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Synthesis of vinyldihydropyran by cooperative catalysis

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2016
2048.pdf (387.4Kb)
Authors
Vulović, Bojan
Maric, Ivana
Matović, Radomir
Saičić, Radomir N.
Article (Published version)
Metadata
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Abstract
Delta(5)-Unsaturated aldehydes with a suitably positioned allylic halide, or phosphate, leaving group undergo doubly-catalyzed cyclization to give dihydropyran derivatives. The cyclization proceeds under the synergetic action of diazabicycloundecene and Pd(PPh3)(4). This type of transformation was also accomplished with an aryl ketone.
Keywords:
dihydropyran / cooperative catalysis / cyclization / organopalladium reagents
Source:
Journal of the Serbian Chemical Society, 2016, 81, 12, 1335-1343
Publisher:
  • Serbian Chemical Soc, Belgrade
Funding / projects:
  • The development of new synthetic methods and their application in the synthesis of natural products and biologically active molecules (RS-172027)

DOI: 10.2298/JSC161102103V

ISSN: 0352-5139

WoS: 000392946100001

Scopus: 2-s2.0-85009739628
[ Google Scholar ]
1
1
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/2050
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Vulović, Bojan
AU  - Maric, Ivana
AU  - Matović, Radomir
AU  - Saičić, Radomir N.
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2050
AB  - Delta(5)-Unsaturated aldehydes with a suitably positioned allylic halide, or phosphate, leaving group undergo doubly-catalyzed cyclization to give dihydropyran derivatives. The cyclization proceeds under the synergetic action of diazabicycloundecene and Pd(PPh3)(4). This type of transformation was also accomplished with an aryl ketone.
PB  - Serbian Chemical Soc, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Synthesis of vinyldihydropyran by cooperative catalysis
VL  - 81
IS  - 12
SP  - 1335
EP  - 1343
DO  - 10.2298/JSC161102103V
ER  - 
@article{
author = "Vulović, Bojan and Maric, Ivana and Matović, Radomir and Saičić, Radomir N.",
year = "2016",
abstract = "Delta(5)-Unsaturated aldehydes with a suitably positioned allylic halide, or phosphate, leaving group undergo doubly-catalyzed cyclization to give dihydropyran derivatives. The cyclization proceeds under the synergetic action of diazabicycloundecene and Pd(PPh3)(4). This type of transformation was also accomplished with an aryl ketone.",
publisher = "Serbian Chemical Soc, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Synthesis of vinyldihydropyran by cooperative catalysis",
volume = "81",
number = "12",
pages = "1335-1343",
doi = "10.2298/JSC161102103V"
}
Vulović, B., Maric, I., Matović, R.,& Saičić, R. N.. (2016). Synthesis of vinyldihydropyran by cooperative catalysis. in Journal of the Serbian Chemical Society
Serbian Chemical Soc, Belgrade., 81(12), 1335-1343.
https://doi.org/10.2298/JSC161102103V
Vulović B, Maric I, Matović R, Saičić RN. Synthesis of vinyldihydropyran by cooperative catalysis. in Journal of the Serbian Chemical Society. 2016;81(12):1335-1343.
doi:10.2298/JSC161102103V .
Vulović, Bojan, Maric, Ivana, Matović, Radomir, Saičić, Radomir N., "Synthesis of vinyldihydropyran by cooperative catalysis" in Journal of the Serbian Chemical Society, 81, no. 12 (2016):1335-1343,
https://doi.org/10.2298/JSC161102103V . .

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