Voltammetric and Quantum Investigation of Selected Succinimides
2018
Autori
Božić, BojanLović, Jelena
Banjac, Nebojša R.
Vitnik, Željko
Vitnik, Vesna
Mijin, Dušan
Ušćumlić, Gordana
Avramov Ivić, Milka
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
A series of succinimide derivatives were studied using the cyclic and square wave voltammetry. Density function theory was used in order to determinate which of the structural parameters influence the electrochemical activity. The quantum chemical calculations of the investigated succinimides were linked with the experimental electrochemical data and used to propose the oxidation mechanism. The most active among studied succinimides is 1,3-diphenylsuccinimide. The results obtained from the cyclic and square wave voltammetry and quantum chemical calculations indicate that the investigated compounds undergo oxidation by irreversible, diffusion controlled process including transfer of 1e(-) and 1 proton. The voltammetric and DFT results signify that the mechanism of electrochemical oxidation of all compounds involve the conversion of carbonyl-methyne-phenyl segment or methylene group in free radical. This conversion proceeds by the loss of one proton one electron process.
Ključne reči:
Diphenylsuccinimide / Threephenylsuccinimide / Voltammetry / Quantum chemical calculations / Reaction mechanismsIzvor:
International Journal of Electrochemical Science, 2018, 13, 5, 4285-4297Izdavač:
- Esg, Belgrade
Finansiranje / projekti:
- Proučavanje sinteze, strukture i aktivnosti organskih jedinjenja prirodnog i sintetskog porekla (RS-MESTD-Basic Research (BR or ON)-172013)
- Racionalni dizajn i sinteza biološki aktivnih i koordinacionih jedinjenja i funkcionalnih materijala, relevantnih u (bio)nanotehnologiji (RS-MESTD-Basic Research (BR or ON)-172035)
- Nov pristup dizajniranju materijala za konverziju i skladištenje energije (RS-MESTD-Basic Research (BR or ON)-172060)
DOI: 10.20964/2018.05.54
ISSN: 1452-3981
WoS: 000436257800020
Scopus: 2-s2.0-85046802281
Institucija/grupa
IHTMTY - JOUR AU - Božić, Bojan AU - Lović, Jelena AU - Banjac, Nebojša R. AU - Vitnik, Željko AU - Vitnik, Vesna AU - Mijin, Dušan AU - Ušćumlić, Gordana AU - Avramov Ivić, Milka PY - 2018 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2300 AB - A series of succinimide derivatives were studied using the cyclic and square wave voltammetry. Density function theory was used in order to determinate which of the structural parameters influence the electrochemical activity. The quantum chemical calculations of the investigated succinimides were linked with the experimental electrochemical data and used to propose the oxidation mechanism. The most active among studied succinimides is 1,3-diphenylsuccinimide. The results obtained from the cyclic and square wave voltammetry and quantum chemical calculations indicate that the investigated compounds undergo oxidation by irreversible, diffusion controlled process including transfer of 1e(-) and 1 proton. The voltammetric and DFT results signify that the mechanism of electrochemical oxidation of all compounds involve the conversion of carbonyl-methyne-phenyl segment or methylene group in free radical. This conversion proceeds by the loss of one proton one electron process. PB - Esg, Belgrade T2 - International Journal of Electrochemical Science T1 - Voltammetric and Quantum Investigation of Selected Succinimides VL - 13 IS - 5 SP - 4285 EP - 4297 DO - 10.20964/2018.05.54 ER -
@article{ author = "Božić, Bojan and Lović, Jelena and Banjac, Nebojša R. and Vitnik, Željko and Vitnik, Vesna and Mijin, Dušan and Ušćumlić, Gordana and Avramov Ivić, Milka", year = "2018", abstract = "A series of succinimide derivatives were studied using the cyclic and square wave voltammetry. Density function theory was used in order to determinate which of the structural parameters influence the electrochemical activity. The quantum chemical calculations of the investigated succinimides were linked with the experimental electrochemical data and used to propose the oxidation mechanism. The most active among studied succinimides is 1,3-diphenylsuccinimide. The results obtained from the cyclic and square wave voltammetry and quantum chemical calculations indicate that the investigated compounds undergo oxidation by irreversible, diffusion controlled process including transfer of 1e(-) and 1 proton. The voltammetric and DFT results signify that the mechanism of electrochemical oxidation of all compounds involve the conversion of carbonyl-methyne-phenyl segment or methylene group in free radical. This conversion proceeds by the loss of one proton one electron process.", publisher = "Esg, Belgrade", journal = "International Journal of Electrochemical Science", title = "Voltammetric and Quantum Investigation of Selected Succinimides", volume = "13", number = "5", pages = "4285-4297", doi = "10.20964/2018.05.54" }
Božić, B., Lović, J., Banjac, N. R., Vitnik, Ž., Vitnik, V., Mijin, D., Ušćumlić, G.,& Avramov Ivić, M.. (2018). Voltammetric and Quantum Investigation of Selected Succinimides. in International Journal of Electrochemical Science Esg, Belgrade., 13(5), 4285-4297. https://doi.org/10.20964/2018.05.54
Božić B, Lović J, Banjac NR, Vitnik Ž, Vitnik V, Mijin D, Ušćumlić G, Avramov Ivić M. Voltammetric and Quantum Investigation of Selected Succinimides. in International Journal of Electrochemical Science. 2018;13(5):4285-4297. doi:10.20964/2018.05.54 .
Božić, Bojan, Lović, Jelena, Banjac, Nebojša R., Vitnik, Željko, Vitnik, Vesna, Mijin, Dušan, Ušćumlić, Gordana, Avramov Ivić, Milka, "Voltammetric and Quantum Investigation of Selected Succinimides" in International Journal of Electrochemical Science, 13, no. 5 (2018):4285-4297, https://doi.org/10.20964/2018.05.54 . .