Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone)

Pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with condensation product of 2,6-diacetylpyridine and trimethylammoniumacetohydrazide (Girard's T reagent) were synthesized and characterized by elemental analyses, IR and UV-vis spectra, molar conductivity, and magnetic susceptibility. Crystal structures of the Co(II) and Ni(II) complexes were also determined. Antimicrobial activities of the ligand and metal complexes were examined.

Keywords:

Co(II) complexes / Ni(II) complex / 2,6-diacetylpyridine dihydrazone / crystal structure / antimicrobial activity

Source:
Journal of Coordination Chemistry, 2016, 69, 5, 801-811

Publisher:

Taylor & Francis Ltd, Abingdon

Projects:

Interactions of natural products, their derivatives and coordination compounds with proteins and nucleic acids (RS-172055)
Slovenian Research Agency [P-0175]

Note:

Peer-reviewed manusript: http://cer.ihtm.bg.ac.rs/handle/123456789/3189

DOI: 10.1080/00958972.2016.1139702

ISSN: 0095-8972

WoS: 000373140700006

Scopus: 2-s2.0-84958543408

[ Google Scholar ]


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TY  - JOUR
AU  - Bradan, Gabrijela
AU  - Čobeljić, Božidar
AU  - Pevec, Andrej
AU  - Turel, Iztok
AU  - Milenković, Marina
AU  - Radanović, Dušanka
AU  - Šumar-Ristović, Maja
AU  - Adaila, Kawther
AU  - Milenković, Milica R.
AU  - Anđelković, Katarina
PY  - 2016
UR  - http://cer.ihtm.bg.ac.rs/handle/123456789/2038
AB  - Pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with condensation product of 2,6-diacetylpyridine and trimethylammoniumacetohydrazide (Girard's T reagent) were synthesized and characterized by elemental analyses, IR and UV-vis spectra, molar conductivity, and magnetic susceptibility. Crystal structures of the Co(II) and Ni(II) complexes were also determined. Antimicrobial activities of the ligand and metal complexes were examined.
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone)
VL  - 69
IS  - 5
SP  - 801
EP  - 811
DO  - 10.1080/00958972.2016.1139702
ER  -

@article{
author = "Bradan, Gabrijela and Čobeljić, Božidar and Pevec, Andrej and Turel, Iztok and Milenković, Marina and Radanović, Dušanka and Šumar-Ristović, Maja and Adaila, Kawther and Milenković, Milica R. and Anđelković, Katarina",
year = "2016",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/2038",
abstract = "Pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with condensation product of 2,6-diacetylpyridine and trimethylammoniumacetohydrazide (Girard's T reagent) were synthesized and characterized by elemental analyses, IR and UV-vis spectra, molar conductivity, and magnetic susceptibility. Crystal structures of the Co(II) and Ni(II) complexes were also determined. Antimicrobial activities of the ligand and metal complexes were examined.",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone)",
volume = "69",
number = "5",
pages = "801-811",
doi = "10.1080/00958972.2016.1139702"
}

Bradan G, Čobeljić B, Pevec A, Turel I, Milenković M, Radanović D, Šumar-Ristović M, Adaila K, Milenković MR, Anđelković K. Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone). Journal of Coordination Chemistry. 2016;69(5):801-811

Bradan, G., Čobeljić, B., Pevec, A., Turel, I., Milenković, M., Radanović, D., Šumar-Ristović, M., Adaila, K., Milenković, M. R.,& Anđelković, K. (2016). Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone).
Journal of Coordination ChemistryTaylor & Francis Ltd, Abingdon., 69(5), 801-811.
https://doi.org/10.1080/00958972.2016.1139702

Bradan Gabrijela, Čobeljić Božidar, Pevec Andrej, Turel Iztok, Milenković Marina, Radanović Dušanka, Šumar-Ristović Maja, Adaila Kawther, Milenković Milica R., Anđelković Katarina, "Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone)" 69, no. 5 (2016):801-811,
https://doi.org/10.1080/00958972.2016.1139702 .