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The influence of m-aminobenzoic acid on electrochemical synthesis and behavior of poly(aniline-co-(m-aminobenzoic acid)

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2017
Authors
Jokić, Bojan
Dzunuzovic, Enis S.
Grgur, Branimir N.
Jugović, Branimir
Trišović, Tomislav
Stevanović, Jasmina
Gvozdenović, Milica M.
Article (Published version)
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Abstract
Poly(aniline-co-(m-aminobenzoic acid)) was synthesized electrochemically at graphite electrode under galvanostatic conditions. Aqueous electrolyte for synthesis was consisted of HCl and different amount of aniline and m-aminobenzoic acid. The presence of the meta positioned carboxylic group in m-aminobenzoic acid influenced higher co-polymerization potential, different morphology and electrochemical behavior of copolymers compared to polyaniline. Electrochemical activity is achieved by proton exchange in neutral environment that can result in a faster charge/discharge process, which is in the case of PANI limited by slow anion exchange, making this material promising for consideration in super-capacitors and in biological system.
Keywords:
Electrochemical co-polymerization / Cyclic voltammetry / Poly(aniline-co-(m-aminobenzoic acid) / UV-vis spectroscopy
Source:
Journal of Polymer Research, 2017, 24, 9
Publisher:
  • Springer, Dordrecht
Projects:
  • Electrochemical synthesis and characterization of nanostructured functional materials for application in new technologies (RS-172046)
  • Synthesis, processing and applications of nanostructured multifunctional materials with defined properties (RS-45019)

DOI: 10.1007/s10965-017-1313-5

ISSN: 1022-9760

WoS: 000408478900001

Scopus: 2-s2.0-85028326537
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URI
http://cer.ihtm.bg.ac.rs/handle/123456789/2173
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IHTM

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