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dc.creatorČupić, Željko
dc.creatorMacesic, Stevan
dc.creatorNovakovic, Katarina
dc.creatorAnić, Slobodan
dc.creatorKolar-Anić, Ljiljana
dc.date.accessioned2019-01-30T18:00:20Z
dc.date.available2019-08-17
dc.date.issued2018
dc.identifier.issn1054-1500
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/2431
dc.description.abstractStoichiometric Network Analysis (SNA) is a powerful method that can be used to examine instabilities in modelling a broad range of reaction systems without knowing the explicit values of reaction rate constants. Due to a lack of understanding, SNA is rarely used and its full potential is not yet fulfilled. Using the oscillatory carbonylation of a polymeric substrate [poly(ethylene glycol) methyl ether acetylene] as a case study, in this work, we consider two mathematical methods for the application of SNA to the reaction models when conservation constraints between species have an important role. The first method takes conservation constraints into account and uses only independent intermediate species, while the second method applies to the full set of intermediate species, without the separation of independent and dependent variables. Both methods are used for examination of steady state stability by means of a characteristic polynomial and related Jacobian matrix. It was shown that both methods give the same results. Therefore, as the second method is simpler, we suggest it as a more straightforward method for the applications. Published by AIP Publishing.en
dc.publisherAmer Inst Physics, Melville
dc.relationUK Engineering and Physical Sciences Research Council (EPSRC) - EP/N033655/1
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172015/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45001/RS//
dc.rightsembargoedAccess
dc.sourceChaos
dc.titleStoichiometric network analysis of a reaction system with conservation constraintsen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractНоваковиц, Катарина; Колар-Aниц, Љиљана; Чупић, Жељко; Мацесиц, Стеван; Aниц, Слободан;
dc.citation.volume28
dc.citation.issue8
dc.citation.other28(8):
dc.citation.rankaM21
dc.identifier.pmid30180608
dc.identifier.doi10.1063/1.5026791
dc.identifier.rcubConv_3987
dc.identifier.fulltexthttp://cer.ihtm.bg.ac.rs/bitstream/id/14431/chaos.pdf
dc.identifier.scopus2-s2.0-85052325290
dc.identifier.wos000443760700019
dc.type.versionpublishedVersion


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