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dc.creatorPavlovic, Radoslav Z
dc.creatorBjelaković, Mira
dc.creatorMilić, Dragana
dc.date.accessioned2019-01-30T17:51:57Z
dc.date.available2019-01-30T17:51:57Z
dc.date.issued2016
dc.identifier.issn2046-2069
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/2029
dc.description.abstractThe synthesis, characterization and behaviour of two novel Leigh-type amide [2]rotaxanes are reported. NMR study shows that fullerosteroidal and disteroidal rotaxanes occur in a peptide co-conformation in CDCl3. [D-6]DMSO induces fast unthreading of disteroidal rotaxane, which includes steroid co-conformers as intermediates. On the other hand, fullerosteroidal rotaxane undergoes predominantly a shuttling process occupying the stacked co-conformation, whereas unthreading is very slow in comparison with its disteroidal analogue (25% after 7 days). Moreover, organogelation and self-organization properties were studied. It was found that disteroidal rotaxane is an organogelator and its SEM image shows that it forms a branched film-like network in a PhMe/EtOAc 1 : 1 mixture.en
dc.publisherRoyal Soc Chemistry, Cambridge
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172002/RS//
dc.rightsopenAccess
dc.sourceRSC Advances
dc.titleDiamide-based fullerosteroidal and disteroidal [2] rotaxanes: solvent-induced macrocycle translocation and/or unthreadingen
dc.typearticle
dc.rights.licenseBY-NC
dcterms.abstractПавловиц, Радослав З; Бјелаковић, Мира; Милиц, Драгана Р;
dc.citation.volume6
dc.citation.issue43
dc.citation.spage37246
dc.citation.epage37253
dc.citation.other6(43): 37246-37253
dc.citation.rankM22
dc.identifier.doi10.1039/c6ra03872g
dc.identifier.rcubConv_3521
dc.identifier.fulltexthttp://cer.ihtm.bg.ac.rs//bitstream/id/8459/2027.pdf
dc.identifier.scopus2-s2.0-84968807628
dc.identifier.wos000374561300119
dc.type.versionpublishedVersion


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