Macroporous copolymers of poly[(glycidyl methacrylate)-co-(ethylene glycol dimethacrylate)] (PGME) with various crosslinker (ethylene glycol dimethacrylate) concentrations and porosity parameters and additionally functionalized with hexamethylene diamine (PGME-HD) were tested as potential Cr(VI) oxyanion sorbents from aqueous solutions. Kinetics of Cr(VI) sorption was investigated in the temperature range 298-343 K and the results were fitted to chemical reaction and particle diffusion models. The Cr(VI) sorption obeys the pseudo-second-order model with definite influence of pore diffusion. A temperature rise promotes chromium removal, with a maximum experimental uptake capacity of 4.21 mmol g(-1) at 343 K for the sample with the highest amino group concentration. Equilibrium data were analysed with Langmuir, Freundlich and Temkin adsorption isotherm models. Thermodynamic parameters, i.e. Gibbs free energy (G(0)), enthalpy (H-0) and entropy change (S-0) and activation energy of sorptio...n (E-a), were calculated. The Cr(VI) adsorption onto PGME-HD was found to be spontaneous and endothermic, with increased randomness in the system. Desorption experiments show that chromium anion sorption was reversible and the PGME-HD sample GMA 60 HD was easily regenerated with 0.1 mol L-1 NaOH up to 90% recovery in the fourth sorption/desorption cycle. In the fifth cycle, a substantial sorption loss of 37% was observed.
TY - JOUR
AU - Marković, Bojana
AU - Stefanović, Ivan
AU - Hercigonja, Radmila
AU - Pergal, Marija
AU - Markovic, Jelena P.
AU - Onjia, Antonije E.
AU - Nastasović, Aleksandra
PY - 2017
UR - http://cer.ihtm.bg.ac.rs/handle/123456789/2223
AB - Macroporous copolymers of poly[(glycidyl methacrylate)-co-(ethylene glycol dimethacrylate)] (PGME) with various crosslinker (ethylene glycol dimethacrylate) concentrations and porosity parameters and additionally functionalized with hexamethylene diamine (PGME-HD) were tested as potential Cr(VI) oxyanion sorbents from aqueous solutions. Kinetics of Cr(VI) sorption was investigated in the temperature range 298-343 K and the results were fitted to chemical reaction and particle diffusion models. The Cr(VI) sorption obeys the pseudo-second-order model with definite influence of pore diffusion. A temperature rise promotes chromium removal, with a maximum experimental uptake capacity of 4.21 mmol g(-1) at 343 K for the sample with the highest amino group concentration. Equilibrium data were analysed with Langmuir, Freundlich and Temkin adsorption isotherm models. Thermodynamic parameters, i.e. Gibbs free energy (G(0)), enthalpy (H-0) and entropy change (S-0) and activation energy of sorption (E-a), were calculated. The Cr(VI) adsorption onto PGME-HD was found to be spontaneous and endothermic, with increased randomness in the system. Desorption experiments show that chromium anion sorption was reversible and the PGME-HD sample GMA 60 HD was easily regenerated with 0.1 mol L-1 NaOH up to 90% recovery in the fourth sorption/desorption cycle. In the fifth cycle, a substantial sorption loss of 37% was observed.
PB - Wiley, Hoboken
T2 - Polymer International
T1 - Novel hexamethylene diamine-functionalized macroporous copolymer for chromium removal from aqueous solutions
VL - 66
IS - 5
SP - 679
EP - 689
DO - 10.1002/pi.5306
ER -
@article{
author = "Marković, Bojana and Stefanović, Ivan and Hercigonja, Radmila and Pergal, Marija and Markovic, Jelena P. and Onjia, Antonije E. and Nastasović, Aleksandra",
year = "2017",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/2223",
abstract = "Macroporous copolymers of poly[(glycidyl methacrylate)-co-(ethylene glycol dimethacrylate)] (PGME) with various crosslinker (ethylene glycol dimethacrylate) concentrations and porosity parameters and additionally functionalized with hexamethylene diamine (PGME-HD) were tested as potential Cr(VI) oxyanion sorbents from aqueous solutions. Kinetics of Cr(VI) sorption was investigated in the temperature range 298-343 K and the results were fitted to chemical reaction and particle diffusion models. The Cr(VI) sorption obeys the pseudo-second-order model with definite influence of pore diffusion. A temperature rise promotes chromium removal, with a maximum experimental uptake capacity of 4.21 mmol g(-1) at 343 K for the sample with the highest amino group concentration. Equilibrium data were analysed with Langmuir, Freundlich and Temkin adsorption isotherm models. Thermodynamic parameters, i.e. Gibbs free energy (G(0)), enthalpy (H-0) and entropy change (S-0) and activation energy of sorption (E-a), were calculated. The Cr(VI) adsorption onto PGME-HD was found to be spontaneous and endothermic, with increased randomness in the system. Desorption experiments show that chromium anion sorption was reversible and the PGME-HD sample GMA 60 HD was easily regenerated with 0.1 mol L-1 NaOH up to 90% recovery in the fourth sorption/desorption cycle. In the fifth cycle, a substantial sorption loss of 37% was observed.",
publisher = "Wiley, Hoboken",
journal = "Polymer International",
title = "Novel hexamethylene diamine-functionalized macroporous copolymer for chromium removal from aqueous solutions",
volume = "66",
number = "5",
pages = "679-689",
doi = "10.1002/pi.5306"
}
Marković, B., Stefanović, I., Hercigonja, R., Pergal, M., Markovic, J. P., Onjia, A. E.,& Nastasović, A. (2017). Novel hexamethylene diamine-functionalized macroporous copolymer for chromium removal from aqueous solutions.
Polymer International
Wiley, Hoboken., 66(5), 679-689.
https://doi.org/10.1002/pi.5306
Marković B, Stefanović I, Hercigonja R, Pergal M, Markovic JP, Onjia AE, Nastasović A. Novel hexamethylene diamine-functionalized macroporous copolymer for chromium removal from aqueous solutions. Polymer International. 2017;66(5):679-689
Marković Bojana, Stefanović Ivan, Hercigonja Radmila, Pergal Marija, Markovic Jelena P., Onjia Antonije E., Nastasović Aleksandra, "Novel hexamethylene diamine-functionalized macroporous copolymer for chromium removal from aqueous solutions" Polymer International, 66, no. 5 (2017):679-689,
https://doi.org/10.1002/pi.5306 .
