A novel macroporous polymer-inorganic nanocomposite as a sorbent for pertechnetate ions

2017
Authors
Marković, Bojana
Janković, Drina

Vukadinovic, Aleksandar A.

Randjelović, Danijela

Maksin, Danijela

Spasojević, Vojislav

Nastasović, Aleksandra

Article (Published version)
Metadata
Show full item recordAbstract
A novel magnetic macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) (mPGME) was prepared by suspension copolymerization and functionalized with diethylenetriamine (mPGME-deta). The samples were characterized by Fourier transform infrared spectroscopy (FTIR) analysis, mercury porosimetry, scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), atomic force microscopy (AFM) and SQUID magnetometry. The sorption behavior of mPGME-deta toward pertechnetate ions (TcO4-) from aqueous solution was studied. Experimental results indicated relatively fast TcO4- sorption kinetics that depends on pH and ionic strength, with a high removal efficiency of 99% within 180 min in the pH range 3.0-5.0. The pseudo-second-order model yielded the best fit for the kinetic data.
Source:
RSC Advances, 2017, 7, 35, 21412-21421Publisher:
- The Royal Society of Chemistry
Funding / projects:
- Advanced technologies for monitoring and environmental protection from chemical pollutants and radiation burden (RS-43009)
- Magnetic and radionuclide labeled nanostructured materials for medical applications (RS-45015)
- Synthesis and characterization of novel functional polymers and polymeric nanocomposites (RS-172062)
- Micro- Nanosystems and Sensors for Electric Power and Process Industry and Environmental Protection (RS-32008)
- Agrobiodiversity and land-use change in Serbia: an integrated biodiversity assessment of key functional groups of arthropods and plant pathogens (RS-43001)
DOI: 10.1039/c7ra02783d
ISSN: 2046-2069
WoS: 000399810800008
Scopus: 2-s2.0-85018480652
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Institution/Community
IHTMTY - JOUR AU - Marković, Bojana AU - Janković, Drina AU - Vukadinovic, Aleksandar A. AU - Randjelović, Danijela AU - Maksin, Danijela AU - Spasojević, Vojislav AU - Nastasović, Aleksandra PY - 2017 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2241 AB - A novel magnetic macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) (mPGME) was prepared by suspension copolymerization and functionalized with diethylenetriamine (mPGME-deta). The samples were characterized by Fourier transform infrared spectroscopy (FTIR) analysis, mercury porosimetry, scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), atomic force microscopy (AFM) and SQUID magnetometry. The sorption behavior of mPGME-deta toward pertechnetate ions (TcO4-) from aqueous solution was studied. Experimental results indicated relatively fast TcO4- sorption kinetics that depends on pH and ionic strength, with a high removal efficiency of 99% within 180 min in the pH range 3.0-5.0. The pseudo-second-order model yielded the best fit for the kinetic data. PB - The Royal Society of Chemistry T2 - RSC Advances T1 - A novel macroporous polymer-inorganic nanocomposite as a sorbent for pertechnetate ions VL - 7 IS - 35 SP - 21412 EP - 21421 DO - 10.1039/c7ra02783d ER -
@article{ author = "Marković, Bojana and Janković, Drina and Vukadinovic, Aleksandar A. and Randjelović, Danijela and Maksin, Danijela and Spasojević, Vojislav and Nastasović, Aleksandra", year = "2017", abstract = "A novel magnetic macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) (mPGME) was prepared by suspension copolymerization and functionalized with diethylenetriamine (mPGME-deta). The samples were characterized by Fourier transform infrared spectroscopy (FTIR) analysis, mercury porosimetry, scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), atomic force microscopy (AFM) and SQUID magnetometry. The sorption behavior of mPGME-deta toward pertechnetate ions (TcO4-) from aqueous solution was studied. Experimental results indicated relatively fast TcO4- sorption kinetics that depends on pH and ionic strength, with a high removal efficiency of 99% within 180 min in the pH range 3.0-5.0. The pseudo-second-order model yielded the best fit for the kinetic data.", publisher = "The Royal Society of Chemistry", journal = "RSC Advances", title = "A novel macroporous polymer-inorganic nanocomposite as a sorbent for pertechnetate ions", volume = "7", number = "35", pages = "21412-21421", doi = "10.1039/c7ra02783d" }
Marković, B., Janković, D., Vukadinovic, A. A., Randjelović, D., Maksin, D., Spasojević, V.,& Nastasović, A.. (2017). A novel macroporous polymer-inorganic nanocomposite as a sorbent for pertechnetate ions. in RSC Advances The Royal Society of Chemistry., 7(35), 21412-21421. https://doi.org/10.1039/c7ra02783d
Marković B, Janković D, Vukadinovic AA, Randjelović D, Maksin D, Spasojević V, Nastasović A. A novel macroporous polymer-inorganic nanocomposite as a sorbent for pertechnetate ions. in RSC Advances. 2017;7(35):21412-21421. doi:10.1039/c7ra02783d .
Marković, Bojana, Janković, Drina, Vukadinovic, Aleksandar A., Randjelović, Danijela, Maksin, Danijela, Spasojević, Vojislav, Nastasović, Aleksandra, "A novel macroporous polymer-inorganic nanocomposite as a sorbent for pertechnetate ions" in RSC Advances, 7, no. 35 (2017):21412-21421, https://doi.org/10.1039/c7ra02783d . .