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dc.creatorLović, Jelena
dc.date.accessioned2019-01-30T17:55:30Z
dc.date.available2019-01-30T17:55:30Z
dc.date.issued2017
dc.identifier.issn1070-4272
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/2201
dc.description.abstractElectrodeposited PdNi and Pd samples were tested for methanol and ethanol oxidation reaction (MOR and EOR) in alkaline solution using cyclic voltammetry (CV) and chronoamperometric (CA) measurements. Among the CVs for the MOR, all alloy samples showed higher current densities than pure Pd. Also the peak current densities for MOR of PdNi coatings are 5 to 8 times higher than that obtained on Pd coating depending on composition. Based on the ratio of the forward peak current to the backward peak current the tolerance of the catalysts to accumulation of carbonaceous species is determined. Besides this ratio increased with extending the anodic potential limit. The most tolerant catalyst is found to be Pd0.74Ni0.28 in methanol oxidation. Comparative study of methanol and ethanol electrooxidation in the alkaline media reveals that Pd0.74Ni0.26 alloy has a higher catalytic activity, as well as a better tolerance to accumulation of carbonaceous species.en
dc.publisherPleiades Publishing Inc, Moscow
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172060/RS//
dc.rightsrestrictedAccess
dc.sourceRussian Journal of Applied Chemistry
dc.titleElectrochemical Oxidation of Methanol and Ethanol on Electrodeposited Pd and PdNi-Coated Electrodesen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractЛовић, Јелена;
dc.citation.volume90
dc.citation.issue12
dc.citation.spage2039
dc.citation.epage2045
dc.citation.other90(12): 2039-2045
dc.citation.rankM23
dc.identifier.doi10.1134/S1070427217120229
dc.identifier.rcubConv_4044
dc.identifier.scopus2-s2.0-85046652785
dc.identifier.wos000455086200001
dc.type.versionpublishedVersion


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