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Experimental and Theoretical Identification of the Origin of Magnetic Anisotropy in Intermediate Spin Iron(III) Complexes
dc.creator | Wang, Lianke | |
dc.creator | Zlatar, Matija | |
dc.creator | Vlahović, Filip | |
dc.creator | Demeshko, Serhiy | |
dc.creator | Philouze, Christian | |
dc.creator | Molton, Florian | |
dc.creator | Gennari, Marcello | |
dc.creator | Meyer, Franc | |
dc.creator | Duboc, Carole | |
dc.creator | Gruden, Maja | |
dc.date.accessioned | 2019-01-30T17:58:21Z | |
dc.date.available | 2019-01-30T17:58:21Z | |
dc.date.issued | 2018 | |
dc.identifier.issn | 0947-6539 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/2335 | |
dc.description.abstract | The complexes [(FeLX)-X-N2S2] [in which L-N2S2 = 2,2'-(2,2'-bipryridine-6,6'-diyl)bis(1,1'-diphenylethanethiolate) and X = Cl, Br and I], characterized crystallographically earlier and here (Fe(L)Br), reveal a square pyramidal coordinated Fe-III ion. Unusually, all three complexes have intermediate spin ground states. Susceptibility measurements, powder cw X- and Q-band EPR spectra, and zero-field powder Mossbauer spectra show that all complexes display distinct magnetic anisotropy, which has been rationalized by DFT calculations. | en |
dc.publisher | Wiley-V C H Verlag Gmbh, Weinheim | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172035/RS// | |
dc.relation | COST Action ECOSTBio (Explicit Control Over Spin-States in Technology and Biochemistry) including a STSM grant [CM1305, COST-STSM-CM1305-25068] | |
dc.relation | China Scholarship Council | |
dc.relation | Deutsche Forschungsgemeinschaft (collaborative DFG/ANR project) [Me1313/14-1] | |
dc.relation | Serbian-French collaboration project [451-03-39/2016-09/06, 36224WB, ANR-11-LABX-003] | |
dc.rights | openAccess | |
dc.source | Chemistry-A European Journal | |
dc.subject | density functional calculations | en |
dc.subject | electronic structure | en |
dc.subject | intermediate spin state | en |
dc.subject | iron(III) | en |
dc.subject | magnetic properties | en |
dc.title | Experimental and Theoretical Identification of the Origin of Magnetic Anisotropy in Intermediate Spin Iron(III) Complexes | en |
dc.type | article | |
dc.rights.license | ARR | |
dcterms.abstract | Молтон, Флориан; Геннари, Марцелло; Дубоц, Цароле; Груден, Маја; Меyер, Франц; Влаховиц, Филип; Демесхко, Серхиy; Wанг, Лианке; Златар, Матија; Пхилоузе, Цхристиан; | |
dc.citation.volume | 24 | |
dc.citation.issue | 20 | |
dc.citation.spage | 5091 | |
dc.citation.epage | 5094 | |
dc.citation.other | 24(20): 5091-5094 | |
dc.citation.rank | M21 | |
dc.identifier.pmid | 29447424 | |
dc.identifier.doi | 10.1002/chem.201705989 | |
dc.identifier.fulltext | https://cer.ihtm.bg.ac.rs//bitstream/id/8724/2333.pdf | |
dc.identifier.scopus | 2-s2.0-85042682197 | |
dc.identifier.wos | 000429703700018 | |
dc.type.version | publishedVersion |