina
dc.creatorČobeljić, Božidar
dc.date.accessioned2019-01-30T18:01:20Z
dc.date.available2019-01-30T18:01:20Z
dc.date.issued2018
dc.identifier.issn0277-5387
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/2476
dc.description.abstractA tridentate NNO condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent (HLC1) in the presence of azide ions coordinates with cobalt(II) giving mononuclear azido Co(II) complex [CoHL (N-3)(3)](1) as a main product and dinuclear end-on azido bridged Co(II) complex [Co2L2(mu-(1,1)-N-3)(2)(N-3)(2)] (2) in traces. Crystal structures of both complexes were determined. Variable temperature magnetic susceptibility measurement studies of complex I showed that Co(II) cation is in the low-spin state with t(2g)(6)e(g)(1) (S = 1/2) configuration. DFT-BS calculations for complex 2 anticipated ferromagnetic type interaction between paramagnetic centers (J = 53 cm(-1)).en
dc.publisherPergamon-Elsevier Science Ltd, Oxford
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172055/RS//
dc.relationCOST Action ECOSTBio (Explicit Control Over Spin-States in Technology and Biochemistry) including a STSM grant [CM1305, COST-STSM-CM1305-25068]
dc.relationSlovenian Research Agency [P-0175]
dc.rightsrestrictedAccess
dc.sourcePolyhedron
dc.subjectHydrazonesen
dc.subjectCobalt(II) azido complexesen
dc.subjectSingle crystal structuresen
dc.subjectDFT calculationsen
dc.subjectMagnetic propertiesen
dc.titleCrystal structures, magnetic properties and DFT study of cobalt(II) azido complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagenten
dc.typearticle
dc.rights.licenseARR
dcterms.abstractГрубишић, Соња; Спасојевиц, Војислав; Миленковиц, Милица Р.; Радановић, Душанка; Aнђелковиц, Катарина; Романовиц, Мима Ц.; Певец, Aндреј; Цобељиц, Бозидар; Турел, Изток;
dc.citation.volume139
dc.citation.spage142
dc.citation.epage147
dc.citation.other139: 142-147
dc.citation.rankM22
dc.description.otherThe peer-reviewed version: [http://cer.ihtm.bg.ac.rs/handle/123456789/3006]
dc.identifier.doi10.1016/j.poly.2017.10.018
dc.identifier.rcubrcub_2474
dc.identifier.scopus2-s2.0-85032457069
dc.identifier.wos000419409900016
dc.type.versionpublishedVersion


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