dc.creator | Pavlovic, Radoslav Z | |
dc.creator | Bjelaković, Mira | |
dc.creator | Milić, Dragana | |
dc.date.accessioned | 2019-01-30T17:51:57Z | |
dc.date.available | 2019-01-30T17:51:57Z | |
dc.date.issued | 2016 | |
dc.identifier.issn | 2046-2069 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/2029 | |
dc.description.abstract | The synthesis, characterization and behaviour of two novel Leigh-type amide [2]rotaxanes are reported. NMR study shows that fullerosteroidal and disteroidal rotaxanes occur in a peptide co-conformation in CDCl3. [D-6]DMSO induces fast unthreading of disteroidal rotaxane, which includes steroid co-conformers as intermediates. On the other hand, fullerosteroidal rotaxane undergoes predominantly a shuttling process occupying the stacked co-conformation, whereas unthreading is very slow in comparison with its disteroidal analogue (25% after 7 days). Moreover, organogelation and self-organization properties were studied. It was found that disteroidal rotaxane is an organogelator and its SEM image shows that it forms a branched film-like network in a PhMe/EtOAc 1 : 1 mixture. | en |
dc.publisher | Royal Soc Chemistry, Cambridge | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172002/RS// | |
dc.rights | openAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc/4.0/ | |
dc.source | RSC Advances | |
dc.title | Diamide-based fullerosteroidal and disteroidal [2] rotaxanes: solvent-induced macrocycle translocation and/or unthreading | en |
dc.type | article | |
dc.rights.license | BY-NC | |
dcterms.abstract | Павловиц, Радослав З; Бјелаковић, Мира; Милиц, Драгана Р; | |
dc.citation.volume | 6 | |
dc.citation.issue | 43 | |
dc.citation.spage | 37246 | |
dc.citation.epage | 37253 | |
dc.citation.other | 6(43): 37246-37253 | |
dc.citation.rank | M22 | |
dc.identifier.doi | 10.1039/c6ra03872g | |
dc.identifier.fulltext | https://cer.ihtm.bg.ac.rs//bitstream/id/8459/2027.pdf | |
dc.identifier.scopus | 2-s2.0-84968807628 | |
dc.identifier.wos | 000374561300119 | |
dc.type.version | publishedVersion | |