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dc.creatorSmiljanić, Milutin
dc.creatorRakočević, Zlatko Lj.
dc.creatorŠtrbac, Svetlana
dc.date.accessioned2019-01-30T17:58:14Z
dc.date.available2019-01-30T17:58:14Z
dc.date.issued2018
dc.identifier.issn0360-3199
dc.identifier.urihttps://cer.ihtm.bg.ac.rs/handle/123456789/2330
dc.description.abstractHydrogen evolution reaction (HER) was investigated in alkaline solution on tri-metallic Rh"Pd/Pt(poly) electrode, prepared by spontaneous deposition of Rh on top of Pd/Pt(poly) electrode with intermediate Pd coverage of 35%. Characterization of tri-metallic catalyst was performed by electrochemical methods of cyclic voltammetry and CO stripping voltammetry, while its activity for HER was tested by linear sweep voltammetry in 0.1 M NaOH. Rh"Pd/Pt(poly) catalyst has shown superior catalytic activity for HER with respect to initial Pt(poly) and both corresponding bimetallic Pd/Pt(poly) and Rh/Pt(poly) electrodes. This was explained by a strong synergistic electronic interaction between three metals in close contact induced at a number of different active sites across the surface of tri-metallic catalyst, which results with lowering of the binding energy for the adsorption of H intermediate species.en
dc.publisherOxford : Pergamon-Elsevier Science Ltd
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45005/RS//
dc.rightsrestrictedAccess
dc.sourceInternational Journal of Hydrogen Energy
dc.subjectPlatinumen
dc.subjectPalladiumen
dc.subjectRhodiumen
dc.subjectTri-metallic electrodeen
dc.subjectHydrogen evolutionen
dc.titleElectrocatalysis of hydrogen evolution reaction on tri-metallic Rh@Pd/Pt(poly) electrodeen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractСмиљанић, Милутин; Ракочевић, Златко Љ.; Штрбац, Светлана;
dc.citation.volume43
dc.citation.issue5
dc.citation.spage2763
dc.citation.epage2771
dc.citation.other43(5): 2763-2771
dc.citation.rankM21
dc.identifier.doi10.1016/j.ijhydene.2017.12.112
dc.identifier.rcubConv_3877
dc.identifier.scopus2-s2.0-85040351742
dc.identifier.wos000425563200020
dc.type.versionpublishedVersion


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