The influence of m-aminobenzoic acid on electrochemical synthesis and behavior of poly(aniline-co-(m-aminobenzoic acid)
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2017
Authors
Jokić, BojanDzunuzovic, Enis S.
Grgur, Branimir N.

Jugović, Branimir

Trišović, Tomislav

Stevanović, Jasmina

Gvozdenović, Milica M.

Article (Published version)

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Show full item recordAbstract
Poly(aniline-co-(m-aminobenzoic acid)) was synthesized electrochemically at graphite electrode under galvanostatic conditions. Aqueous electrolyte for synthesis was consisted of HCl and different amount of aniline and m-aminobenzoic acid. The presence of the meta positioned carboxylic group in m-aminobenzoic acid influenced higher co-polymerization potential, different morphology and electrochemical behavior of copolymers compared to polyaniline. Electrochemical activity is achieved by proton exchange in neutral environment that can result in a faster charge/discharge process, which is in the case of PANI limited by slow anion exchange, making this material promising for consideration in super-capacitors and in biological system.
Keywords:
Electrochemical co-polymerization / Cyclic voltammetry / Poly(aniline-co-(m-aminobenzoic acid) / UV-vis spectroscopySource:
Journal of Polymer Research, 2017, 24, 9Publisher:
- Springer, Dordrecht
Projects:
- Electrochemical synthesis and characterization of nanostructured functional materials for application in new technologies (RS-172046)
- Synthesis, processing and applications of nanostructured multifunctional materials with defined properties (RS-45019)
DOI: 10.1007/s10965-017-1313-5
ISSN: 1022-9760