CER - Central Repository
Institute of Chemistry, Technology and Metallurgy
    • English
    • Српски
    • Српски (Serbia)
  • English 
    • English
    • Serbian (Cyrillic)
    • Serbian (Latin)
  • Login
View Item 
  •   CER
  • IHTM
  • Radovi istraživača / Researchers' publications
  • View Item
  •   CER
  • IHTM
  • Radovi istraživača / Researchers' publications
  • View Item
JavaScript is disabled for your browser. Some features of this site may not work without it.

Organic geochemical approach in the identification of oil-type pollutants in water and sediment of the River Ibar

Thumbnail
2017
2161.pdf (2.078Mb)
Authors
Milićević, Zoran
Marinović, Dragan
Gajica, Gordana
Kašanin-Grubin, Milica
Jovanović, Verka
Jovančićević, Branimir
Article (Published version)
Metadata
Show full item record
Abstract
In this paper an applied organic geochemical approach in studying the nature of organic matter (OM) in water and sediments of the River Ibar (upsteream and downstream of towns Kosovska Mitrovica and Kraljevo) was used. A forensic approach that relies on the fact that the composition of OM of recent sediments and oil varies due to geological age and maturity was applied. The content of bitumen, its group composition of saturated, aromatic and NSO compounds (nitrogen, sulphur, and oxygen compounds) and the distribution of n-alkanes in saturated fractions identified by gas chromatography-mass spectrometry (in almost all samples incorporated into the colloidal micelles formed by water and NSO compounds) could not answer the question whether OM in isolated extracts has native or anthropogenic origin. However, the presence of sterane and terpane, with the distribution of structural and stereochemical isomers characteristic of oil, as a form of most matture OM in sediments, unambiguously conf...irmed presence of oil type pollutants in anlayzed samples. Based on significant differences in the distributions of these polycyclic alkane (water-water, sediment-sediment and water-sediment), it was concluded that they have more than one source of pollution, and that the River Ibar is permanently exposed to this form of pollution.

Keywords:
petroleum pollutants / biomarkers / urban pollution / environment
Source:
Journal of the Serbian Chemical Society, 2017, 82, 5, 593-605
Publisher:
  • Serbian Chemical Soc, Belgrade
Funding / projects:
  • Geochemical investigations of sedimentary rocks - fossil fuels and environmental pollutants (RS-176006)

DOI: 10.2298/JSC161129022M

ISSN: 0352-5139

WoS: 000408085400010

Scopus: 2-s2.0-85021700762
[ Google Scholar ]
3
4
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/2163
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Milićević, Zoran
AU  - Marinović, Dragan
AU  - Gajica, Gordana
AU  - Kašanin-Grubin, Milica
AU  - Jovanović, Verka
AU  - Jovančićević, Branimir
PY  - 2017
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2163
AB  - In this paper an applied organic geochemical approach in studying the nature of organic matter (OM) in water and sediments of the River Ibar (upsteream and downstream of towns Kosovska Mitrovica and Kraljevo) was used. A forensic approach that relies on the fact that the composition of OM of recent sediments and oil varies due to geological age and maturity was applied. The content of bitumen, its group composition of saturated, aromatic and NSO compounds (nitrogen, sulphur, and oxygen compounds) and the distribution of n-alkanes in saturated fractions identified by gas chromatography-mass spectrometry (in almost all samples incorporated into the colloidal micelles formed by water and NSO compounds) could not answer the question whether OM in isolated extracts has native or anthropogenic origin. However, the presence of sterane and terpane, with the distribution of structural and stereochemical isomers characteristic of oil, as a form of most matture OM in sediments, unambiguously confirmed presence of oil type pollutants in anlayzed samples. Based on significant differences in the distributions of these polycyclic alkane (water-water, sediment-sediment and water-sediment), it was concluded that they have more than one source of pollution, and that the River Ibar is permanently exposed to this form of pollution.
PB  - Serbian Chemical Soc, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Organic geochemical approach in the identification of oil-type pollutants in water and sediment of the River Ibar
VL  - 82
IS  - 5
SP  - 593
EP  - 605
DO  - 10.2298/JSC161129022M
ER  - 
@article{
author = "Milićević, Zoran and Marinović, Dragan and Gajica, Gordana and Kašanin-Grubin, Milica and Jovanović, Verka and Jovančićević, Branimir",
year = "2017",
abstract = "In this paper an applied organic geochemical approach in studying the nature of organic matter (OM) in water and sediments of the River Ibar (upsteream and downstream of towns Kosovska Mitrovica and Kraljevo) was used. A forensic approach that relies on the fact that the composition of OM of recent sediments and oil varies due to geological age and maturity was applied. The content of bitumen, its group composition of saturated, aromatic and NSO compounds (nitrogen, sulphur, and oxygen compounds) and the distribution of n-alkanes in saturated fractions identified by gas chromatography-mass spectrometry (in almost all samples incorporated into the colloidal micelles formed by water and NSO compounds) could not answer the question whether OM in isolated extracts has native or anthropogenic origin. However, the presence of sterane and terpane, with the distribution of structural and stereochemical isomers characteristic of oil, as a form of most matture OM in sediments, unambiguously confirmed presence of oil type pollutants in anlayzed samples. Based on significant differences in the distributions of these polycyclic alkane (water-water, sediment-sediment and water-sediment), it was concluded that they have more than one source of pollution, and that the River Ibar is permanently exposed to this form of pollution.",
publisher = "Serbian Chemical Soc, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Organic geochemical approach in the identification of oil-type pollutants in water and sediment of the River Ibar",
volume = "82",
number = "5",
pages = "593-605",
doi = "10.2298/JSC161129022M"
}
Milićević, Z., Marinović, D., Gajica, G., Kašanin-Grubin, M., Jovanović, V.,& Jovančićević, B.. (2017). Organic geochemical approach in the identification of oil-type pollutants in water and sediment of the River Ibar. in Journal of the Serbian Chemical Society
Serbian Chemical Soc, Belgrade., 82(5), 593-605.
https://doi.org/10.2298/JSC161129022M
Milićević Z, Marinović D, Gajica G, Kašanin-Grubin M, Jovanović V, Jovančićević B. Organic geochemical approach in the identification of oil-type pollutants in water and sediment of the River Ibar. in Journal of the Serbian Chemical Society. 2017;82(5):593-605.
doi:10.2298/JSC161129022M .
Milićević, Zoran, Marinović, Dragan, Gajica, Gordana, Kašanin-Grubin, Milica, Jovanović, Verka, Jovančićević, Branimir, "Organic geochemical approach in the identification of oil-type pollutants in water and sediment of the River Ibar" in Journal of the Serbian Chemical Society, 82, no. 5 (2017):593-605,
https://doi.org/10.2298/JSC161129022M . .

DSpace software copyright © 2002-2015  DuraSpace
About CeR – Central Repository | Send Feedback

re3dataOpenAIRERCUB
 

 

All of DSpaceInstitutions/communitiesAuthorsTitlesSubjectsThis institutionAuthorsTitlesSubjects

Statistics

View Usage Statistics

DSpace software copyright © 2002-2015  DuraSpace
About CeR – Central Repository | Send Feedback

re3dataOpenAIRERCUB