Selective magnetic GMA based potential sorbents for molybdenum and rhenium sorption

Marković, Bojana; Vuković, Zorica; Spasojević, Vojislav; Kusigerski, Vladan B.; Pavlović, Vladimir B.; Onjia, Antonije E.; Nastasović, Aleksandra

doi:10.1016/j.jallcom.2017.02.108

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2017

Authors

Marković, Bojana
Vuković, Zorica
Spasojević, Vojislav

Kusigerski, Vladan B.

Pavlović, Vladimir B.

Onjia, Antonije E.

Nastasović, Aleksandra

Article (Published version)

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Abstract

Magnetic macroporous crosslinked copolymer glycidyl methacrylate (GMA) and ethylene glycol dimethacrylate (EGDMA) samples with different magnetite content were prepared by suspension copolymerization and functionalized with diethylene triamine. Samples were characterized by elemental analysis, mercury porosimetry, Fourier transform infrared spectroscopy (FTIR) analysis, scanning electron microscopy with energy-dispersive X-ray spectroscopy, transmission electron microscopy, SQUID magnetometry and X-ray photoelectron spectroscopy (XPS). The selected amino-functionalized sample was tested as a potential sorbent for the Mo(VI) and Re(VII) oxyanions from aqueous solutions. The influence of pH, ionic strength and possible interfering of cations and anions was investigated. Equilibrium data were analyzed with Langmuir, Freundlich and Tempkin adsorption isotherm models. Sorption studies were carried out in a batch competitive experiments, in the pH range 1-8, at 298 K. Obtained results indica...

Keywords:

Magnetic macroporous copolymer / Diethylene triamine / Mo(VI) and Re(VII) sorption

Source:
Journal of Alloys and Compounds, 2017, 705, 38-50

Publisher:

Elsevier

Projects:

Note:

Peer-reviewed version: http://cer.ihtm.bg.ac.rs/handle/123456789/3014

DOI: 10.1016/j.jallcom.2017.02.108

ISSN: 0925-8388

WoS: 000397994700006

Scopus: 2-s2.0-85012965542

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TY - JOUR
AU - Marković, Bojana
AU - Vuković, Zorica
AU - Spasojević, Vojislav
AU - Kusigerski, Vladan B.
AU - Pavlović, Vladimir B.
AU - Onjia, Antonije E.
AU - Nastasović, Aleksandra
PY - 2017
UR - http://cer.ihtm.bg.ac.rs/handle/123456789/2191
AB - Magnetic macroporous crosslinked copolymer glycidyl methacrylate (GMA) and ethylene glycol dimethacrylate (EGDMA) samples with different magnetite content were prepared by suspension copolymerization and functionalized with diethylene triamine. Samples were characterized by elemental analysis, mercury porosimetry, Fourier transform infrared spectroscopy (FTIR) analysis, scanning electron microscopy with energy-dispersive X-ray spectroscopy, transmission electron microscopy, SQUID magnetometry and X-ray photoelectron spectroscopy (XPS). The selected amino-functionalized sample was tested as a potential sorbent for the Mo(VI) and Re(VII) oxyanions from aqueous solutions. The influence of pH, ionic strength and possible interfering of cations and anions was investigated. Equilibrium data were analyzed with Langmuir, Freundlich and Tempkin adsorption isotherm models. Sorption studies were carried out in a batch competitive experiments, in the pH range 1-8, at 298 K. Obtained results indicate that 92% of Re(VII) and 98% of Mo(VI) were sorbed at pH 2.
PB - Elsevier
T2 - Journal of Alloys and Compounds
T1 - Selective magnetic GMA based potential sorbents for molybdenum and rhenium sorption
VL - 705
SP - 38
EP - 50
DO - 10.1016/j.jallcom.2017.02.108
ER -

@article{
author = "Marković, Bojana and Vuković, Zorica and Spasojević, Vojislav and Kusigerski, Vladan B. and Pavlović, Vladimir B. and Onjia, Antonije E. and Nastasović, Aleksandra",
year = "2017",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/2191",
abstract = "Magnetic macroporous crosslinked copolymer glycidyl methacrylate (GMA) and ethylene glycol dimethacrylate (EGDMA) samples with different magnetite content were prepared by suspension copolymerization and functionalized with diethylene triamine. Samples were characterized by elemental analysis, mercury porosimetry, Fourier transform infrared spectroscopy (FTIR) analysis, scanning electron microscopy with energy-dispersive X-ray spectroscopy, transmission electron microscopy, SQUID magnetometry and X-ray photoelectron spectroscopy (XPS). The selected amino-functionalized sample was tested as a potential sorbent for the Mo(VI) and Re(VII) oxyanions from aqueous solutions. The influence of pH, ionic strength and possible interfering of cations and anions was investigated. Equilibrium data were analyzed with Langmuir, Freundlich and Tempkin adsorption isotherm models. Sorption studies were carried out in a batch competitive experiments, in the pH range 1-8, at 298 K. Obtained results indicate that 92% of Re(VII) and 98% of Mo(VI) were sorbed at pH 2.",
publisher = "Elsevier",
journal = "Journal of Alloys and Compounds",
title = "Selective magnetic GMA based potential sorbents for molybdenum and rhenium sorption",
volume = "705",
pages = "38-50",
doi = "10.1016/j.jallcom.2017.02.108"
}

Marković B, Vuković Z, Spasojević V, Kusigerski VB, Pavlović VB, Onjia AE, Nastasović A. Selective magnetic GMA based potential sorbents for molybdenum and rhenium sorption. Journal of Alloys and Compounds. 2017;705:38-50

Marković, B., Vuković, Z., Spasojević, V., Kusigerski, V. B., Pavlović, V. B., Onjia, A. E.,& Nastasović, A. (2017). Selective magnetic GMA based potential sorbents for molybdenum and rhenium sorption.
Journal of Alloys and CompoundsElsevier., 705, 38-50.
https://doi.org/10.1016/j.jallcom.2017.02.108

Marković Bojana, Vuković Zorica, Spasojević Vojislav, Kusigerski Vladan B., Pavlović Vladimir B., Onjia Antonije E., Nastasović Aleksandra, "Selective magnetic GMA based potential sorbents for molybdenum and rhenium sorption" 705 (2017):38-50,
https://doi.org/10.1016/j.jallcom.2017.02.108 .