CER - Central Repository
Institute of Chemistry, Technology and Metallurgy
    • English
    • Српски
    • Српски (Serbia)
  • English 
    • English
    • Serbian (Cyrillic)
    • Serbian (Latin)
  • Login
View Item 
  •   CER
  • IHTM
  • Radovi istraživača / Researchers' publications
  • View Item
  •   CER
  • IHTM
  • Radovi istraživača / Researchers' publications
  • View Item
JavaScript is disabled for your browser. Some features of this site may not work without it.

Production of rubber plasticizers based on waste PET: Techno-economical aspect

Sinteza plastifikatora iz otpadnog PET-a za primenu u gumenim proizvodima - tehno-ekonomska analiza

Thumbnail
2017
2074.pdf (491.2Kb)
Authors
Rusmirović, Jelena
Milošević, Dragana
Veličić, Zorica
Karanac, Milica
Kalifa, Mustafa
Nikolić, Jovana
Marinković, Aleksandar D.
Article (Published version)
Metadata
Show full item record
Abstract
Production of rubber plasticizers, based on waste poly(ethylene terephthalate) (PET), and economic effectiveness of developed technologies are presented and discussed. Waste PET glycolyzates, named diisononyl terephthalate(DINTP), didecyl terephthalate (DDTP), dibenzyl terephthalate(DBTP) and diglyceryl terephthalate(DGTP), were obtained by catalytic depolymerization of PET with isononyl alcohol, decyl alcohol, benzyl alcohol and glycerol. The structural analysis of the synthesized plasticizers was done using elemental, FTIR and NMR spectral analysis. Physical-mechanical properties of the rubber products composed of 100 phr of 28 % nitrile butadiene caoutchouc (NBR) and 20.7 phr of plasticizer were investigated. Influence of the synthesized plasticizers on Shore hardness, breaking strength and elongation at break was investigated. Obtained results were compared with ones obtained for commercial plasticizer dioctyl phthatale (DOP). Evaluation of economic potential of new technology for ...plasticizers production, i.e. results of techno-economic analysis, was presented. Benefits of the presented technology was based on the use of waste PET which is related to both environmental protection and profitability aspects.

U radu je predstavljen postupak sinteze plastifikatora na bazi otpadnog poli(etilen tereftalata) (PET-a), kao i ekonomičnost razvijene tehnologije. Plastifikatori na bazi otpadnog PET-a: diizononil-tereftalat (DINTP), didecil-tereftalat (DDTP), dibenzil-tereftalat (DBTP) i digliceriltereftalat (DGTP) dobijeni su katalitičkom depolimerizacijom PET-a monohidroksilnim alkoholima (izononil, decil i benzil alkoholi) i trohidroksilnim alkoholom (glicerinom). Struktura sintetisanih plastifikatora potvrđena je primenom elementalne, FT-IR i NMR analize. Proučavane su fizičkomehaničke karakteristike (tvrdoća po Šoru, prekidna jačina i prekidno istezanje) proizvoda od gume, koje se sastoje od 100 phr-a 28%-nog nitril butadien kaučuka (NBR) i 20,7 phr-a plastifikatora na bazi otpadnog PET-a. Dobijeni rezultati su upoređeni sa fizičko-mehaničkim karakteristikama proizvoda dobijenim korišćenjem komercijalnog plastifikatora dioktil-ftalata (DOPa). Procena ekonomskog potnecijala prikazane tehnologije ...za proizvodnju plastifikatora na bazi otpadnog PET-a izvršena je izradom detaljne tehno-ekonomske analize. Na osnovu određene tačke rentabiliteta doređena je minimalna cena koštanja jedinice proizvoda koja je, uz evidentno smanjen uticaj na životnu sredinu, konkurentna komercijalnom DOP-u.

