The isothiocyanato Fe(III) complex with (E)-N, N, N-trimethyl-2-oxo- 2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium was synthesized and characterized by elemental analysis, IR spectroscopy and X-ray analysis. The octahedral geometry of the Fe(III) complex consists of the deprotonated form of the hydrazone ligand coordinated through the pyridine nitrogen, azomethine nitrogen and carbonyl oxygen atoms with three isothiocyanato ligands in the remaining coordination places. The measured effective magnetic moment for Fe(III) complex corresponds to high spin Fe(III) ion. The hydrazone ligand and its Fe(III) complex showed lower activity against the tested microbial strains than standard antimicrobial drugs.
Keywords:
hydrazone / X-ray structure / magnetic properties / pseudohalides
Source:
Journal of the Serbian Chemical Society, 2018, 83, 12, 1327-1337
TY - JOUR
AU - Čobeljić, Božidar
AU - Pevec, Andrej
AU - Jagličić, Zvonko
AU - Milenković, Milica R.
AU - Turel, Iztok
AU - Radanović, Dušanka
AU - Milenković, Marina
AU - Anđelković, Katarina
PY - 2018
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2410
AB - The isothiocyanato Fe(III) complex with (E)-N, N, N-trimethyl-2-oxo- 2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium was synthesized and characterized by elemental analysis, IR spectroscopy and X-ray analysis. The octahedral geometry of the Fe(III) complex consists of the deprotonated form of the hydrazone ligand coordinated through the pyridine nitrogen, azomethine nitrogen and carbonyl oxygen atoms with three isothiocyanato ligands in the remaining coordination places. The measured effective magnetic moment for Fe(III) complex corresponds to high spin Fe(III) ion. The hydrazone ligand and its Fe(III) complex showed lower activity against the tested microbial strains than standard antimicrobial drugs.
PB - Serbian Chemical Society
T2 - Journal of the Serbian Chemical Society
T1 - Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard's T hydrazone complex
VL - 83
IS - 12
SP - 1327
EP - 1337
DO - 10.2298/JSC180828079C
ER -
@article{
author = "Čobeljić, Božidar and Pevec, Andrej and Jagličić, Zvonko and Milenković, Milica R. and Turel, Iztok and Radanović, Dušanka and Milenković, Marina and Anđelković, Katarina",
year = "2018",
abstract = "The isothiocyanato Fe(III) complex with (E)-N, N, N-trimethyl-2-oxo- 2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium was synthesized and characterized by elemental analysis, IR spectroscopy and X-ray analysis. The octahedral geometry of the Fe(III) complex consists of the deprotonated form of the hydrazone ligand coordinated through the pyridine nitrogen, azomethine nitrogen and carbonyl oxygen atoms with three isothiocyanato ligands in the remaining coordination places. The measured effective magnetic moment for Fe(III) complex corresponds to high spin Fe(III) ion. The hydrazone ligand and its Fe(III) complex showed lower activity against the tested microbial strains than standard antimicrobial drugs.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard's T hydrazone complex",
volume = "83",
number = "12",
pages = "1327-1337",
doi = "10.2298/JSC180828079C"
}
Čobeljić, B., Pevec, A., Jagličić, Z., Milenković, M. R., Turel, I., Radanović, D., Milenković, M.,& Anđelković, K.. (2018). Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard's T hydrazone complex. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 83(12), 1327-1337.
https://doi.org/10.2298/JSC180828079C
Čobeljić B, Pevec A, Jagličić Z, Milenković MR, Turel I, Radanović D, Milenković M, Anđelković K. Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard's T hydrazone complex. in Journal of the Serbian Chemical Society. 2018;83(12):1327-1337.
doi:10.2298/JSC180828079C .
Čobeljić, Božidar, Pevec, Andrej, Jagličić, Zvonko, Milenković, Milica R., Turel, Iztok, Radanović, Dušanka, Milenković, Marina, Anđelković, Katarina, "Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard's T hydrazone complex" in Journal of the Serbian Chemical Society, 83, no. 12 (2018):1327-1337,
https://doi.org/10.2298/JSC180828079C . .
