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dc.creatorMarković, Bojana
dc.creatorMaksin, Danijela
dc.creatorMojović, Zorica
dc.creatorVuković, Zorica
dc.creatorNastasović, Aleksandra
dc.creatorJovanović, Dušan M.
dc.date.accessioned2019-01-30T17:53:01Z
dc.date.available2019-01-30T17:53:01Z
dc.date.issued2017
dc.identifier.issn1572-6657
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/2079
dc.description.abstractIn this study, macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) was synthesized by suspension copolymerization, functionalized by ring-opening reaction of the pendant epoxy groups with diethylene triamine and used for immobilization of Pd(II) ions from chloride and nitrate solutions under batch experimental condition. The amino-functionalized sample and samples with immobilized Pd(II) ions were characterized by Fourier transform infrared spectroscopy (FTIR) analysis and scanning energy-dispersive X-ray spectroscopy (SEM-EDX). The electrochemical behavior of electrodes composed of synthesized samples was tested in 0.1 M H2SO4 by means of cyclic voltammetry (CV). The shape of recorded CV showed dependence on the type of Pd-salt used for Pd immobilization. The reaction of oxidation of 4-chlorophenol (4-CP) from 0.1 M H2SO4 at investigated samples was also studied. Electrooxidation of 4-CP resulted in passivation and formation of reversible hydroquinone/benzoquinone on both investigated electrodes, although hydroquinone/benzoquinone formation was more pronounced on Pd immobilized from nitrite solution.en
dc.publisherElsevier
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/43001/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45001/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/43009/RS//
dc.rightsrestrictedAccess
dc.sourceJournal of Electroanalytical Chemistry
dc.subjectPGMEen
dc.subjectPalladiumen
dc.subjectChlorophenolen
dc.subjectElectrooxidationen
dc.titleElectrochemical behavior of palladium modified amino-functionalized macroporous copolymeren
dc.typearticle
dc.rights.licenseARR
dcterms.abstractНастасовић, Aлександра; Марковић, Бојана; Вуковић, Зорица; Јовановиц, Дусан М.; Максин, Данијела Д.; Мојовић, Зорица;
dc.citation.volume786
dc.citation.spage94
dc.citation.epage101
dc.citation.other786: 94-101
dc.citation.rankM21
dc.description.otherThe peer-reviewed version: [http://cer.ihtm.bg.ac.rs/handle/123456789/3019]
dc.identifier.doi10.1016/j.jelechem.2017.01.018
dc.identifier.rcubConv_3320
dc.identifier.scopus2-s2.0-85009183692
dc.identifier.wos000394063600014
dc.type.versionpublishedVersion


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