Comparison of liquid and liquid-gas phase plasma reactors for discoloration of azo dyes: Analysis of degradation products

Kozakova, Zdenka; Klimova, Edita J.; Obradović, Bratislav M.; Dojčinović, Biljana; Krcma, Frantisek; Kuraica, Milorad M.; Olejnickova, Zuzana; Sykora, Richard; Vavrova, Milada

doi:10.1002/ppap.201700178

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2018

Authors

Kozakova, Zdenka
Klimova, Edita J.
Obradović, Bratislav M.

Dojčinović, Biljana

Krcma, Frantisek
Kuraica, Milorad M.

Olejnickova, Zuzana
Sykora, Richard
Vavrova, Milada

Article (Published version)

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Abstract

Three plasma systems are used for decomposition of two organic textile dyes. The highest discoloration efficiency over 90% is reached in the water falling film DBD when maximal energy of 270 and 450kJL(-1) is applied into Reactive Yellow 125 and Direct Red 79 dye solutions, respectively. Decomposition of the dye molecules is confirmed by concentration decreases in dye chromatograms. Similar degradation products are identified in the positive diaphragm discharge and water falling film DBD. In the negative diaphragm discharge, different products are formed due to electrochemical reactions on the anode. Substitution of halogens, hydrogen addition on the azo group and the cleavage of the azo group itself are the main mechanisms contributing to the destruction of the dye molecule in the compared plasma systems.

Keywords:

azo textile dyes / DC discharges / dielectric barrier discharges / discoloration / HPLC-MS analyses

Source:
Plasma Processes and Polymers, 2018, 15, 6

Publisher:

Wiley-V C H Verlag Gmbh, Weinheim

Projects:

Diagnostics and Optimization of Plasma Sources Important for Applications (RS-171034)
Application of advanced oxidation processes and nanostructured oxide materials for the removal of pollutants from the environment, development and optimisation of instrumental techniques for efficiency monitoring (RS-172030)
Czech Ministry of Education, Youth and Sports - COST LC14014

DOI: 10.1002/ppap.201700178

ISSN: 1612-8850

WoS: 000436407300001

Scopus: 2-s2.0-85043369443

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TY  - JOUR
AU  - Kozakova, Zdenka
AU  - Klimova, Edita J.
AU  - Obradović, Bratislav M.
AU  - Dojčinović, Biljana
AU  - Krcma, Frantisek
AU  - Kuraica, Milorad M.
AU  - Olejnickova, Zuzana
AU  - Sykora, Richard
AU  - Vavrova, Milada
PY  - 2018
UR  - http://cer.ihtm.bg.ac.rs/handle/123456789/2437
AB  - Three plasma systems are used for decomposition of two organic textile dyes. The highest discoloration efficiency over 90% is reached in the water falling film DBD when maximal energy of 270 and 450kJL(-1) is applied into Reactive Yellow 125 and Direct Red 79 dye solutions, respectively. Decomposition of the dye molecules is confirmed by concentration decreases in dye chromatograms. Similar degradation products are identified in the positive diaphragm discharge and water falling film DBD. In the negative diaphragm discharge, different products are formed due to electrochemical reactions on the anode. Substitution of halogens, hydrogen addition on the azo group and the cleavage of the azo group itself are the main mechanisms contributing to the destruction of the dye molecule in the compared plasma systems.
PB  - Wiley-V C H Verlag Gmbh, Weinheim
T2  - Plasma Processes and Polymers
T1  - Comparison of liquid and liquid-gas phase plasma reactors for discoloration of azo dyes: Analysis of degradation products
VL  - 15
IS  - 6
DO  - 10.1002/ppap.201700178
ER  -

@article{
author = "Kozakova, Zdenka and Klimova, Edita J. and Obradović, Bratislav M. and Dojčinović, Biljana and Krcma, Frantisek and Kuraica, Milorad M. and Olejnickova, Zuzana and Sykora, Richard and Vavrova, Milada",
year = "2018",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/2437",
abstract = "Three plasma systems are used for decomposition of two organic textile dyes. The highest discoloration efficiency over 90% is reached in the water falling film DBD when maximal energy of 270 and 450kJL(-1) is applied into Reactive Yellow 125 and Direct Red 79 dye solutions, respectively. Decomposition of the dye molecules is confirmed by concentration decreases in dye chromatograms. Similar degradation products are identified in the positive diaphragm discharge and water falling film DBD. In the negative diaphragm discharge, different products are formed due to electrochemical reactions on the anode. Substitution of halogens, hydrogen addition on the azo group and the cleavage of the azo group itself are the main mechanisms contributing to the destruction of the dye molecule in the compared plasma systems.",
publisher = "Wiley-V C H Verlag Gmbh, Weinheim",
journal = "Plasma Processes and Polymers",
title = "Comparison of liquid and liquid-gas phase plasma reactors for discoloration of azo dyes: Analysis of degradation products",
volume = "15",
number = "6",
doi = "10.1002/ppap.201700178"
}

Kozakova Z, Klimova EJ, Obradović BM, Dojčinović B, Krcma F, Kuraica MM, Olejnickova Z, Sykora R, Vavrova M. Comparison of liquid and liquid-gas phase plasma reactors for discoloration of azo dyes: Analysis of degradation products. Plasma Processes and Polymers. 2018;15(6)

Kozakova, Z., Klimova, E. J., Obradović, B. M., Dojčinović, B., Krcma, F., Kuraica, M. M., Olejnickova, Z., Sykora, R.,& Vavrova, M. (2018). Comparison of liquid and liquid-gas phase plasma reactors for discoloration of azo dyes: Analysis of degradation products.
Plasma Processes and PolymersWiley-V C H Verlag Gmbh, Weinheim., 15(6).
https://doi.org/10.1002/ppap.201700178

Kozakova Zdenka, Klimova Edita J., Obradović Bratislav M., Dojčinović Biljana, Krcma Frantisek, Kuraica Milorad M., Olejnickova Zuzana, Sykora Richard, Vavrova Milada, "Comparison of liquid and liquid-gas phase plasma reactors for discoloration of azo dyes: Analysis of degradation products" 15, no. 6 (2018),
https://doi.org/10.1002/ppap.201700178 .