Voltammetric and Quantum Investigation of Selected Succinimides
2018
Authors
Božić, BojanLović, Jelena
Banjac, Nebojša R.
Vitnik, Željko
Vitnik, Vesna
Mijin, Dušan
Ušćumlić, Gordana
Avramov Ivić, Milka
Article (Published version)
Metadata
Show full item recordAbstract
A series of succinimide derivatives were studied using the cyclic and square wave voltammetry. Density function theory was used in order to determinate which of the structural parameters influence the electrochemical activity. The quantum chemical calculations of the investigated succinimides were linked with the experimental electrochemical data and used to propose the oxidation mechanism. The most active among studied succinimides is 1,3-diphenylsuccinimide. The results obtained from the cyclic and square wave voltammetry and quantum chemical calculations indicate that the investigated compounds undergo oxidation by irreversible, diffusion controlled process including transfer of 1e(-) and 1 proton. The voltammetric and DFT results signify that the mechanism of electrochemical oxidation of all compounds involve the conversion of carbonyl-methyne-phenyl segment or methylene group in free radical. This conversion proceeds by the loss of one proton one electron process.
Keywords:
Diphenylsuccinimide / Threephenylsuccinimide / Voltammetry / Quantum chemical calculations / Reaction mechanismsSource:
International Journal of Electrochemical Science, 2018, 13, 5, 4285-4297Publisher:
- Esg, Belgrade
Funding / projects:
- Study of the Synthesis, Structure and Activity of Natural and Synthetic Organic Compounds (RS-172013)
- Rational design and synthesis of biologically active and coordination compounds and functional materials, relevant for (bio)nanotechnology (RS-172035)
- New approach in designing materials for energy conversion and energy storage systems (RS-172060)
DOI: 10.20964/2018.05.54
ISSN: 1452-3981
WoS: 000436257800020
Scopus: 2-s2.0-85046802281
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Institution/Community
IHTMTY - JOUR AU - Božić, Bojan AU - Lović, Jelena AU - Banjac, Nebojša R. AU - Vitnik, Željko AU - Vitnik, Vesna AU - Mijin, Dušan AU - Ušćumlić, Gordana AU - Avramov Ivić, Milka PY - 2018 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2300 AB - A series of succinimide derivatives were studied using the cyclic and square wave voltammetry. Density function theory was used in order to determinate which of the structural parameters influence the electrochemical activity. The quantum chemical calculations of the investigated succinimides were linked with the experimental electrochemical data and used to propose the oxidation mechanism. The most active among studied succinimides is 1,3-diphenylsuccinimide. The results obtained from the cyclic and square wave voltammetry and quantum chemical calculations indicate that the investigated compounds undergo oxidation by irreversible, diffusion controlled process including transfer of 1e(-) and 1 proton. The voltammetric and DFT results signify that the mechanism of electrochemical oxidation of all compounds involve the conversion of carbonyl-methyne-phenyl segment or methylene group in free radical. This conversion proceeds by the loss of one proton one electron process. PB - Esg, Belgrade T2 - International Journal of Electrochemical Science T1 - Voltammetric and Quantum Investigation of Selected Succinimides VL - 13 IS - 5 SP - 4285 EP - 4297 DO - 10.20964/2018.05.54 ER -
@article{ author = "Božić, Bojan and Lović, Jelena and Banjac, Nebojša R. and Vitnik, Željko and Vitnik, Vesna and Mijin, Dušan and Ušćumlić, Gordana and Avramov Ivić, Milka", year = "2018", abstract = "A series of succinimide derivatives were studied using the cyclic and square wave voltammetry. Density function theory was used in order to determinate which of the structural parameters influence the electrochemical activity. The quantum chemical calculations of the investigated succinimides were linked with the experimental electrochemical data and used to propose the oxidation mechanism. The most active among studied succinimides is 1,3-diphenylsuccinimide. The results obtained from the cyclic and square wave voltammetry and quantum chemical calculations indicate that the investigated compounds undergo oxidation by irreversible, diffusion controlled process including transfer of 1e(-) and 1 proton. The voltammetric and DFT results signify that the mechanism of electrochemical oxidation of all compounds involve the conversion of carbonyl-methyne-phenyl segment or methylene group in free radical. This conversion proceeds by the loss of one proton one electron process.", publisher = "Esg, Belgrade", journal = "International Journal of Electrochemical Science", title = "Voltammetric and Quantum Investigation of Selected Succinimides", volume = "13", number = "5", pages = "4285-4297", doi = "10.20964/2018.05.54" }
Božić, B., Lović, J., Banjac, N. R., Vitnik, Ž., Vitnik, V., Mijin, D., Ušćumlić, G.,& Avramov Ivić, M.. (2018). Voltammetric and Quantum Investigation of Selected Succinimides. in International Journal of Electrochemical Science Esg, Belgrade., 13(5), 4285-4297. https://doi.org/10.20964/2018.05.54
Božić B, Lović J, Banjac NR, Vitnik Ž, Vitnik V, Mijin D, Ušćumlić G, Avramov Ivić M. Voltammetric and Quantum Investigation of Selected Succinimides. in International Journal of Electrochemical Science. 2018;13(5):4285-4297. doi:10.20964/2018.05.54 .
Božić, Bojan, Lović, Jelena, Banjac, Nebojša R., Vitnik, Željko, Vitnik, Vesna, Mijin, Dušan, Ušćumlić, Gordana, Avramov Ivić, Milka, "Voltammetric and Quantum Investigation of Selected Succinimides" in International Journal of Electrochemical Science, 13, no. 5 (2018):4285-4297, https://doi.org/10.20964/2018.05.54 . .