Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard's T hydrazone complex

2018
Аутори
Čobeljić, Božidar
Pevec, Andrej

Jagličić, Zvonko

Milenković, Milica R.

Turel, Iztok

Radanović, Dušanka

Milenković, Marina

Anđelković, Katarina

Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The isothiocyanato Fe(III) complex with (E)-N, N, N-trimethyl-2-oxo- 2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium was synthesized and characterized by elemental analysis, IR spectroscopy and X-ray analysis. The octahedral geometry of the Fe(III) complex consists of the deprotonated form of the hydrazone ligand coordinated through the pyridine nitrogen, azomethine nitrogen and carbonyl oxygen atoms with three isothiocyanato ligands in the remaining coordination places. The measured effective magnetic moment for Fe(III) complex corresponds to high spin Fe(III) ion. The hydrazone ligand and its Fe(III) complex showed lower activity against the tested microbial strains than standard antimicrobial drugs.
Кључне речи:
hydrazone / X-ray structure / magnetic properties / pseudohalidesИзвор:
Journal of the Serbian Chemical Society, 2018, 83, 12, 1327-1337Издавач:
- Serbian Chemical Society
Финансирање / пројекти:
- Интеракције природних производа, њихових деривата и комплексних једињења са протеинима и нуклеинским киселинама (RS-172055)
- Slovenian Research Agency - P-0175
- Slovenian Research Agency - P2-0348
DOI: 10.2298/JSC180828079C
ISSN: 0352-5139
WoS: 000454508900004
Scopus: 2-s2.0-85059303962
Институција/група
IHTMTY - JOUR AU - Čobeljić, Božidar AU - Pevec, Andrej AU - Jagličić, Zvonko AU - Milenković, Milica R. AU - Turel, Iztok AU - Radanović, Dušanka AU - Milenković, Marina AU - Anđelković, Katarina PY - 2018 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2410 AB - The isothiocyanato Fe(III) complex with (E)-N, N, N-trimethyl-2-oxo- 2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium was synthesized and characterized by elemental analysis, IR spectroscopy and X-ray analysis. The octahedral geometry of the Fe(III) complex consists of the deprotonated form of the hydrazone ligand coordinated through the pyridine nitrogen, azomethine nitrogen and carbonyl oxygen atoms with three isothiocyanato ligands in the remaining coordination places. The measured effective magnetic moment for Fe(III) complex corresponds to high spin Fe(III) ion. The hydrazone ligand and its Fe(III) complex showed lower activity against the tested microbial strains than standard antimicrobial drugs. PB - Serbian Chemical Society T2 - Journal of the Serbian Chemical Society T1 - Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard's T hydrazone complex VL - 83 IS - 12 SP - 1327 EP - 1337 DO - 10.2298/JSC180828079C ER -
@article{ author = "Čobeljić, Božidar and Pevec, Andrej and Jagličić, Zvonko and Milenković, Milica R. and Turel, Iztok and Radanović, Dušanka and Milenković, Marina and Anđelković, Katarina", year = "2018", abstract = "The isothiocyanato Fe(III) complex with (E)-N, N, N-trimethyl-2-oxo- 2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium was synthesized and characterized by elemental analysis, IR spectroscopy and X-ray analysis. The octahedral geometry of the Fe(III) complex consists of the deprotonated form of the hydrazone ligand coordinated through the pyridine nitrogen, azomethine nitrogen and carbonyl oxygen atoms with three isothiocyanato ligands in the remaining coordination places. The measured effective magnetic moment for Fe(III) complex corresponds to high spin Fe(III) ion. The hydrazone ligand and its Fe(III) complex showed lower activity against the tested microbial strains than standard antimicrobial drugs.", publisher = "Serbian Chemical Society", journal = "Journal of the Serbian Chemical Society", title = "Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard's T hydrazone complex", volume = "83", number = "12", pages = "1327-1337", doi = "10.2298/JSC180828079C" }
Čobeljić, B., Pevec, A., Jagličić, Z., Milenković, M. R., Turel, I., Radanović, D., Milenković, M.,& Anđelković, K.. (2018). Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard's T hydrazone complex. in Journal of the Serbian Chemical Society Serbian Chemical Society., 83(12), 1327-1337. https://doi.org/10.2298/JSC180828079C
Čobeljić B, Pevec A, Jagličić Z, Milenković MR, Turel I, Radanović D, Milenković M, Anđelković K. Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard's T hydrazone complex. in Journal of the Serbian Chemical Society. 2018;83(12):1327-1337. doi:10.2298/JSC180828079C .
Čobeljić, Božidar, Pevec, Andrej, Jagličić, Zvonko, Milenković, Milica R., Turel, Iztok, Radanović, Dušanka, Milenković, Marina, Anđelković, Katarina, "Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard's T hydrazone complex" in Journal of the Serbian Chemical Society, 83, no. 12 (2018):1327-1337, https://doi.org/10.2298/JSC180828079C . .