Keywords:
waste PET glycolysis / plasticizers / rubber / PET recycling / glikolizati otpadnog PET-a / tehnologija plasticizera / tehnologija gume / reciklaža PET-a
Source:
Zaštita materijala, 2017, 58, 2, 189-197
Publisher:
  • Belgrade, Serbia : Engineering Society for Corrosion

DOI: 10.5937/ZasMat1702189R

ISSN: 0351-9465

[ Google Scholar ]
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/2076
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Rusmirović, Jelena
AU  - Milošević, Dragana
AU  - Veličić, Zorica
AU  - Karanac, Milica
AU  - Kalifa, Mustafa
AU  - Nikolić, Jovana
AU  - Marinković, Aleksandar D.
PY  - 2017
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2076
AB  - Production of rubber plasticizers, based on waste poly(ethylene terephthalate) (PET), and economic effectiveness of developed technologies are presented and discussed. Waste PET glycolyzates, named diisononyl terephthalate(DINTP), didecyl terephthalate (DDTP), dibenzyl terephthalate(DBTP) and diglyceryl terephthalate(DGTP), were obtained by catalytic depolymerization of PET with isononyl alcohol, decyl alcohol, benzyl alcohol and glycerol. The structural analysis of the synthesized plasticizers was done using elemental, FTIR and NMR spectral analysis. Physical-mechanical properties of the rubber products composed of 100 phr of 28 % nitrile butadiene caoutchouc (NBR) and 20.7 phr of plasticizer were investigated. Influence of the synthesized plasticizers on Shore hardness, breaking strength and elongation at break was investigated. Obtained results were compared with ones obtained for commercial plasticizer dioctyl phthatale (DOP). Evaluation of economic potential of new technology for plasticizers production, i.e. results of techno-economic analysis, was presented. Benefits of the presented technology was based on the use of waste PET which is related to both environmental protection and profitability aspects.
AB  - U radu je predstavljen postupak sinteze plastifikatora na bazi otpadnog poli(etilen tereftalata) (PET-a), kao i ekonomičnost razvijene tehnologije. Plastifikatori na bazi otpadnog PET-a: diizononil-tereftalat (DINTP), didecil-tereftalat (DDTP), dibenzil-tereftalat (DBTP) i digliceriltereftalat (DGTP) dobijeni su katalitičkom depolimerizacijom PET-a monohidroksilnim alkoholima (izononil, decil i benzil alkoholi) i trohidroksilnim alkoholom (glicerinom). Struktura sintetisanih plastifikatora potvrđena je primenom elementalne, FT-IR i NMR analize. Proučavane su fizičkomehaničke karakteristike (tvrdoća po Šoru, prekidna jačina i prekidno istezanje) proizvoda od gume, koje se sastoje od 100 phr-a 28%-nog nitril butadien kaučuka (NBR) i 20,7 phr-a plastifikatora na bazi otpadnog PET-a. Dobijeni rezultati su upoređeni sa fizičko-mehaničkim karakteristikama proizvoda dobijenim korišćenjem komercijalnog plastifikatora dioktil-ftalata (DOPa). Procena ekonomskog potnecijala prikazane tehnologije za proizvodnju plastifikatora na bazi otpadnog PET-a izvršena je izradom detaljne tehno-ekonomske analize. Na osnovu određene tačke rentabiliteta doređena je minimalna cena koštanja jedinice proizvoda koja je, uz evidentno smanjen uticaj na životnu sredinu, konkurentna komercijalnom DOP-u.
PB  - Belgrade, Serbia : Engineering Society for Corrosion
T2  - Zaštita materijala
T1  - Production of rubber plasticizers based on waste PET: Techno-economical aspect
T1  - Sinteza plastifikatora iz otpadnog PET-a za primenu u gumenim proizvodima - tehno-ekonomska analiza
VL  - 58
IS  - 2
SP  - 189
EP  - 197
DO  - 10.5937/ZasMat1702189R
ER  - 
@article{
author = "Rusmirović, Jelena and Milošević, Dragana and Veličić, Zorica and Karanac, Milica and Kalifa, Mustafa and Nikolić, Jovana and Marinković, Aleksandar D.",
year = "2017",
