Preparation and Properties of Short Oil Alkyd Resin/TiO2 Nanocomposites Based on Surface Modified TiO2 Nanoparticles
Samo za registrovane korisnike
2018
Autori
Radoman, Tijana S.Džunuzović, Jasna
Spasojević, Pavle
Marinović-Cincović, Milena
Jeremić, Katarina B.
Popović, Ivanka G.
Džunuzović, Enis S.
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Alkyd resin/TiO2 nanocomposites (NC) were prepared from short oil alkyd resin and TiO2 nanoparticles (NPs) surface modified with in situ formed imine ligand, based on 3,4-dihydroxybenzaldehyde and oleylamine, or with three gallic acid esters. The short oil alkyd resin was synthesized from sunflower oil, phthalic anhydride, and trimethylolpropane. Unmodified and surface modified TiO2 NPs were examined by transmission electron microscopy. Rheological investigation revealed that prepared dispersions have higher dynamic viscosity than pure alkyd resin. Using different characterization methods it was obtained that NCs have similar thermooxidative stability as alkyd resin, lower glass transition temperature, better barrier properties, enhanced hardness, better chemical resistance, and lower adhesion to the metal, except in the case of NC prepared using TiO2 NPs surface modified with imine, which exhibited better adhesion to the metal than pure alkyd resin.
Izvor:
Polymer Composites, 2018, 39, 5, 1488-1499Izdavač:
- Hoboken : Wiley
Finansiranje / projekti:
- Sinteza i karakterizacija novih funkcionalnih polimera i polimernih nanokompozita (RS-MESTD-Basic Research (BR or ON)-172062)
DOI: 10.1002/pc.24089
ISSN: 0272-8397
WoS: 000436299100010
Scopus: 2-s2.0-84973352568
Institucija/grupa
IHTMTY - JOUR AU - Radoman, Tijana S. AU - Džunuzović, Jasna AU - Spasojević, Pavle AU - Marinović-Cincović, Milena AU - Jeremić, Katarina B. AU - Popović, Ivanka G. AU - Džunuzović, Enis S. PY - 2018 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2331 AB - Alkyd resin/TiO2 nanocomposites (NC) were prepared from short oil alkyd resin and TiO2 nanoparticles (NPs) surface modified with in situ formed imine ligand, based on 3,4-dihydroxybenzaldehyde and oleylamine, or with three gallic acid esters. The short oil alkyd resin was synthesized from sunflower oil, phthalic anhydride, and trimethylolpropane. Unmodified and surface modified TiO2 NPs were examined by transmission electron microscopy. Rheological investigation revealed that prepared dispersions have higher dynamic viscosity than pure alkyd resin. Using different characterization methods it was obtained that NCs have similar thermooxidative stability as alkyd resin, lower glass transition temperature, better barrier properties, enhanced hardness, better chemical resistance, and lower adhesion to the metal, except in the case of NC prepared using TiO2 NPs surface modified with imine, which exhibited better adhesion to the metal than pure alkyd resin. PB - Hoboken : Wiley T2 - Polymer Composites T1 - Preparation and Properties of Short Oil Alkyd Resin/TiO2 Nanocomposites Based on Surface Modified TiO2 Nanoparticles VL - 39 IS - 5 SP - 1488 EP - 1499 DO - 10.1002/pc.24089 ER -
@article{ author = "Radoman, Tijana S. and Džunuzović, Jasna and Spasojević, Pavle and Marinović-Cincović, Milena and Jeremić, Katarina B. and Popović, Ivanka G. and Džunuzović, Enis S.", year = "2018", abstract = "Alkyd resin/TiO2 nanocomposites (NC) were prepared from short oil alkyd resin and TiO2 nanoparticles (NPs) surface modified with in situ formed imine ligand, based on 3,4-dihydroxybenzaldehyde and oleylamine, or with three gallic acid esters. The short oil alkyd resin was synthesized from sunflower oil, phthalic anhydride, and trimethylolpropane. Unmodified and surface modified TiO2 NPs were examined by transmission electron microscopy. Rheological investigation revealed that prepared dispersions have higher dynamic viscosity than pure alkyd resin. Using different characterization methods it was obtained that NCs have similar thermooxidative stability as alkyd resin, lower glass transition temperature, better barrier properties, enhanced hardness, better chemical resistance, and lower adhesion to the metal, except in the case of NC prepared using TiO2 NPs surface modified with imine, which exhibited better adhesion to the metal than pure alkyd resin.", publisher = "Hoboken : Wiley", journal = "Polymer Composites", title = "Preparation and Properties of Short Oil Alkyd Resin/TiO2 Nanocomposites Based on Surface Modified TiO2 Nanoparticles", volume = "39", number = "5", pages = "1488-1499", doi = "10.1002/pc.24089" }
Radoman, T. S., Džunuzović, J., Spasojević, P., Marinović-Cincović, M., Jeremić, K. B., Popović, I. G.,& Džunuzović, E. S.. (2018). Preparation and Properties of Short Oil Alkyd Resin/TiO2 Nanocomposites Based on Surface Modified TiO2 Nanoparticles. in Polymer Composites Hoboken : Wiley., 39(5), 1488-1499. https://doi.org/10.1002/pc.24089
Radoman TS, Džunuzović J, Spasojević P, Marinović-Cincović M, Jeremić KB, Popović IG, Džunuzović ES. Preparation and Properties of Short Oil Alkyd Resin/TiO2 Nanocomposites Based on Surface Modified TiO2 Nanoparticles. in Polymer Composites. 2018;39(5):1488-1499. doi:10.1002/pc.24089 .
Radoman, Tijana S., Džunuzović, Jasna, Spasojević, Pavle, Marinović-Cincović, Milena, Jeremić, Katarina B., Popović, Ivanka G., Džunuzović, Enis S., "Preparation and Properties of Short Oil Alkyd Resin/TiO2 Nanocomposites Based on Surface Modified TiO2 Nanoparticles" in Polymer Composites, 39, no. 5 (2018):1488-1499, https://doi.org/10.1002/pc.24089 . .