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Synthesis of vinyldihydropyran by cooperative catalysis

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2016
2048.pdf (387.4Kb)
Authors
Vulović, Bojan
Maric, Ivana
Matović, Radomir
Saičić, Radomir N.
Article (Published version)
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Abstract
Delta(5)-Unsaturated aldehydes with a suitably positioned allylic halide, or phosphate, leaving group undergo doubly-catalyzed cyclization to give dihydropyran derivatives. The cyclization proceeds under the synergetic action of diazabicycloundecene and Pd(PPh3)(4). This type of transformation was also accomplished with an aryl ketone.
Keywords:
dihydropyran / cooperative catalysis / cyclization / organopalladium reagents
Source:
Journal of the Serbian Chemical Society, 2016, 81, 12, 1335-1343
Publisher:
  • Serbian Chemical Soc, Belgrade
Projects:
  • The development of new synthetic methods and their application in the synthesis of natural products and biologically active molecules (RS-172027)

DOI: 10.2298/JSC161102103V

ISSN: 0352-5139

WoS: 000392946100001

Scopus: 2-s2.0-85009739628
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URI
http://cer.ihtm.bg.ac.rs/handle/123456789/2050
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