The synthesized rod-like Ag2CO3 particles (2-4 x 0.3-0.6 mu m, length x diameter) served as a precursor for preparation of the AgX/Ag2CO3 (X = CI, I) composites by ion exchange method. The various microstructural (X-ray diffraction analysis, transmission electron microscopy, nitrogen adsorption desorption isotherms) and optical (diffuse reflection spectroscopy) techniques were used for thorough characterization of obtained heterostructures. The enhanced photocatalytic performance of AgX/Ag2CO3 heterostructures in comparison to Ag2CO3 nanorods (NRs) was evidenced using degradation of organic dye methylene blue as a test reaction. Also, the formation of composites improved their stability under long run illumination conditions. The effect of AgX content on photocatalytic activity of the composites were also investigated. The possible photocatalytic mechanism that facilitates efficient separation of photo-formed charge carriers in heterostructures was discussed in terms of the relative en...ergetic of valence and conduction bands.
TY - JOUR
AU - Dostanić, Jasmina
AU - Lončarević, Davor
AU - Đorđević, Vesna
AU - Ahrenkiel, Scott Phillip
AU - Nedeljković, Jovan M.
PY - 2017
UR - http://cer.ihtm.bg.ac.rs/handle/123456789/2242
AB - The synthesized rod-like Ag2CO3 particles (2-4 x 0.3-0.6 mu m, length x diameter) served as a precursor for preparation of the AgX/Ag2CO3 (X = CI, I) composites by ion exchange method. The various microstructural (X-ray diffraction analysis, transmission electron microscopy, nitrogen adsorption desorption isotherms) and optical (diffuse reflection spectroscopy) techniques were used for thorough characterization of obtained heterostructures. The enhanced photocatalytic performance of AgX/Ag2CO3 heterostructures in comparison to Ag2CO3 nanorods (NRs) was evidenced using degradation of organic dye methylene blue as a test reaction. Also, the formation of composites improved their stability under long run illumination conditions. The effect of AgX content on photocatalytic activity of the composites were also investigated. The possible photocatalytic mechanism that facilitates efficient separation of photo-formed charge carriers in heterostructures was discussed in terms of the relative energetic of valence and conduction bands.
PB - Elsevier Science Sa, Lausanne
T2 - Journal of Photochemistry and Photobiology A-Chemistry
T1 - The photocatalytic performance of silver halides - Silver carbonate heterostructures
VL - 336
SP - 1
EP - 7
DO - 10.1016/j.jphotochem.2016.12.019
ER -
@article{
author = "Dostanić, Jasmina and Lončarević, Davor and Đorđević, Vesna and Ahrenkiel, Scott Phillip and Nedeljković, Jovan M.",
year = "2017",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/2242",
abstract = "The synthesized rod-like Ag2CO3 particles (2-4 x 0.3-0.6 mu m, length x diameter) served as a precursor for preparation of the AgX/Ag2CO3 (X = CI, I) composites by ion exchange method. The various microstructural (X-ray diffraction analysis, transmission electron microscopy, nitrogen adsorption desorption isotherms) and optical (diffuse reflection spectroscopy) techniques were used for thorough characterization of obtained heterostructures. The enhanced photocatalytic performance of AgX/Ag2CO3 heterostructures in comparison to Ag2CO3 nanorods (NRs) was evidenced using degradation of organic dye methylene blue as a test reaction. Also, the formation of composites improved their stability under long run illumination conditions. The effect of AgX content on photocatalytic activity of the composites were also investigated. The possible photocatalytic mechanism that facilitates efficient separation of photo-formed charge carriers in heterostructures was discussed in terms of the relative energetic of valence and conduction bands.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Journal of Photochemistry and Photobiology A-Chemistry",
title = "The photocatalytic performance of silver halides - Silver carbonate heterostructures",
volume = "336",
pages = "1-7",
doi = "10.1016/j.jphotochem.2016.12.019"
}
Dostanić, J., Lončarević, D., Đorđević, V., Ahrenkiel, S. P.,& Nedeljković, J. M. (2017). The photocatalytic performance of silver halides - Silver carbonate heterostructures.
Journal of Photochemistry and Photobiology A-Chemistry
Elsevier Science Sa, Lausanne., 336, 1-7.
https://doi.org/10.1016/j.jphotochem.2016.12.019
Dostanić J, Lončarević D, Đorđević V, Ahrenkiel SP, Nedeljković JM. The photocatalytic performance of silver halides - Silver carbonate heterostructures. Journal of Photochemistry and Photobiology A-Chemistry. 2017;336:1-7
Dostanić Jasmina, Lončarević Davor, Đorđević Vesna, Ahrenkiel Scott Phillip, Nedeljković Jovan M., "The photocatalytic performance of silver halides - Silver carbonate heterostructures" Journal of Photochemistry and Photobiology A-Chemistry, 336 (2017):1-7,
https://doi.org/10.1016/j.jphotochem.2016.12.019 .
