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Synthesis, structures and electronic properties of Co(III) complexes with 2-quinolinecarboxaldehyde thio- and selenosemicarbazone: A combined experimental and theoretical study

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2164.pdf (2.696Mb)
Authors
Đorđević, Ivana
Vukasinovic, Jelena
Todorović, Tamara
Filipovic, Nenad R.
Rodić, Marko V.
Lolic, Aleksandar
Portalone, Gustavo
Zlatović, Mario
Grubišić, Sonja
Article (Published version)
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Abstract
Cobalt(III) complexes derived from thio-and selenosemicarbazone ligands have been studied to elucidate the nature and consequences of S to Se substitution on their possible biological activity. Solid state structures of cobalt(III) complexes with bis-tridentate coordinated 2-quinolinecarboxaldehyde thio-and selenosemicarbazone were determined by single crystal X-ray diffraction analysis. The complexes were also characterized by spectroscopic methods and cyclic voltammetry. Electronic properties of the complexes were studied using DFT and TD-DFT methods. Finally, evident in vitro antioxidant activity of the complexes was demonstrated.
Keywords:
X-ray crystal structure / cobalt(III) / Schiff base / antioxidant activity / DFT / Fukui
Source:
Journal of the Serbian Chemical Society, 2017, 82, 7-8, 825-839
Publisher:
  • Serbian Chemical Soc, Belgrade
Projects:
  • Rational design and synthesis of biologically active and coordination compounds and functional materials, relevant for (bio)nanotechnology (RS-172035)
  • Interactions of natural products, their derivatives and coordination compounds with proteins and nucleic acids (RS-172055)

DOI: 10.2298/JSC170412062D

ISSN: 0352-5139

WoS: 000410203200005

Scopus: 2-s2.0-85029451534
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URI
http://cer.ihtm.bg.ac.rs/handle/123456789/2166
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