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dc.creatorMacesic, Stevan
dc.creatorČupić, Željko
dc.creatorIvanović-Šašić, Ana
dc.creatorAnić, Slobodan
dc.creatorRadenkovic, Mirjana
dc.creatorPejić, Nataša
dc.creatorKolar-Anić, Ljiljana
dc.date.accessioned2019-01-30T18:00:58Z
dc.date.available2019-01-30T18:00:58Z
dc.date.issued2018
dc.identifier.issn1878-5190
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/2461
dc.description.abstractIn this paper, we intend to show the importance of the bifurcation analysis in understanding of an oscillatory process. Hence, we use the bifurcation diagram of the Bray-Liebhafsky reaction performed in continuous well-stirred tank reactor under controlled temperature variations for the determination of the activation energies as well as rate constants of particular steps appearing in the kinetic model of oscillatory reaction mechanism. This approach has led us to the development of general procedure for treatment of experimentally obtained data and extracting kinetic parameters from them, which was very important considering that some rate constants of the already proposed model could not be determined experimentally and have to be fitted (or guessed). Also, the proposed approach has the potential to inspire the refinement of already proposed models and the development of a new one that will be able to reproduce experimentally obtained system's dynamical features more successfully. In particular, the dynamic states of the Bray-Liebhafsky oscillatory reaction have been analyzed experimentally and numerically using already proposed model together with qualitative and quantitative analysis of bifurcation diagrams in both cases.en
dc.publisherSpringer Netherlands
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172015/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45001/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/43009/RS//
dc.rightsrestrictedAccess
dc.sourceReaction Kinetics, Mechanisms and Catalysis
dc.subjectNonlinear dynamicsen
dc.subjectBifurcation analysisen
dc.subjectBray-Liebhafsky oscillatory reactionen
dc.subjectModellingen
dc.subjectCSTRen
dc.titleBifurcation analysis: a tool for determining model parameters of the considered processen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractЧупић, Жељко; Раденковиц, Мирјана; Aниц, Слободан; Ивановић-Шашић, Aна; Пејиц, Натаса; Колар-Aниц, Љиљана; Мацесиц, Стеван;
dc.citation.volume123
dc.citation.issue1
dc.citation.spage31
dc.citation.epage45
dc.citation.other123(1): 31-45
dc.citation.rankM23
dc.identifier.doi10.1007/s11144-017-1324-6
dc.identifier.rcubConv_3857
dc.identifier.scopus2-s2.0-85035793444
dc.identifier.wos000419514200003
dc.type.versionpublishedVersion


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