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Investigation of mechanism and critical parameters for removal of arsenic from water using Zr-TiO2 composite

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Authors
Anđelković, Ivan
Amaizah, Naser Ramdan R.
Marković, Smilja B.
Stanković, Dalibor
Marković, Marijana
Kuzmanovic, D.
Roglić, Goran
Article (Published version)
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Abstract
Using the microwave-hydrothermal method for the synthesis of composite, high surface density of hydroxyl groups, as an active adsorption sites for arsenic, was obtained. Adsorption mechanisms of As(III) and As(V) onto zirconium-doped titanium dioxide (Zr-TiO2) were investigated and proposed using macroscopic and microscopic methods. Obtained results are suggesting inner-sphere and outer-sphere adsorption mechanisms for As(III) and As(V), respectively. This allowed us to identify parameters that are critical for the successful removal of arsenic from water, which is essential information for further optimization of the removal process. The composite was further applied for the removal of As(III) and As(V) from water in a dynamic flow through the reactor. Column study proved that the removal of both arsenic species below the value recommended by WHO can be achieved. Elution of As(III) and As(V) from the composite can be done by using small amounts of 0.01M NaOH solution resulting in prec...oncentration of arsenic species and possible multiple usage of composite.

Keywords:
Microwave-hydrothermal synthesis / As(III) / As(V) / adsorption / mechanism
Source:
Environmental Technology, 2017, 38, 17, 2233-2240
Publisher:
  • Taylor & Francis Ltd, Abingdon
Funding / projects:
  • Application of advanced oxidation processes and nanostructured oxide materials for the removal of pollutants from the environment, development and optimisation of instrumental techniques for efficiency monitoring (RS-172030)
Note:
  • The peer-reviewed version: http://cer.ihtm.bg.ac.rs/handle/123456789/2671

DOI: 10.1080/09593330.2016.1255664

ISSN: 0959-3330

PubMed: 27804788

WoS: 000406560200014

Scopus: 2-s2.0-84996560155
[ Google Scholar ]
5
3
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/2151
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Anđelković, Ivan
AU  - Amaizah, Naser Ramdan R.
AU  - Marković, Smilja B.
AU  - Stanković, Dalibor
AU  - Marković, Marijana
AU  - Kuzmanovic, D.
AU  - Roglić, Goran
PY  - 2017
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2151
AB  - Using the microwave-hydrothermal method for the synthesis of composite, high surface density of hydroxyl groups, as an active adsorption sites for arsenic, was obtained. Adsorption mechanisms of As(III) and As(V) onto zirconium-doped titanium dioxide (Zr-TiO2) were investigated and proposed using macroscopic and microscopic methods. Obtained results are suggesting inner-sphere and outer-sphere adsorption mechanisms for As(III) and As(V), respectively. This allowed us to identify parameters that are critical for the successful removal of arsenic from water, which is essential information for further optimization of the removal process. The composite was further applied for the removal of As(III) and As(V) from water in a dynamic flow through the reactor. Column study proved that the removal of both arsenic species below the value recommended by WHO can be achieved. Elution of As(III) and As(V) from the composite can be done by using small amounts of 0.01M NaOH solution resulting in preconcentration of arsenic species and possible multiple usage of composite.
PB  - Taylor & Francis Ltd, Abingdon
T2  - Environmental Technology
T1  - Investigation of mechanism and critical parameters for removal of arsenic from water using Zr-TiO2 composite
VL  - 38
IS  - 17
SP  - 2233
EP  - 2240
DO  - 10.1080/09593330.2016.1255664
ER  - 
@article{
author = "Anđelković, Ivan and Amaizah, Naser Ramdan R. and Marković, Smilja B. and Stanković, Dalibor and Marković, Marijana and Kuzmanovic, D. and Roglić, Goran",
year = "2017",
abstract = "Using the microwave-hydrothermal method for the synthesis of composite, high surface density of hydroxyl groups, as an active adsorption sites for arsenic, was obtained. Adsorption mechanisms of As(III) and As(V) onto zirconium-doped titanium dioxide (Zr-TiO2) were investigated and proposed using macroscopic and microscopic methods. Obtained results are suggesting inner-sphere and outer-sphere adsorption mechanisms for As(III) and As(V), respectively. This allowed us to identify parameters that are critical for the successful removal of arsenic from water, which is essential information for further optimization of the removal process. The composite was further applied for the removal of As(III) and As(V) from water in a dynamic flow through the reactor. Column study proved that the removal of both arsenic species below the value recommended by WHO can be achieved. Elution of As(III) and As(V) from the composite can be done by using small amounts of 0.01M NaOH solution resulting in preconcentration of arsenic species and possible multiple usage of composite.",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Environmental Technology",
title = "Investigation of mechanism and critical parameters for removal of arsenic from water using Zr-TiO2 composite",
volume = "38",
number = "17",
pages = "2233-2240",
doi = "10.1080/09593330.2016.1255664"
}
Anđelković, I., Amaizah, N. R. R., Marković, S. B., Stanković, D., Marković, M., Kuzmanovic, D.,& Roglić, G.. (2017). Investigation of mechanism and critical parameters for removal of arsenic from water using Zr-TiO2 composite. in Environmental Technology
Taylor & Francis Ltd, Abingdon., 38(17), 2233-2240.
https://doi.org/10.1080/09593330.2016.1255664
Anđelković I, Amaizah NRR, Marković SB, Stanković D, Marković M, Kuzmanovic D, Roglić G. Investigation of mechanism and critical parameters for removal of arsenic from water using Zr-TiO2 composite. in Environmental Technology. 2017;38(17):2233-2240.
doi:10.1080/09593330.2016.1255664 .
Anđelković, Ivan, Amaizah, Naser Ramdan R., Marković, Smilja B., Stanković, Dalibor, Marković, Marijana, Kuzmanovic, D., Roglić, Goran, "Investigation of mechanism and critical parameters for removal of arsenic from water using Zr-TiO2 composite" in Environmental Technology, 38, no. 17 (2017):2233-2240,
https://doi.org/10.1080/09593330.2016.1255664 . .

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