The aim of this work was to prepare and characterize the series of segmented polyurethane nanocomposites (PUNC) modified with poly(dimethylsiloxane) and based on montmorillonite (Mt) as a nano-filler. alpha,omega-Dihydroxy-poly(propylene oxide)-b-poly(dimethylsiloxane)-b-poly(propylene oxide) macrodiol was used as the soft segment component, while 4,4'-diphenylmethane diisocyanate (MDI) and 1,4-butanediol (BD) were selected as the hard segment components. PUNC were synthesized with different ratio of hard/soft segments. PUNC were morphologically, structurally, thermally, mechanically and surface characterized by XRD, TEM, FTIR, AFM, TGA, DMTA, tensile test, XPS, contact angle, surface free energy (SFE) and water absorption measurements. Added Mt (1 wt%) was completely delaminated and well dispersed in the form of mixed exfoliated/intercalated layers in the polymer matrix, and that PUNC have more pronounced microphase separated morphology, higher thermal stability, superior mechanical f...eatures, enhanced surface properties, as well as outstanding hydrophobicity. Due to the improved features, developed polymers can be considered as candidates for materials with specific biomedical applications or as waterproof coatings.
TY - JOUR
AU - Stefanović, Ivan
AU - Spirkova, Milena
AU - Ostojić, Sanja
AU - Stefanov, Plamen
AU - Pavlović, Vladimir B.
AU - Pergal, Marija
PY - 2017
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2092
AB - The aim of this work was to prepare and characterize the series of segmented polyurethane nanocomposites (PUNC) modified with poly(dimethylsiloxane) and based on montmorillonite (Mt) as a nano-filler. alpha,omega-Dihydroxy-poly(propylene oxide)-b-poly(dimethylsiloxane)-b-poly(propylene oxide) macrodiol was used as the soft segment component, while 4,4'-diphenylmethane diisocyanate (MDI) and 1,4-butanediol (BD) were selected as the hard segment components. PUNC were synthesized with different ratio of hard/soft segments. PUNC were morphologically, structurally, thermally, mechanically and surface characterized by XRD, TEM, FTIR, AFM, TGA, DMTA, tensile test, XPS, contact angle, surface free energy (SFE) and water absorption measurements. Added Mt (1 wt%) was completely delaminated and well dispersed in the form of mixed exfoliated/intercalated layers in the polymer matrix, and that PUNC have more pronounced microphase separated morphology, higher thermal stability, superior mechanical features, enhanced surface properties, as well as outstanding hydrophobicity. Due to the improved features, developed polymers can be considered as candidates for materials with specific biomedical applications or as waterproof coatings.
PB - Elsevier
T2 - Applied Clay Science
T1 - Montmorillonite/poly(urethane-siloxane) nanocomposites: Morphological, thermal, mechanical and surface properties
VL - 149
SP - 136
EP - 146
DO - 10.1016/j.clay.2017.08.021
ER -
@article{
author = "Stefanović, Ivan and Spirkova, Milena and Ostojić, Sanja and Stefanov, Plamen and Pavlović, Vladimir B. and Pergal, Marija",
year = "2017",
abstract = "The aim of this work was to prepare and characterize the series of segmented polyurethane nanocomposites (PUNC) modified with poly(dimethylsiloxane) and based on montmorillonite (Mt) as a nano-filler. alpha,omega-Dihydroxy-poly(propylene oxide)-b-poly(dimethylsiloxane)-b-poly(propylene oxide) macrodiol was used as the soft segment component, while 4,4'-diphenylmethane diisocyanate (MDI) and 1,4-butanediol (BD) were selected as the hard segment components. PUNC were synthesized with different ratio of hard/soft segments. PUNC were morphologically, structurally, thermally, mechanically and surface characterized by XRD, TEM, FTIR, AFM, TGA, DMTA, tensile test, XPS, contact angle, surface free energy (SFE) and water absorption measurements. Added Mt (1 wt%) was completely delaminated and well dispersed in the form of mixed exfoliated/intercalated layers in the polymer matrix, and that PUNC have more pronounced microphase separated morphology, higher thermal stability, superior mechanical features, enhanced surface properties, as well as outstanding hydrophobicity. Due to the improved features, developed polymers can be considered as candidates for materials with specific biomedical applications or as waterproof coatings.",
publisher = "Elsevier",
journal = "Applied Clay Science",
title = "Montmorillonite/poly(urethane-siloxane) nanocomposites: Morphological, thermal, mechanical and surface properties",
volume = "149",
pages = "136-146",
doi = "10.1016/j.clay.2017.08.021"
}
Stefanović, I., Spirkova, M., Ostojić, S., Stefanov, P., Pavlović, V. B.,& Pergal, M.. (2017). Montmorillonite/poly(urethane-siloxane) nanocomposites: Morphological, thermal, mechanical and surface properties. in Applied Clay Science
Elsevier., 149, 136-146.
https://doi.org/10.1016/j.clay.2017.08.021
Stefanović I, Spirkova M, Ostojić S, Stefanov P, Pavlović VB, Pergal M. Montmorillonite/poly(urethane-siloxane) nanocomposites: Morphological, thermal, mechanical and surface properties. in Applied Clay Science. 2017;149:136-146.
doi:10.1016/j.clay.2017.08.021 .
Stefanović, Ivan, Spirkova, Milena, Ostojić, Sanja, Stefanov, Plamen, Pavlović, Vladimir B., Pergal, Marija, "Montmorillonite/poly(urethane-siloxane) nanocomposites: Morphological, thermal, mechanical and surface properties" in Applied Clay Science, 149 (2017):136-146,
https://doi.org/10.1016/j.clay.2017.08.021 . .
