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Hybrid visible-light responsive Al2O3 particles

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2017
Authors
Đorđević, Vesna
Dostanić, Jasmina
Lončarević, Davor
Ahrenkiel, Scott Phillip
Sredojević, Dušan
Svrakic, Nenad
Belić, Milivoj
Nedeljković, Jovan M.
Article (Published version)
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Abstract
Detailed study of Al2O3, an insulator with the band gap of about 8.7 eV, and its different organic/inorganic charge transfer complexes with visible-light photo activity is presented. In particular, prepared Al2O3 particles of the size 0.1-0.3 mu m are coated with several organic complexes - the specific details for catecholate- and salicylate-type of ligands are described below - and the light absorption properties and photocatalytic activity of such hybrids are scrutinized and compared with those of other organic/inorganic hybrid materials previously studied. In addition, the obtained experimental results are supported with quantum chemical calculations based on density functional theory.
Keywords:
Inorganic/organic hybrids / Charge transfer complex / Visible light responsive material / Al2O3 / Photocatalysis
Source:
Chemical Physics Letters, 2017, 685, 416-421
Publisher:
  • Elsevier Science Bv, Amsterdam
Projects:
  • Qatar National Research Fund - 6-02-1-1005
  • Qatar National Research Fund - 5-674-1-114
  • Materials of Reduced Dimensions for Efficient Light Harvesting and Energy conversion (RS-45020)
  • Modeling and Numerical Simulations of Complex Many-Body Systems (RS-171017)

DOI: 10.1016/j.cplett.2017.08.012

ISSN: 0009-2614

WoS: 000410841500064

Scopus: 2-s2.0-85028003703
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URI
http://cer.ihtm.bg.ac.rs/handle/123456789/2160
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