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Correlation between crystal structure and morphology of potentiostatically electrodeposited silver dendritic nanostructures

Authorized Users Only
2018
Authors
Avramović, Ljiljana
Ivanović, Evica
Maksimović, Vesna M.
Pavlović, Miroslav M.
Vuković, Marina
Stevanović, Jasmina
Nikolić, Nebojša D.
Article (Published version)
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Abstract
Silver dendritic nanonstructures obtained by the potentiostatic electrolysis from different electrolytes at different overpotentials were characterized by the scanning electron microscopy (SEM) technique and X-ray diffraction analysis of the produced particles. The needle-like and fern-like dendrites were formed from the nitrate electrolyte at overpotentials inside and outside plateaus of the limiting diffusion current density, respectively. The three-dimensional pine-like dendrites constructed from approximately spherical grains were formed from the ammonium electrolyte at overpotentials both inside and outside plateaus of the limiting diffusion current density. The morphology of silver dendrites was correlated with their crystal structure at the semi quantiative level. The change of crystal orientation from the strong (111) preferred orientation for the needle-like dendrites to almost randomly orientied spherical grains in the pine-like dendrites obtained at the overpotential outside... the plateau of the limiting diffusion current density was observed. This trend in change of crystal orientation and morphology of Ag nanostructures was accompanied by considerable increase of the specific surface area (SSA) of the produced powders. The average crystallite sizes were in the range of 38-50 nm, proving nanostructural character of the formed Ag particles.

Keywords:
electrodeposition / silver / dendrites / SEM / XRD
Source:
Transactions of Nonferrous Metals Society of China, 2018, 28, 9, 1903-1912
Publisher:
  • Elsevier
Funding / projects:
  • Electrochemical synthesis and characterization of nanostructured functional materials for application in new technologies (RS-172046)

DOI: 10.1016/S1003-6326(18)64835-6

ISSN: 1003-6326

WoS: 000446870200024

Scopus: 2-s2.0-85054468310
[ Google Scholar ]
13
10
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/2372
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Avramović, Ljiljana
AU  - Ivanović, Evica
AU  - Maksimović, Vesna M.
AU  - Pavlović, Miroslav M.
AU  - Vuković, Marina
AU  - Stevanović, Jasmina
AU  - Nikolić, Nebojša D.
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2372
AB  - Silver dendritic nanonstructures obtained by the potentiostatic electrolysis from different electrolytes at different overpotentials were characterized by the scanning electron microscopy (SEM) technique and X-ray diffraction analysis of the produced particles. The needle-like and fern-like dendrites were formed from the nitrate electrolyte at overpotentials inside and outside plateaus of the limiting diffusion current density, respectively. The three-dimensional pine-like dendrites constructed from approximately spherical grains were formed from the ammonium electrolyte at overpotentials both inside and outside plateaus of the limiting diffusion current density. The morphology of silver dendrites was correlated with their crystal structure at the semi quantiative level. The change of crystal orientation from the strong (111) preferred orientation for the needle-like dendrites to almost randomly orientied spherical grains in the pine-like dendrites obtained at the overpotential outside the plateau of the limiting diffusion current density was observed. This trend in change of crystal orientation and morphology of Ag nanostructures was accompanied by considerable increase of the specific surface area (SSA) of the produced powders. The average crystallite sizes were in the range of 38-50 nm, proving nanostructural character of the formed Ag particles.
PB  - Elsevier
T2  - Transactions of Nonferrous Metals Society of China
T1  - Correlation between crystal structure and morphology of potentiostatically electrodeposited silver dendritic nanostructures
VL  - 28
IS  - 9
SP  - 1903
EP  - 1912
DO  - 10.1016/S1003-6326(18)64835-6
UR  - Conv_4002
ER  - 
@article{
author = "Avramović, Ljiljana and Ivanović, Evica and Maksimović, Vesna M. and Pavlović, Miroslav M. and Vuković, Marina and Stevanović, Jasmina and Nikolić, Nebojša D.",
year = "2018",
abstract = "Silver dendritic nanonstructures obtained by the potentiostatic electrolysis from different electrolytes at different overpotentials were characterized by the scanning electron microscopy (SEM) technique and X-ray diffraction analysis of the produced particles. The needle-like and fern-like dendrites were formed from the nitrate electrolyte at overpotentials inside and outside plateaus of the limiting diffusion current density, respectively. The three-dimensional pine-like dendrites constructed from approximately spherical grains were formed from the ammonium electrolyte at overpotentials both inside and outside plateaus of the limiting diffusion current density. The morphology of silver dendrites was correlated with their crystal structure at the semi quantiative level. The change of crystal orientation from the strong (111) preferred orientation for the needle-like dendrites to almost randomly orientied spherical grains in the pine-like dendrites obtained at the overpotential outside the plateau of the limiting diffusion current density was observed. This trend in change of crystal orientation and morphology of Ag nanostructures was accompanied by considerable increase of the specific surface area (SSA) of the produced powders. The average crystallite sizes were in the range of 38-50 nm, proving nanostructural character of the formed Ag particles.",
publisher = "Elsevier",
journal = "Transactions of Nonferrous Metals Society of China",
title = "Correlation between crystal structure and morphology of potentiostatically electrodeposited silver dendritic nanostructures",
volume = "28",
number = "9",
pages = "1903-1912",
doi = "10.1016/S1003-6326(18)64835-6",
url = "Conv_4002"
}
Avramović, L., Ivanović, E., Maksimović, V. M., Pavlović, M. M., Vuković, M., Stevanović, J.,& Nikolić, N. D.. (2018). Correlation between crystal structure and morphology of potentiostatically electrodeposited silver dendritic nanostructures. in Transactions of Nonferrous Metals Society of China
Elsevier., 28(9), 1903-1912.
https://doi.org/10.1016/S1003-6326(18)64835-6
Conv_4002
Avramović L, Ivanović E, Maksimović VM, Pavlović MM, Vuković M, Stevanović J, Nikolić ND. Correlation between crystal structure and morphology of potentiostatically electrodeposited silver dendritic nanostructures. in Transactions of Nonferrous Metals Society of China. 2018;28(9):1903-1912.
doi:10.1016/S1003-6326(18)64835-6
Conv_4002 .
Avramović, Ljiljana, Ivanović, Evica, Maksimović, Vesna M., Pavlović, Miroslav M., Vuković, Marina, Stevanović, Jasmina, Nikolić, Nebojša D., "Correlation between crystal structure and morphology of potentiostatically electrodeposited silver dendritic nanostructures" in Transactions of Nonferrous Metals Society of China, 28, no. 9 (2018):1903-1912,
https://doi.org/10.1016/S1003-6326(18)64835-6 .,
Conv_4002 .

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