Synthesis, characterization, DFT calculations and antimicrobial activity of Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent
Authorized Users Only
2017
Authors
Romanović, Mima
Čobeljić, Božidar

Pevec, Andrej

Turel, Iztok

Grubišić, Sonja

Radanović, Dušanka

Anđelković, Katarina

Milenković, Marina

Milenković, Milica R.

Article (Published version)

Metadata
Show full item recordAbstract
The chloro (1) and isocyanato (2) Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) have been synthesized and characterized by elemental analysis, IR, and NMR spectroscopy. The crystal structure of chloro Cd(II) complex (1) was determined. In 1 and 2, coordination surrounding of Cd(II) consists of deprotonated hydrazone ligand coordinated through NNO-donor atoms and two monodentates at the rest of the coordination places. Quantum chemical calculations of the molecular structures and the relative stabilities of linkage isomers of the Cd(II) complex showed that the isomer with N-Cd-N coordination of OCN- is the most stable. The investigated Cd(II) complexes showed lower activity than standard antimicrobial drugs. [GRAPHICS] .
Keywords:
Cd(II) complexes / hydrazones / crystal structure / antimicrobial activity / DFTSource:
Journal of Coordination Chemistry, 2017, 70, 21, 3702-3714Publisher:
- Taylor & Francis Ltd, Abingdon
Funding / projects:
- Interactions of natural products, their derivatives and coordination compounds with proteins and nucleic acids (RS-172055)
- COST Action ECOSTBio (Explicit Control Over Spin-States in Technology and Biochemistry) including a STSM grant [CM1305, COST-STSM-CM1305-25068]
- COST Action ECOSTBio (Explicit Control Over Spin-States in Technology and Biochemistry) including a STSM grant [CM1305, COST-STSM-CM1305-25068]
- Slovenian Research Agency [P1-0175]
Note:
- The peer-reviewed version: http://cer.ihtm.bg.ac.rs/handle/123456789/3122
DOI: 10.1080/00958972.2017.1405262
ISSN: 0095-8972
WoS: 000418940000010
Scopus: 2-s2.0-85034657439
Collections
Institution/Community
IHTMTY - JOUR AU - Romanović, Mima AU - Čobeljić, Božidar AU - Pevec, Andrej AU - Turel, Iztok AU - Grubišić, Sonja AU - Radanović, Dušanka AU - Anđelković, Katarina AU - Milenković, Marina AU - Milenković, Milica R. PY - 2017 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2109 AB - The chloro (1) and isocyanato (2) Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) have been synthesized and characterized by elemental analysis, IR, and NMR spectroscopy. The crystal structure of chloro Cd(II) complex (1) was determined. In 1 and 2, coordination surrounding of Cd(II) consists of deprotonated hydrazone ligand coordinated through NNO-donor atoms and two monodentates at the rest of the coordination places. Quantum chemical calculations of the molecular structures and the relative stabilities of linkage isomers of the Cd(II) complex showed that the isomer with N-Cd-N coordination of OCN- is the most stable. The investigated Cd(II) complexes showed lower activity than standard antimicrobial drugs. [GRAPHICS] . PB - Taylor & Francis Ltd, Abingdon T2 - Journal of Coordination Chemistry T1 - Synthesis, characterization, DFT calculations and antimicrobial activity of Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent VL - 70 IS - 21 SP - 3702 EP - 3714 DO - 10.1080/00958972.2017.1405262 ER -
@article{ author = "Romanović, Mima and Čobeljić, Božidar and Pevec, Andrej and Turel, Iztok and Grubišić, Sonja and Radanović, Dušanka and Anđelković, Katarina and Milenković, Marina and Milenković, Milica R.", year = "2017", abstract = "The chloro (1) and isocyanato (2) Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) have been synthesized and characterized by elemental analysis, IR, and NMR spectroscopy. The crystal structure of chloro Cd(II) complex (1) was determined. In 1 and 2, coordination surrounding of Cd(II) consists of deprotonated hydrazone ligand coordinated through NNO-donor atoms and two monodentates at the rest of the coordination places. Quantum chemical calculations of the molecular structures and the relative stabilities of linkage isomers of the Cd(II) complex showed that the isomer with N-Cd-N coordination of OCN- is the most stable. The investigated Cd(II) complexes showed lower activity than standard antimicrobial drugs. [GRAPHICS] .", publisher = "Taylor & Francis Ltd, Abingdon", journal = "Journal of Coordination Chemistry", title = "Synthesis, characterization, DFT calculations and antimicrobial activity of Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent", volume = "70", number = "21", pages = "3702-3714", doi = "10.1080/00958972.2017.1405262" }
Romanović, M., Čobeljić, B., Pevec, A., Turel, I., Grubišić, S., Radanović, D., Anđelković, K., Milenković, M.,& Milenković, M. R.. (2017). Synthesis, characterization, DFT calculations and antimicrobial activity of Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent. in Journal of Coordination Chemistry Taylor & Francis Ltd, Abingdon., 70(21), 3702-3714. https://doi.org/10.1080/00958972.2017.1405262
Romanović M, Čobeljić B, Pevec A, Turel I, Grubišić S, Radanović D, Anđelković K, Milenković M, Milenković MR. Synthesis, characterization, DFT calculations and antimicrobial activity of Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent. in Journal of Coordination Chemistry. 2017;70(21):3702-3714. doi:10.1080/00958972.2017.1405262 .
Romanović, Mima, Čobeljić, Božidar, Pevec, Andrej, Turel, Iztok, Grubišić, Sonja, Radanović, Dušanka, Anđelković, Katarina, Milenković, Marina, Milenković, Milica R., "Synthesis, characterization, DFT calculations and antimicrobial activity of Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent" in Journal of Coordination Chemistry, 70, no. 21 (2017):3702-3714, https://doi.org/10.1080/00958972.2017.1405262 . .