abstract = "Production of rubber plasticizers, based on waste poly(ethylene terephthalate) (PET), and economic effectiveness of developed technologies are presented and discussed. Waste PET glycolyzates, named diisononyl terephthalate(DINTP), didecyl terephthalate (DDTP), dibenzyl terephthalate(DBTP) and diglyceryl terephthalate(DGTP), were obtained by catalytic depolymerization of PET with isononyl alcohol, decyl alcohol, benzyl alcohol and glycerol. The structural analysis of the synthesized plasticizers was done using elemental, FTIR and NMR spectral analysis. Physical-mechanical properties of the rubber products composed of 100 phr of 28 % nitrile butadiene caoutchouc (NBR) and 20.7 phr of plasticizer were investigated. Influence of the synthesized plasticizers on Shore hardness, breaking strength and elongation at break was investigated. Obtained results were compared with ones obtained for commercial plasticizer dioctyl phthatale (DOP). Evaluation of economic potential of new technology for plasticizers production, i.e. results of techno-economic analysis, was presented. Benefits of the presented technology was based on the use of waste PET which is related to both environmental protection and profitability aspects., U radu je predstavljen postupak sinteze plastifikatora na bazi otpadnog poli(etilen tereftalata) (PET-a), kao i ekonomičnost razvijene tehnologije. Plastifikatori na bazi otpadnog PET-a: diizononil-tereftalat (DINTP), didecil-tereftalat (DDTP), dibenzil-tereftalat (DBTP) i digliceriltereftalat (DGTP) dobijeni su katalitičkom depolimerizacijom PET-a monohidroksilnim alkoholima (izononil, decil i benzil alkoholi) i trohidroksilnim alkoholom (glicerinom). Struktura sintetisanih plastifikatora potvrđena je primenom elementalne, FT-IR i NMR analize. Proučavane su fizičkomehaničke karakteristike (tvrdoća po Šoru, prekidna jačina i prekidno istezanje) proizvoda od gume, koje se sastoje od 100 phr-a 28%-nog nitril butadien kaučuka (NBR) i 20,7 phr-a plastifikatora na bazi otpadnog PET-a. Dobijeni rezultati su upoređeni sa fizičko-mehaničkim karakteristikama proizvoda dobijenim korišćenjem komercijalnog plastifikatora dioktil-ftalata (DOPa). Procena ekonomskog potnecijala prikazane tehnologije za proizvodnju plastifikatora na bazi otpadnog PET-a izvršena je izradom detaljne tehno-ekonomske analize. Na osnovu određene tačke rentabiliteta doređena je minimalna cena koštanja jedinice proizvoda koja je, uz evidentno smanjen uticaj na životnu sredinu, konkurentna komercijalnom DOP-u.",
publisher = "Belgrade, Serbia : Engineering Society for Corrosion",
journal = "Zaštita materijala",
title = "Production of rubber plasticizers based on waste PET: Techno-economical aspect, Sinteza plastifikatora iz otpadnog PET-a za primenu u gumenim proizvodima - tehno-ekonomska analiza",
volume = "58",
number = "2",
pages = "189-197",
doi = "10.5937/ZasMat1702189R"
}
Rusmirović, J., Milošević, D., Veličić, Z., Karanac, M., Kalifa, M., Nikolić, J.,& Marinković, A. D.. (2017). Production of rubber plasticizers based on waste PET: Techno-economical aspect. in Zaštita materijala
Belgrade, Serbia : Engineering Society for Corrosion., 58(2), 189-197.
https://doi.org/10.5937/ZasMat1702189R
Rusmirović J, Milošević D, Veličić Z, Karanac M, Kalifa M, Nikolić J, Marinković AD. Production of rubber plasticizers based on waste PET: Techno-economical aspect. in Zaštita materijala. 2017;58(2):189-197.
doi:10.5937/ZasMat1702189R .
Rusmirović, Jelena, Milošević, Dragana, Veličić, Zorica, Karanac, Milica, Kalifa, Mustafa, Nikolić, Jovana, Marinković, Aleksandar D., "Production of rubber plasticizers based on waste PET: Techno-economical aspect" in Zaštita materijala, 58, no. 2 (2017):189-197,
https://doi.org/10.5937/ZasMat1702189R . .

DSpace software copyright © 2002-2015  DuraSpace
About CeR – Central Repository | Send Feedback

re3dataOpenAIRERCUB
 

 

All of DSpaceInstitutions/communitiesAuthorsTitlesSubjectsThis institutionAuthorsTitlesSubjects

Statistics

View Usage Statistics

DSpace software copyright © 2002-2015  DuraSpace
About CeR – Central Repository | Send Feedback

re3dataOpenAIRERCUB